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Ceramic with light weight, high strength and high toughness and preparation method thereof

A high-toughness, ceramic technology, applied in the field of high-strength, light-weight, high-toughness ceramics, can solve the problems of difficult preparation of nanocrystalline ceramic products, difficulty in ensuring mixing uniformity, and insignificant toughening effect, etc., to achieve light weight, The effect of high toughness and easy molding

Inactive Publication Date: 2011-11-16
HEBEI YL BANGDA NEW MATERIALS LTD CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The particle dispersion toughening operation is relatively simple, but the toughening effect is not significant; the introduction of nano-scale particles into the ceramic matrix can achieve a good strengthening and toughening effect, but the preparation of nano-powders grows rapidly during the sintering process, making it difficult to prepare Real nanocrystalline ceramic products; phase change toughening has a good effect at room temperature, but toughening fails at high temperatures (above 1000 ° C); ceramic fiber (or whisker) reinforced and toughened ceramic matrix composites It has excellent mechanical properties at room temperature and high temperature. The preparation process of whiskers as a toughening phase is simpler. The disadvantage of fiber and whisker toughening is that it is difficult to ensure the uniformity of mixing, and whiskers are harmful to the human body, and the application is limited.
In recent years, inspired by the relationship between the structure and performance of biological materials in the biological world, people have designed bionic structures of ceramic materials, such as imitating bamboo and wood structures to make Si 3 N 4 / BN fiber monolithic ceramic material, imitating shell nacre structure made of Si 3 N 4 / BN layered structure ceramic materials, etc., also have a certain toughening effect, but its disadvantages are mainly that the properties parallel to and perpendicular to the interlayer direction are quite different, showing anisotropy
At the same time, the toughness of the layered and fiber monolithic ceramics is improved at the expense of strength, that is, although the toughness is greatly improved, the strength is reduced.

Method used

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  • Ceramic with light weight, high strength and high toughness and preparation method thereof
  • Ceramic with light weight, high strength and high toughness and preparation method thereof

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preparation example Construction

[0025] A kind of preparation method of light weight, high strength, high toughness ceramics of the present invention comprises the following steps:

[0026] Step 1, pre-sintering the ceramic hollow microsphere powder to improve the strength of the ceramic hollow microsphere powder;

[0027] Step 2, adding the above-mentioned pre-fired ceramic hollow microsphere powder to the ceramic powder, and adding relevant additives;

[0028] Step 3, select a forming process to form ceramics;

[0029] Step 4, drying the green body;

[0030] Step five, sintering the dried green body.

[0031] The ceramic hollow microsphere powder is pre-sintered. The sintering atmosphere is air or nitrogen. Different powder systems choose different sintering atmospheres. For example, silicon nitride hollow microspheres are pre-sintered in a nitrogen atmosphere, and alumina, zirconia, etc Other oxide ceramics can be pre-sintered in an air atmosphere.

[0032] Wherein, the ceramic hollow microsphere powde...

Embodiment 1

[0041] Example 1: Preparation of light, high-strength, high-toughness silicon nitride ceramic material

[0042] First, the silicon nitride hollow microsphere powder is pre-sintered. The sintering system is as follows: the temperature is raised at a rate of 10°C / min, the sintering temperature is 1600°C, and the sintering is carried out under a nitrogen atmosphere. The holding time at 1600°C is 0.5 hours. Dissolve monomer acrylamide and cross-linking agent N,N'-methylenebisacrylamide in water, the monomer concentration is 14.5%, the cross-linking agent concentration is 0.5%, to form a monomer premix, in the monomer premix Add 107.1g of silicon nitride powder to 80mL, add 2.99g of alumina powder as a sintering aid with a silicon nitride powder content of 2.5%, and 8.86g of yttrium oxide powder with a silicon nitride powder content of 7.5%, and a dispersant of alkaline water Agent 1.19g, silicon nitride hollow microsphere powder 11.9g, stir to obtain ceramic slurry, add the cataly...

Embodiment 2

[0043] Embodiment 2: Preparation of light weight, high strength, high toughness silicon nitride ceramic material

[0044] Add 11.9g of silicon nitride hollow microsphere powder, 2.99g of sintering aid alumina powder and 8.86g of yttrium oxide powder to 107.1g of silicon nitride powder, add alcohol and balls to wet mill for 24 hours, dry and sieve , adding 5% paraffin as a molding agent, pressing the elongated sample in a steel mold with a pressure of 120Mpa, and sintering after dewaxing. The bulk density, strength, fracture toughness and other properties of the sintered body are tested. The results show that the prepared silicon nitride ceramics have a bulk density of 3.2, a flexural strength of 550MPa, and a fracture toughness of 9MPa·m 1 / 2 .

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Abstract

The invention provides a ceramic with light weight, high strength and high toughness and a preparation method thereof. The method comprises the following steps: 1) presintering ceramic cenosphere powder to increase the strength of the ceramic cenosphere powder; 2) adding the presintered ceramic cenosphere powder in ceramic powder, adding the related additives; 3) selecting a moulding technology to mould the ceramic; 4) drying the obtained blank; and 5) sintering the dried blank. The invention provides the ceramic with light weight, high strength and high toughness and the preparation method thereof, wherein the ceramic cenosphere is a ceramic material toughened by the toughening body.

Description

technical field [0001] The invention relates to the field of inorganic non-metallic ceramics, in particular to a new method for preparing light-weight, high-strength and high-toughness ceramics. Background technique [0002] Due to the molecular arrangement and chemical bond properties of ceramic materials, the grain dislocation density in ceramic materials is low, the slip system is small, and the energy of crack nucleation and growth is small, thus determining the brittle nature of ceramic materials. Brittleness and low reliability severely limit the application range of ceramic materials. Only by improving the fracture toughness of ceramics, realizing the strengthening and toughening of materials, and improving their reliability and service life, can ceramic materials be widely used. Therefore, ceramic toughening technology has always been a hot spot in ceramic research. [0003] The essence of toughening is to introduce a mechanism to absorb fracture energy in the mater...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/622C04B35/626C04B35/64
Inventor 杨金龙蔡锴席小庆黄勇
Owner HEBEI YL BANGDA NEW MATERIALS LTD CO
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