Rubber seed oil-based epoxy fatty acid methyl ester and preparation method and application thereof
A technology of oil-based epoxy fatty acid methyl ester and fatty acid methyl ester, which is applied in the field of preparation of bio-based plasticizers, can solve problems such as insufficient effective utilization, achieve high-value development and utilization, simple preparation process, and environmentally friendly friendly effect
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[0027] The preparation method of the technical scheme specifically adopted by the present invention includes the following steps:
[0028] A two-step method was used to prepare the fatty acid methyl esters of rubber seed oil. Take 100g of rubber seed oil after degumming, mix it with 20-40g methanol and 0.8-1.2g catalyst, carry out the esterification reaction at a constant temperature of 60-80℃, and stop the reaction after the acid value drops below 2mg KOH / g When a solid catalyst is used, the catalyst is separated, and the excess methanol and water generated by the esterification reaction are removed by distillation under reduced pressure at 90°C. If a liquid catalyst is used, it is removed together with methanol, etc.; the resulting oil phase product is then added 10- 30g methanol and 0.8-1.2g catalyst, carry out the transesterification reaction at a constant temperature of 55-65°C for 2h, cool appropriately, and then distill under reduced pressure to 90°C, stand still for str...
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[0041] Example 1
[0042] A two-step method was used to prepare the fatty acid methyl esters of rubber seed oil. Take 100g of rubber seed oil after degumming, mix it with 20-40g methanol and 0.8-1.2g cation exchange resin catalyst, and carry out esterification reaction under constant temperature of 60-80℃, until the acid value drops to 2mg KOH / g After the following, stop the reaction, separate the catalyst, and distill at 90°C under reduced pressure to remove the excess methanol and the water generated by the esterification reaction; add 10-30g methanol and 0.8-1.2g catalyst to the resulting oil phase product, and add 10-30g methanol and 0.8-1.2g catalyst at 55-65 The transesterification reaction was carried out at a constant temperature of ℃ for 2h, and after proper cooling, it was distilled to 90 ℃ under reduced pressure, left standing for stratification, the lower layer of glycerol was recovered, and the crude fatty acid methyl ester of the upper layer was taken for use.
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[0046] Example 2
[0047] A two-step method was used to prepare the fatty acid methyl esters of rubber seed oil. Take 100g of the rubber seed oil after degumming, mix it with 20-40g methanol and 0.8-1.2g catalyst p-toluenesulfonic acid, and carry out the esterification reaction at a constant temperature of 60-80℃ until the acid value drops to 2mg KOH / g After the following, stop the reaction and distill under reduced pressure at 90°C to remove excess methanol, p-toluenesulfonic acid and moisture generated by the esterification reaction; add 10-30g methanol and 0.8-1.2g catalyst to the resulting oil phase product, and add 10-30g methanol and 0.8-1.2g catalyst at 55- The transesterification reaction was carried out at a constant temperature of 65°C for 2h, and after proper cooling, it was distilled to 90°C under reduced pressure, left standing for stratification, and the lower layer of glycerin was recovered, and the crude fatty acid methyl ester of the upper layer was taken for ...
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