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Surface preservative treatment method for aviation aluminium alloy material

An aluminum alloy material, anti-corrosion treatment technology, applied in the direction of metal material coating process, anti-corrosion coating, coating, etc., can solve the problem of no corrosion resistance, improve the interface bonding ability, improve the anti-corrosion performance, and enhance the anti-corrosion performance. Effects of Corrosive Properties

Inactive Publication Date: 2012-07-18
SHANGHAI JIAO TONG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] It has been described in the literature that 3%-5% organosiloxane sol can form a film with a dry film thickness of 200 to 500nm on the surface of the metal or its alloy. Adhesion between primer and paint, but not inherently corrosion resistant

Method used

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  • Surface preservative treatment method for aviation aluminium alloy material
  • Surface preservative treatment method for aviation aluminium alloy material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] 1. Preparation of sol solution

[0058] In the mixture of 895 milliliters of ethanol and 5 milliliters of acetic acid, add 25 milliliters of the aqueous solution of 0.1mg / milliliter graphene oxide, then add 25 milliliters of high-purity water, stir evenly for 15 minutes, add 40 milliliters of bis-(( 3-triethoxy) silylpropyl) tetrasulfide, after adding, stir for 10 seconds to 1 hour; then let it stand, the total time of stirring and standing is 30 minutes to 1.5 hours. Filter the sol solution with a slow quantitative filter paper in the laboratory, and transfer it to a clean container for airtight storage until use.

[0059] 2. The sol is applied to the base material

[0060] 2.1 Surface cleaning and activation of matrix materials:

[0061] Fully polish the sample with sandpaper, wash the surface of the sample with tap water and detergent; soak the sample with alkaline detergent at room temperature for 10 minutes to remove the grease on the surface of the sample, and ...

Embodiment 2

[0068] 1. Preparation of sol solution

[0069] In the mixture of 895 milliliters of ethanol and 5 milliliters of acetic acid, add 25 milliliters of the aqueous solution of 0.02 mg / ml graphene oxide, then add 25 milliliters of high-purity water and stir evenly for 15 minutes, while stirring, add 40 milliliters of bis-((3- Triethoxy) silylpropyl) tetrasulfide, after adding, stir for 10 seconds to 1 hour; then let it stand, the total time of stirring and standing is 30 minutes to 1.5 hours. Filter the sol solution with a slow quantitative filter paper in the laboratory, and transfer it to a clean container for airtight storage until use.

[0070] 2. The sol is applied to the base material

[0071] 2.1 Surface cleaning and activation of matrix materials:

[0072] Fully polish the sample with sandpaper, wash the surface of the sample with tap water and detergent; soak the sample with alkaline detergent at room temperature for 10 minutes to remove the grease on the surface of the ...

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Abstract

The invention discloses a method for forming one layer of sol-gel coating with a compact reticular crosslinking structure on the surface of the aviation aluminium alloy substrate material. The coating and an atom on the surface of the aluminium alloy substrate material can be firmly combined by the action of a chemical bond, and the coating has good adhesive force on the substrate material. In the method, graphene is added in a coating ingredient to participate in the crosslinking structure, and therefore the anti-corrosion capability of the coating is enhanced. The coating prepared by the method has strong anti-corrosion capability and adhesive force on the surface of aviation aluminium alloy. In addition, the coating has good chemical stability and thermal stability and can resist the influence on the coating because of an external acid and alkaline environment and temperature variation. The method is simple, is convenient to operate, has low requirement on equipment, is environmentally friendly and is free from pollution.

Description

technical field [0001] The invention relates to a method for treating the surface of a metal or metal alloy substrate, in particular to a method for carrying out anticorrosion treatment on the surface of aluminum and its alloy materials used in the aviation industry, and belongs to the technical field of surface treatment. Background technique [0002] Traditional surface treatment methods include anodic oxidation, chemical oxidation, electroplating and micro-arc oxidation. Among them, the chemical oxidation film prepared by the chemical oxidation method has the advantages of little influence on the fatigue properties of metal and metal alloy materials, simple process, low cost, fast formation speed, good adhesion, etc., and is often used as a primer and coating for metal and metal alloy spraying. pre-processing method. At present, the most commonly used chemical oxidation method is the chromate chemical oxidation method. After the metal and metal alloy are treated with chr...

Claims

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Application Information

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IPC IPC(8): C23C26/00C09D183/04C09D5/08C08G77/04
Inventor 苏跃增刘萍宋袁曾张怡吴松林易俊兰朱瑞鑫陈洁
Owner SHANGHAI JIAO TONG UNIV
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