Preparation method of copper-titanium-oxide mesomorphism material

A titanium oxide and mesogen technology is applied in the field of preparation of functional materials, which can solve the problems of low solar energy utilization efficiency and narrow spectral response range, and achieve the effects of adjustable energy band structure, low preparation cost and low impurity content.

Inactive Publication Date: 2012-08-15
BOHAI UNIV
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

But TiO 2 The forbidden band width (3.2eV) is wide, the spectral response range is narrow, and the absorption wavelength is mainly concentrated in the ultraviolet region (<387nm)
In the solar energy that reaches the ground, the energy in this band is less than 5%, while the proportion of visible light accounts for about 45% of solar energy, and the utilization efficiency of solar energy is low.

Method used

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  • Preparation method of copper-titanium-oxide mesomorphism material
  • Preparation method of copper-titanium-oxide mesomorphism material
  • Preparation method of copper-titanium-oxide mesomorphism material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Slowly add the mixed solution of copper chloride alcohol and water with a concentration of 0.1 mol / L to the mixed solution of tetrabutyl titanate alcohol and water with a concentration of 0.1 mol / L, and add octadecylamine during the mixing process. Wherein the mixed solution of alcohol and water is prepared by ethanol and water according to v:v=1:1, in the mol ratio of cupric chloride / tetrabutyl titanate=0.2:1, octadecylamine is 1% (mol) of cupric chloride ), stirred and reacted for 20 minutes with 70 rpm stirring speed. The obtained mixed solution was subjected to hydrothermal reaction, the hydrothermal reaction temperature was 180° C., and the hydrothermal reaction time was 24 hours. After the completion of the hydrothermal reaction, cool to room temperature naturally, filter and wash the product obtained by the reaction, put it in an oven, and dry it for 4 hours at 40°C to obtain Cu 2 O-TiO 2 mesogenic material ( figure 2 and image 3 ). Will Cu 2 O-TiO 2 Put...

Embodiment 2

[0039] Slowly add the mixed solution of copper nitrate alcohol and water with a concentration of 0.1 mol / L to the mixed solution of tetrabutyl titanate alcohol and water with a concentration of 0.1 mol / L, and add octadecylamine during the mixing process. Wherein the mixed solution of alcohol and water is prepared by ethanol and water according to v:v=1:1, in the mol ratio of copper nitrate / tetrabutyl titanate=0.2:1, octadecylamine is 1% (mol) of copper nitrate, The reaction was stirred at a stirring speed of 70 rpm for 20 minutes. The obtained mixed solution was subjected to hydrothermal reaction, the hydrothermal reaction temperature was 180° C., and the hydrothermal reaction time was 24 hours. After the completion of the hydrothermal reaction, cool to room temperature naturally, filter and wash the product obtained by the reaction, put it in an oven, and dry it for 4 hours at 40°C to obtain Cu 2 O-TiO 2 mesogenic material. Will Cu 2 O-TiO 2 Put the mesogenic material in...

Embodiment 3

[0042] Slowly add the mixed solution of copper nitrate alcohol and water with a concentration of 0.1 mol / L to the mixed solution of tetrabutyl titanate alcohol and water with a concentration of 0.1 mol / L, and add sodium lauryl sulfate during the mixing process. Wherein the mixed solution of alcohol and water is prepared by ethanol and water according to v: v=1: 1, in the mol ratio of copper nitrate / tetrabutyl titanate=0.2: 1, sodium lauryl sulfate is 2% of copper nitrate ( mol), stirred and reacted for 20 minutes with a stirring speed of 70 rev / min. The obtained mixed solution was subjected to hydrothermal reaction, the hydrothermal reaction temperature was 160° C., and the hydrothermal reaction time was 48 hours. After the completion of the hydrothermal reaction, cool down to room temperature naturally, filter and wash the product obtained by the reaction, put it in an oven, and dry it for 3 hours at 40°C to obtain Cu 2 O-TiO 2 mesogenic material. Will Cu 2 O-TiO 2 Put t...

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Abstract

The invention belongs to the technical field of function materials and relates to a preparation method of a copper-titanium-oxide mesomorphism material. The preparation method comprises the following steps of: uniformly dissolving soluble metallic copper slat and titanium salt in a mixed solution of alcohol/water according to a certain proportion, and adding a certain quantity of surfactant in the mixing process; performing hydrothermal reaction, filtering, washing, drying in the mixed solution of alcohol/water continually; and then performing thermal treatment in a muffle furnace to obtain the copper-titanium-oxide mesomorphism material. According to the preparation method, the technology is simple and convenient, the purity of the prepared material is high, the content of impurities is low, the preparation cost of the material is low, the performance of the material is excellent, and thus the material can be subjected to industrialized mass production. The copper-titanium-oxide mesomorphism material prepared by the method can serve as a photochemical catalyst responsive to visible light, and has wide application prospect in the fields of degradation of dyeing waste water and indoor harmful gas, photochemical catalysis disinfection and the like.

Description

technical field [0001] The invention belongs to the technical field of preparation of functional materials, and in particular relates to a preparation method of a copper-titanium oxide mesocrystalline material. Background technique [0002] Functional materials are a large class of materials with special electrical, magnetic, optical, acoustic, thermal, chemical and biological properties, and are important basic materials for high-tech fields such as information technology, biotechnology, energy technology and national defense construction. In recent years, the rapid development of mesocrystals has drawn more attention from chemists and physicists. Especially for materials chemists, mesogens offer new opportunities for materials design due to their microstructure (see H, Antonietti M. Mesocrystals and nonclassical crystallization, John Wiley & Sons, New York 2008.; Song R, H. Mesocrystals-ordered nanoparticle superstructures. Adv. Mater., 2010, 22, 1301-1330.). Mesogens...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/72C02F1/30C02F101/38
CPCY02W10/37
Inventor 许家胜张杰
Owner BOHAI UNIV
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