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UV (Ultraviolet) offset printing ink and preparation method thereof

An offset printing ink and resin technology, applied in the field of printing ink, can solve the problems of poor resin wetting and dispersing, insufficient ink thixotropy, limited drying speed, etc., and achieves excellent dot reproduction performance, good resin wetting and dispersing, The effect of low production cost

Active Publication Date: 2012-10-03
中山市中益油墨涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional UV offset printing inks have to take into account the wettability of pigments, so unsaturated polyester resins and epoxy acrylic resins are often used as the main resins. However, the drying speed of these resins is limited, the thixotropy of the ink is not enough, and the skeleton is not good, so it is difficult to adapt for high speed printing
There are also individual high-functional polyurethane acrylic resins used, but the cost is too high, and the wettability and dispersibility of the resin is not very good, so it is difficult to implement

Method used

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  • UV (Ultraviolet) offset printing ink and preparation method thereof
  • UV (Ultraviolet) offset printing ink and preparation method thereof
  • UV (Ultraviolet) offset printing ink and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4

[0029] One, raw material preparation: batching with the weight percentage of each component shown in table 1:

[0030] Table 1

[0031]

Example ①

Example ②

Example ③

Example ④

magenta

20

Phthalocyanine

20

benzidine yellow

20

black smoke

13

UV hyperbranched polyester acrylic resin

15

17

20

20

Pentaerythritol tetraacrylate UV resin

35

33

30

35

Photoinitiator 907

4

4

4

7

Photoinitiator 1173

3

3

3

3

Wetting and dispersing agent 7710

2

2

2

3

p-benzoquinone

1

1

1

1

calcium carbonate

8

8

8

6

silica

2

2

2

2

HDDA monomer diluent

10

10

10

10

[0032] Through the ring-opening polymerization of methyltetrahydrophthalic anhydri...

Embodiment 5~8

[0044] One, raw material preparation: batching with the weight percentage of each component shown in table 2:

[0045] Table 2

[0046]

Example 5

Example 6

Example 7

Example 8

magenta

20

Phthalocyanine

20

benzidine yellow

20

black smoke

15

UV hyperbranched polyester acrylic resin

20

17

15

15

epoxy acrylic resin

30

33

35

35

Photoinitiator 907

4

4

4

7

Photoinitiator 1173

3

3

3

3

Wetting and dispersing agent 7710

2

2

2

3

p-benzoquinone

1

1

1

1

calcium carbonate

8

8

8

6

silica

2

2

2

2

HDDA monomer diluent

10

10

10

13

[0047] Through the ring-opening polymerization of methyltetrahydrophthalic anhydride and glycidyl alc...

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PUM

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Abstract

The invention relates to UV (Ultraviolet) offset printing ink which comprises the following components by weight: 10-20% of pigment, 30-35% of polyester acrylic resin, 15-20% of UV highly-branched polyester acrylic resin, 10-20% of acrylic ester monomer, 5-10% of photoinitiator, 0.5-3% of polymerization inhibitor, 5-20% of filler and 0.2-3% of aid. A preparation method of the UV highly-branched polyester acrylic resin comprises the following steps: preparing UV highly-branched polyester through a ring opening polymerization reaction of methyl tetrahydrophthalic anhydride and glycidol by a one-step method, wherein the number average molar weight of the polyester is 1,500-2,500, and the branching degree is 0.45-0.72; and then modifying the UV highly-branched polyester by using methacrylic acid glycidyl ester to synthesize the highly-branched polyester acrylic resin. The invention aims to provide the UV offset printing ink which has the advantages of low cost, easy synthesis, good resin wetting dispersion and excellent branch reproduction performance and is suitable for high-speed printing.

Description

Technical field: [0001] The invention relates to the field of printing inks, in particular to a UV offset printing ink suitable for high-speed printing. Background technique: [0002] UV offset printing ink is based on the action of ultraviolet radiation, relying on the free radicals or cations formed after the photoinitiator absorbs the radiation energy, triggering the polymerization, crosslinking and grafting reactions of monomers and oligomers to form a crosslinked three-dimensional network structure. Drying and curing of high molecular polymers. Most UV offset printing inks are composed of epoxy acrylic resins, polyurethane acrylic resins, polyester acrylic resins, acrylate monomers, photoinitiators, fillers, and organic pigments. Due to the incomparable advantages of traditional oil-based inks, UV offset printing inks have attracted more and more attention from the printing industry, and are widely used in cigarette packs, wine packs, cosmetic packaging, pharmaceutical...

Claims

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Application Information

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IPC IPC(8): C09D11/10C09D11/101
Inventor 包勇
Owner 中山市中益油墨涂料有限公司
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