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Antiscale corrosion inhibitor for recycling reclaimed water and preparation method thereof

A technology of scale and corrosion inhibitors and reclaimed water, applied in chemical instruments and methods, descaling and water softening, complex/solubilizer treatment, etc., can solve the application scope and limit of the stabilizing effect of scale and corrosion inhibitors Value, easy to cause serious scaling, limit wastewater reuse and other issues, to achieve the effect of increasing the reuse rate, improving scale and corrosion inhibition performance, and reducing sewage discharge

Inactive Publication Date: 2012-10-17
北京盖雅技术中心有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main reason for restricting water reuse is that in the front-end treatment process of smelting wastewater, the traditional treatment method adopted is mainly the neutralization method, and a large amount of lime is added to achieve the purpose of neutralizing the acid wastewater and removing heavy metals by precipitation, so that the effluent after treatment The pH value, calcium ion and sulfate ion content are high, and it is easy to cause serious fouling during reuse, which seriously limits the reuse of this type of wastewater
At present, some enterprises passively prevent scaling by adding scale and corrosion inhibitors in the process of wastewater reuse, without considering the applicable range and limit value of the stabilizing effect of scale and corrosion inhibitors on calcium ions in wastewater. As the number of wastewater cycles increases, the antiscalant is prone to failure, and it is also likely to affect the production process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Scale and corrosion inhibitors for reuse of reclaimed water, by weight percentage, are prepared from the following components:

[0035] Phosphine-containing acrylic acid-acrylic acid ester-maleic acid multi-polymer copolymer 30%;

[0036] Phosphine-containing acrylic acid-acrylate-AMPS (2-acrylamido-methylpropanesulfonic acid) multi-polymer 35%;

[0037] Sodium gluconate 7%;

[0038] Benzotriazole 1%;

[0039] Sodium tungstate 1%;

[0040] Zinc sulfate 4%;

[0041] Water 22%.

[0042] Described phosphine-containing acrylic acid-acrylic acid ester-maleic acid multiple copolymer is in mass ratio: acrylic acid: acrylic acid ester: maleic acid is 3:1:5; Polymerization was carried out at a reaction temperature of 105°C.

[0043] The mass ratio of the phosphine-containing acrylic acid-acrylic acid ester-AMPS (2-acrylamide-methylpropanesulfonic acid) multi-polymer: acrylic acid: acrylate: AMPS is 5: 1.2: 3; Acrylic acid, acrylate, and AMPS are polymerized at a reaction ...

Embodiment 2

[0047] Scale and corrosion inhibitors for reuse of reclaimed water, by weight percentage, are prepared from the following components:

[0048] Phosphine-containing acrylic acid-acrylic acid ester-maleic acid multi-polymer copolymer 28%;

[0049] Phosphine-containing acrylic acid-acrylate-AMPS (2-acrylamido-methylpropanesulfonic acid) multi-polymer 32%;

[0050] Sodium gluconate 7%;

[0051] Benzotriazole 1.5%;

[0052] Sodium tungstate 1.5%;

[0053] Zinc sulfate 8%;

[0054] Water 22%.

[0055] Described phosphine-containing acrylic acid-acrylic acid ester-maleic acid multiple copolymer is in mass ratio: acrylic acid: acrylic acid ester: maleic acid is 3:1:5; Polymerization was carried out at a reaction temperature of 100°C.

[0056] The mass ratio of the phosphine-containing acrylic acid-acrylic acid ester-AMPS (2-acrylamide-methylpropanesulfonic acid) multi-polymer: acrylic acid: acrylate: AMPS is 5: 1.2: 3; Acrylic acid, acrylate, and AMPS were polymerized at a reac...

Embodiment 3

[0059] Scale and corrosion inhibitors for reuse of reclaimed water, by weight percentage, are prepared from the following components:

[0060] Phosphine-containing acrylic acid-acrylic acid ester-maleic acid multi-polymer copolymer 25%;

[0061] Phosphine-containing acrylic acid-acrylate-AMPS (2-acrylamido-methylpropanesulfonic acid) multi-polymer 30%;

[0062] Sodium gluconate 10%;

[0063] Benzotriazole 1.5%;

[0064] Sodium tungstate 1.5%;

[0065] Zinc sulfate 4%;

[0066] Water 28%.

[0067] Described phosphine-containing acrylic acid-acrylic acid ester-maleic acid multiple copolymer is in mass ratio: acrylic acid: acrylic acid ester: maleic acid is 3: 1: 5; Polymerization was carried out at a reaction temperature of 110°C.

[0068]The mass ratio of the phosphine-containing acrylic acid-acrylic acid ester-AMPS (2-acrylamide-methylpropanesulfonic acid) multi-polymer: acrylic acid: acrylate: AMPS is 5: 1.2: 3; Acrylic acid, acrylate, and AMPS are polymerized at a rea...

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PUM

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Abstract

The invention discloses an antiscale corrosion inhibitor for recycling reclaimed water and a preparation method thereof. The antiscale corrosion inhibitor for recycling reclaimed water is prepared from the following components in percentage by weight: 25-30% of phosphine-containing acrylic acid-acrylate-maleic acid multielement multipolymer, 30-35% of phosphine-containing acrylic acid-acrylate-AMPS (2-acrylamido-methylpropanesulfonic acid) multielement multipolymer, 7-10% of gluconate, 1-1.5% of azole, 1-1.5% of tungstate, 4-8% of zinc salt and 15-30% of water. The antiscale corrosion inhibitor for recycling reclaimed water is suitable for recycling high-hardness high-alkalinity reclaimed water in the representative smelting industry into an industrial circulation cooling water system, has favorable antiscale and corrosion inhibition properties, and can effectively prolong the operation cycle of production equipment, thereby creating beneficial conditions for the enterprise for saving the water resources, reducing the sewage discharge and protecting the environment.

Description

technical field [0001] The invention relates to the field of scale and dispersant agents, in particular to a scale and corrosion inhibitor for reuse of reclaimed water and a preparation method thereof. Background technique [0002] The water quality of smelting wastewater is complex, and the water quality is mostly acidic, containing heavy metals and other toxic substances in a high concentration, which seriously pollutes the environment. At present, the water reuse efficiency of existing domestic smelting enterprises is generally relatively low, and it is far lower than the average reuse level of industrial water in developed countries. The main reason for restricting water reuse is that in the front-end treatment process of smelting wastewater, the traditional treatment method adopted is mainly the neutralization method, and a large amount of lime is added to achieve the purpose of neutralizing the acid wastewater and removing heavy metals by precipitation, so that the eff...

Claims

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Application Information

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IPC IPC(8): C02F5/08C02F5/10C02F5/14C08F222/02C08F230/02C08F220/28C08F220/58
Inventor 付东康于亮吴绍祖吴广安
Owner 北京盖雅技术中心有限公司
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