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Preparation of single-component alkali-activated cement and application method thereof

An alkali-activated cement, single-component technology, applied in cement production, clinker production, etc., can solve the problems of high energy consumption of artificial slag, slag output that cannot meet the demand of cement, and unstable cement properties. The effect of reducing consumption, increasing gelling activity, and improving hydration gelling performance

Active Publication Date: 2014-06-18
HUNAN UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, slag is obtained by water quenching after melting at 1400-1600°C in the iron-making blast furnace. Artificial slag consumes a lot of energy, and the output of slag, a by-product of iron-making, cannot meet the demand for cement, and its composition changes with the needs of iron-making. When a large amount is added to prepare alkali slag cement, the properties of the cement will be unstable (Note: R-monovalent alkali metal oxide, M-divalent alkaline earth metal oxide, A-Al 2 o 3 , S-SiO 2 , C-CaO, H-H 2 O,N-Na 2 O)

Method used

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  • Preparation of single-component alkali-activated cement and application method thereof
  • Preparation of single-component alkali-activated cement and application method thereof

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Embodiment Construction

[0018] The present invention will be further described in detail below in conjunction with specific experimental examples. The equipment used in the embodiments of the present invention is conventional equipment, and the raw materials used are conventional raw materials.

[0019] Raw material 1 in the embodiment of the present invention is obtained by mixing three raw materials containing silicon-aluminum oxides, Pingxiang kaolin, Ningxiang kaolin and Linli bentonite, respectively, and calcareous raw materials. The chemical composition of the former is shown in Table 1; the calcium raw material is containing Ca(OH) 2 Up to 93% hydrated lime or CaCO 3 Up to 97% of Double Fly fans. Raw material 2 has 99%NaOH and 99%Na 2 CO 3 two kinds. Raw material 2 is dissolved in water to form a liquid slurry, and the raw material powder 1 that has been ball-milled to a particle size of 200 mesh sieve and less than 10% of the total mass is uniformly mixed into a slurry, and then calcined...

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Abstract

The invention belongs to the novel cement material field and specifically relates to the preparation of a single-component alkali-activated cement and an application method thereof, wherein a raw material 1 including SiO2, Al2O3, and CaO are mixed with the raw material 2 including Na2O in a certain ratio; the ratio should be decided so that the percentage of the weight of each component of the calcined product, which is obtained by calcining the mixed materials at a temperature greater than or equal to 1100 DEG C, in the total weight is as follows: Al2O3: 8-25%; SiO2: 24-55%; CaO: 10-55%; and Na2O +0.658K2O: 6-25%; after being calcined at a temperature ranging from 950-1200 DEG C for 1.5-3 h, the mixed materials are then ground to obtain cement powder; the cement powder is mixed with water into paste; next, the paste is cured at 50-80 DEG C for 2-3 days so that neat cement paste briquettes excellent in strength can be obtained; and the strength can be continuously increased if curing is continuously performed under normal temperature. The preparation of the single-component alkali-activated cement has the following advantages that: the raw material range of the alkali-activated cement is greatly expanded; the storage, transportation and utilization of the cement are more convenient; and the improvement of the cementitious activity of the cement and the reduction of the cost are expected to be realized.

Description

technical field [0001] The invention belongs to the field of new cement materials, and in particular relates to the preparation and application method of a single-component alkali-activated cement. Background technique [0002] In 2011, my country's cement output reached 2.063 billion tons, most of which were Portland cement. The calcination temperature of Portland cement reaches 1450°C, high energy and material consumption, high carbon emissions, serious environmental pollution, poor acid resistance, corrosion resistance and durability, and consumes a large amount of high-quality limestone resources, so its use should be gradually restricted and reduced. The development trend of cement requires wide sources of raw materials, high waste utilization, low energy consumption, low resource consumption, low pollution, low carbon emissions, and good durability and corrosion resistance. Alkali-activated cement, which has been actively studied recently, is a two-component cement co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/42C04B7/38
CPCY02P40/121
Inventor 彭美勋王正红董颖艳易亚王玲卢爱军陈勇申少华肖秋国
Owner HUNAN UNIV OF SCI & TECH
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