Cylindrical power lithium-ion battery and preparation method
A power battery and cylindrical technology, applied in the field of cylindrical lithium ion power battery and its preparation, can solve the problems of poor charge and discharge characteristics, cycle performance and safety performance, and achieve improved high-power charge and discharge characteristics and stable cycle performance. , good safety and reliability
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preparation example 1
[0047] 1) Preparation of positive electrode active material: The raw material LiNO 3 , Mn(CH 3 COO) 2 4H 2 O, Ni(CH 3 COO) 2 ·6H 2 O and Co(CH 3 COO) 2 4H 2 O is dissolved in absolute ethanol (an excess of 3% lithium salt is added to offset the loss of lithium at high temperature) to form a metal salt ethanol solution, and the lithium salt, nickel salt, manganese salt and cobalt salt in the metal salt ethanol solution The total concentration is 1mol / L.
[0048] Take 10mL metal salt ethanol solution and put it into a 100mL corundum crucible, put the corundum crucible into a box furnace preheated to 500°C, ignite, react vigorously in the air for 10 minutes, cool to room temperature 25°C, and obtain the preliminary The product, after grinding the preliminary product, put it into the box furnace again, annealed it at a high temperature of 800°C for 16 hours, and then cooled it to room temperature 25°C with the furnace to obtain the positive electrode active material.
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preparation example 2
[0052] 1) Preparation of positive electrode active material: The raw material LiNO 3 , Mn(NO 3 ) 2 ·6H 2 O, Ni(NO 3 ) 2 ·6H 2 O and Co(CH 3 COO) 2 4H 2 O is dissolved in absolute ethanol (an excess of 3% lithium salt is added to offset the loss of lithium at high temperature) to form a metal salt ethanol solution, and the lithium salt, nickel salt, manganese salt and cobalt salt in the metal salt ethanol solution The total concentration is 2mol / L.
[0053] Take 10mL metal salt ethanol solution and put it into a 100mL corundum crucible, put the corundum crucible into a box furnace preheated to 500°C, ignite, react vigorously in the air for 10 minutes, cool to room temperature 25°C, and obtain the preliminary The product, after grinding the preliminary product, put it into the box furnace again, annealed it at a high temperature of 800°C for 16 hours, and then cooled it to room temperature 25°C with the furnace to obtain the positive electrode active material.
[0054]...
preparation example 3
[0057] Preparation of negative electrode sheet with uncoated negative electrode active material coating on one side: Weigh 93% modified natural graphite (Shenzhen Bestray Electronic Materials Co., Ltd., model CG-8), 3% conductive agent (Cabot50 conductive carbon black) and 4% water-based binder (the volume ratio of sodium carboxymethyl cellulose: styrene-butadiene rubber (SBR-1500) is 1:1), to obtain a mixture, adding relative to the mixing After vacuum stirring with 60% deionized water of the weight of the material, it is continuously double-sided coated on the copper foil and left on the same side of the same side of the copper foil, and the part that is not coated with the negative electrode active material coating is left on one side, and dried Continuous roll pressing after deionized water; after slitting, a negative electrode sheet with an uncoated negative electrode active material coating on one side remains.
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