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Intelligent light adjusting film based on temperature-sensitive polymer hydrogel and preparation method of intelligent light adjusting film

An intelligent dimming and polymer technology, applied in the field of transparent roofs and solar heat collectors, can solve problems such as increased energy consumption and operation, difficult to achieve mechanical properties, irreversible turbidity of the membrane, etc., to reduce cooling energy consumption, low cost, full lighting effect

Inactive Publication Date: 2012-12-12
BEIJING INSTITUTE OF TECHNOLOGYGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the above-mentioned solid hydrogels reported as temperature-sensitive polymer carriers overcome the inherent shortcomings of liquid polymer solutions, they also have some shortcomings: for example, although the PVA system can impart high elasticity and toughness, the author has confirmed that PVA has a large Molecules are prone to crystallization and precipitation in low temperature environment, especially in winter, resulting in irreversible turbidity of the film; although xanthan gum, carrageenan or gellan gum can solidify the temperature-sensitive polymer solution, they only cross-link by physical action, and their mechanical The performance is difficult to meet the requirements of being used alone as a film; although agarose hydrogel has a certain strength, it is necessary to mix all the film-forming raw materials evenly in a high-temperature environment during the preparation process, and then transfer it to a mold to cool to form a film. Sensitive polymers are aggregated, and ultrasonic vibration is required to ensure their uniform dispersion, and the entire operation needs to be completed at high temperature, which undoubtedly increases energy consumption and cumbersome operation

Method used

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Experimental program
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Embodiment

[0034] Prepare the gel system according to the following formula. The listed values ​​are the percentages of various substances in the total system.

[0035] Temperature sensitive polymer PNIPA 1.0wt%;

[0036] Acrylamide AM 10wt%;

[0037] N,N’-methylenebisacrylamide BIS 0.4wt%;

[0038] Nano clay 1.0wt%;

[0039] Water 87.6wt%

[0040] 10wt% ammonium persulfate solution 260ppm (relative to the total weight of the above solution system)

[0041] 10wt% sodium bisulfite solution 260ppm (relative to the total weight of the above solution system)

[0042] Dissolve PNIPA, AM, BIS, and nano-clay in water according to the above formula at room temperature to prepare a transparent homogeneous solution. After nitrogen and deoxygenation, add 10wt% sodium bisulfite solution to the system and mix well , Then add ammonium persulfate solution with a concentration of 10wt%, mix it evenly and transfer it to the mold, seal it, and let it stand for polymerization at room temperature. Finally, a viscoelas...

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PUM

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Abstract

The invention discloses an intelligent light adjusting film and particularly discloses an intelligent light adjusting film based on a temperature-sensitive polymer hydrogel and a preparation method of the intelligent light adjusting film. A temperature-sensitive polymer and various auxiliaries are dissolved in a polymer hydrogel body without a temperature-sensitive effect to obtain the intelligent light adjusting film with a certain mechanical strength and good temperature sensitivity. The temperature-sensitive polymer, the various auxiliaries, a water-solubility monomer, a cross-linking agent and the like are prepared into an aqueous solution, an initiator is added into the aqueous solution to polymerize the solution to obtain the intelligent light adjusting film. The preparation method of the intelligent light adjusting film is simple in operation and low in cost and can be operated under room temperatures; and the obtained intelligent light adjusting film has certain strength and is good in temperature sensitivity.

Description

Technical field [0001] The invention relates to an intelligent dimming film capable of automatically adjusting light transmittance according to environmental temperature changes and a preparation method thereof, which can be applied to windows of buildings or vehicles, greenhouses or transparent roofs of certain architectural venues and Solar collectors. Background technique [0002] The effective daylighting of indoor spaces such as buildings and vehicles and solar collectors is one of the elements of human society's daily life and the development of a green and low-carbon economy. In recent years, as countries around the world pay more attention to green energy and low-carbon economy, the effective use of solar energy and the development of energy-saving and environmentally-friendly materials have received extensive attention. For buildings and vehicles, reasonable indoor lighting and window layout design can effectively avoid unnecessary power consumption (lighting and heatin...

Claims

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Application Information

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IPC IPC(8): C08J5/18C08F289/00C08F283/04C08F283/06C08F220/56C08F220/54C08F220/06C08F220/28C08F222/38C08F222/14
Inventor 王建全
Owner BEIJING INSTITUTE OF TECHNOLOGYGY
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