The invention provides a thermo-sensitive
condom based on waterborne
polyurethane and a preparation method thereof. The preparation method of the thermo-sensitive
condom comprises the following steps:(1) taking
polyester diol, low-molecular-weight polyether glycol and high-molecular-weight polyether glycol as soft segments, taking diisocyanate and a chain
extender as hard segments, carrying out aprepolymerization reaction, and carrying out a chain extension reaction, a cross-linking reaction and an emulsification process to obtain a
polyurethane aqueous
emulsion, wherein the number-average molecular weight of the low-molecular-weight polyether glycol is 400-1000, the number-average molecular weight of the high-molecular-weight polyether glycol is 2000-5000, and the use amount of the
polyester glycol accounts for not more than 5% of the total weight of solids in the aqueous
emulsion; and (2) subjecting the aqueous
polyurethane emulsion to dipping molding, hemming
drying and demoldingso as to obtain the thermo-sensitive
condom. The thermo-sensitive condom has the advantages of
low modulus, soft product, high somatosensory comfort, thorough
elimination of
foreign body sensation, excellent tensile strength, safety guarantee, and difficult damage.