Flame-retardant glass fiber reinforced PA6 (polyamide 6)/PPO (P-Polyphenylene Oxide) alloy material and preparation method thereof

A technology of alloy materials and glass fiber, which is applied in the field of PA6/PPO alloy materials, can solve the problems of unsuitable electricity environment, low CTI value and GWIT value, etc., achieve high tracking index, improve processing fluidity, and reduce friction The effect of the coefficient

Inactive Publication Date: 2013-03-13
SHANGHAI SUNNY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Some traditional methods are (GF+decabromodiphenylethane+antimony trioxide) compound system, (GF+brominated polystyrene+antimony trioxide) compound system, but the CTI value and GWIT of these compound systems The value is not high, not suitable for high-demand electricity environment

Method used

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  • Flame-retardant glass fiber reinforced PA6 (polyamide 6)/PPO (P-Polyphenylene Oxide) alloy material and preparation method thereof
  • Flame-retardant glass fiber reinforced PA6 (polyamide 6)/PPO (P-Polyphenylene Oxide) alloy material and preparation method thereof
  • Flame-retardant glass fiber reinforced PA6 (polyamide 6)/PPO (P-Polyphenylene Oxide) alloy material and preparation method thereof

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Effect test

Embodiment 3

[0029] A method for preparing environmentally friendly flame retardant glass fiber reinforced PA6 / PPO alloy material with high CTI value and high GWIT value, the method is as follows: Weigh raw materials according to weight ratio: PA6 23%, PPO 22%, compound flame retardant 20%, antimony trioxide 4.3%, glass fiber 20%, commercially available maleic anhydride grafted PPO 10%, antioxidant (1330) 0.1%, iron oxide 0.6%; put into high mixer and mix for 2 minutes, The material is discharged, and then extruded and granulated with a twin-screw extruder, the processing temperature is 240° C., and the screw rotation speed is 300 rpm.

[0030] The compound flame retardant is compounded by our company itself, and is composed of three components, and its mass percentage is BPS: 50%; magnesium hypophosphite: 25%; talcum powder: 25%.

Embodiment 4

[0032] A high CTI value, high GWIT value environmentally friendly flame retardant glass fiber reinforced PA6 / PPO alloy material preparation method, the method is as follows: Weigh raw materials according to weight ratio: PA6 46%, PPO 20%, compound flame retardant 6 %, antimony trioxide 3%, glass fiber 21%, commercially available maleic anhydride grafted PPO 2%, antioxidant (1330) 1%, iron oxide 1%; put into the high mixer and mix for 5 minutes, and the The material is then extruded and granulated with a twin-screw extruder, the processing temperature is 240° C., and the screw speed is 400 rpm.

[0033] The compound flame retardant is compounded by our company itself, and is composed of three components, and its mass percentage is BPS: 50%; magnesium hypophosphite: 25%; talcum powder: 25%.

[0034] The glass fiber is an alkali-free glass fiber, and the glass fiber is added into the silane coupling agent to make its surface treated with the silane coupling agent.

Embodiment 5

[0036] A high CTI value, high GWIT value environmentally friendly flame retardant glass fiber reinforced PA6 / PPO alloy material preparation method, the method is as follows: Weigh raw materials according to weight ratio: PA6 25%, PPO 41%, compound flame retardant 6 %, antimony trioxide 5%, glass fiber 20%, commercially available maleic anhydride grafted PPO 2%, antioxidant (1330) 0.5%, iron oxide 0.5%; The material is then extruded and granulated with a twin-screw extruder, the processing temperature is 240° C., and the screw speed is 350 rpm.

[0037] The compound flame retardant is compounded by our company itself, and is composed of three components, and its mass percentage is BPS: 50%; magnesium hypophosphite: 25%; talcum powder: 25%.

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Abstract

The invention relates to a flame-retardant glass fiber reinforced PA6 (polyamide 6)/PPO (P-Polyphenylene Oxide) alloy material and a preparation method thereof. The alloy material comprises the following components by weight percent: 23-41% of PA6, 22-41% of PPO, 6-20% of compound type flame retardant, 3-15% of antimonous oxide, 20-30% of glass fiber, 2-10% of compatilizer, 0.1-1% of antioxidant and 0.1-1% of oxidizing material. The raw materials are put into a high mixing machine to be mixed for 2-5min and then are discharged, and then a doubles-screw extruder is used for extruding and pelletizing so as to obtain the flame-retardant glass fiber reinforced PA6/PPO alloy material. Compared with the prior art, the flame-retardant glass fiber reinforced PA6/PPO alloy material has the advantages that being high in temperature of a glowing filament, environment-friendly, balanced in comprehensive properties, high in CTI (Comparative Tracking lndex) and GWIT (Glow-Wire Flammability Index), and the like.

Description

technical field [0001] The invention relates to a PA6 / PPO alloy material, in particular to an environmentally friendly flame-retardant glass fiber reinforced PA6 / PPO alloy material with a high CTI value and a high GWIT value and a preparation method thereof. Background technique [0002] Nylon (Nylon), Chinese name polyamide, English name Polyamide, is a general term for thermoplastic resins containing repeated amide groups -[NHCO]- on the main molecular chain. Its name is determined by the specific number of carbon atoms in the synthetic monomer, such as: nylon-6, 66, 1010, 610. It has high crystallinity and obvious melting point; it has high surface hardness, wear resistance, small friction coefficient, and self-lubrication and noise reduction. It has good low temperature performance and certain heat resistance (it can be used below 100 degrees). Non-toxic, odorless, non-mildew, self-extinguishing, good weather resistance, but poor dyeing. PPO is one of the five general...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L71/12C08K13/04C08K7/14C08K3/22C08K3/32C08K3/34B29C47/92B29C48/92
CPCB29B7/46B29B7/72B29B7/7461B29B7/90B29B9/06B29B9/12B29B9/14B29C48/04B29C48/40B29C48/92C08K3/2279C08K3/34C08K7/14C08L51/08C08L71/12C08L77/02C08L2205/03C09K21/14
Inventor 郭建鹏娄小安
Owner SHANGHAI SUNNY
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