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A metal antirust paint containing modified nano-scale titanium dioxide and its preparation method

A titanium dioxide and metal anti-rust technology, applied in chemical instruments and methods, dyed organosilicon compound treatment, anti-corrosion coatings, etc. Low, increase corrosion resistance and heat resistance, good adhesion effect

Inactive Publication Date: 2015-07-29
NANTONG ZHENGDA AGROCHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In recent years, epoxy zinc-rich paint is the most commonly used industrial anti-rust paint to protect metal. Due to the relatively high density of metal zinc powder, in order not to To settle or slow down the settling speed of zinc powder, it is necessary to add a certain amount of anti-settling agent to the paint; the viscosity of the paint will also increase when the anti-settling agent is added. When selecting polyamide resin, it is necessary to choose as small a Molecular weight resin (E44); in order to meet the brushability during construction, a large amount of solvent should be added to the paint. During construction, the solvent seriously endangers the health of workers, and the solvent volatilizes into the air during the drying process to pollute the environment. The construction cost is increased; the brittleness of the paint film after the curing of the small molecular weight resin is large, and the thermal expansion and contraction of the metal is large, and the paint film is easy to crack or fall off when the temperature changes

Method used

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Examples

Experimental program
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Effect test

Embodiment

[0014] Example: Metal antirust paint containing modified nano-scale titanium dioxide, the weight parts of its raw materials are: polyamide resin 35, polytetrafluoroethylene resin 20, modified nano-clay 27, zirconium fluoride 11, sodium polyacrylate 5, decane Base amine 1.3, polycaprolactone 15, dimethyl silicone oil 0.6, poly-4-methyl-1-pentene 0.5, octadecyl succinic acid 0.35, salicylic acid 0.3, oxidizing agent 1010 1. Modification Nanoscale titanium dioxide 3, polyacrylic acid 0.8, bis(dioctyloxypyrophosphate) ethylene titanate 0.5 and polyethylene wax 1.7.

[0015] The preparation method of the metal antirust paint containing modified nano-scale titanium dioxide comprises the following steps:

[0016] (1) Mix and stir polyamide resin, polytetrafluoroethylene resin, modified nano-clay, zirconium fluoride, modified nano-scale titanium dioxide and polyethylene wax according to the weight of the raw materials, disperse at high speed and grind to a fineness of 35um the follo...

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PUM

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Abstract

The invention discloses a metal antirust paint containing modified nano-TiO2, and its preparation method. The metal antirust paint comprises the following raw materials, by weight, 33-38 parts of a polyamide resin, 18-22 parts of a polytetrafluoroethylene resin, 25-28 parts of modified nanometer argil, 10-12 parts of zirconium fluoride, 4-6 parts of sodium polyacrylate, 1.2-15 parts of decylamine, 12-18 parts of polycaprolactone, 0.5-0.7 parts of dimethyl silicone oil, 0.4-0.6 parts of poly-4-methyl-1-pentene, 0.2-0.5 parts of octadecylsuccinic acid, 0.2-0.4 parts of salicylic acid, 0.8-1.2 parts of an oxidant 1010, 2-4 parts of the modified nano-TiO2, 0.5-1.0 part of polyacrylic acid, 0.4-0.6 parts of bis(P,P-bis-ethylhexyl diphosphato)ethanediolato titanate and 1.5-1.8 parts of polyethylene wax. The film of the metal antirust paint has the advantages of good adhesion, fast drying, good heat resistance, environmental protection and no pollution, and the modified nanometer argil and the modified nano-TiO2 which are added to the raw materials improve the excellent performances of high-polymer materials in the raw materials and simultaneously increase the corrosion and heat resistances of the metal antirust paint, and the preparation method has the advantages of simplicity, low cost and suitableness for large-scale production.

Description

technical field [0001] The invention relates to a metal antirust paint containing modified nano-level titanium dioxide and a preparation method thereof, belonging to the technical field of antirust materials. Background technique [0002] In recent years, epoxy zinc-rich paint is the most used industrial anti-rust paint to protect metal. Due to the relatively high density of metal zinc powder, in order to prevent the zinc powder from settling or slow down the settling speed of the zinc powder, it is necessary to add A certain amount of anti-settling agent; the viscosity of the paint will also increase when the anti-settling agent is added. When selecting polyamide resin, it is necessary to choose a resin with a small molecular weight (E44) as much as possible; in order to meet the brushability during construction , to add a large amount of solvent to the paint, the solvent seriously endangers the health of workers during construction, the solvent volatilizes into the air du...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D177/00C09D127/18C09D5/08C09D7/12C09C1/36C09C1/42C09C3/12C09C3/06C09C3/00
Inventor 肖颖张蔓青
Owner NANTONG ZHENGDA AGROCHEM