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Technology for preparing sulfuric acid

A kind of process, sulfuric acid technology, applied in the direction of sustainable manufacturing/processing, sulfur compounds, chemical industry, etc., can solve the problems of imperfection, poor quality, low sulfur purity, etc., and achieve the effect of solving environmental protection problems

Inactive Publication Date: 2013-05-01
ACRE COKING & REFRACTORY ENG CONSULTING CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the desulfurization process is still not perfect: first, the product sulfur produced after desulfurization has low purity and poor quality, and is difficult to sell; second, the waste liquid generated during the desulfurization process lacks a relatively complete treatment process, which is likely to cause new environmental pollution

Method used

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  • Technology for preparing sulfuric acid
  • Technology for preparing sulfuric acid
  • Technology for preparing sulfuric acid

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Embodiment Construction

[0017] Specific embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings.

[0018] A process for producing sulfuric acid, which uses low-quality sulfur generated after wet oxidation desulfurization of coke oven gas and salt waste liquid containing sulfur as raw materials, through incineration, waste heat recovery, wet purification, wet contact conversion, condensation Acid-forming process to produce concentrated sulfuric acid.

[0019] 1. Sulfur and waste liquid incineration process

[0020] Use a pump to send the slurry formed by mixing the sulfur generated by the wet oxidative desulfurization of coke oven gas and the salt waste liquid containing sulfur to the nozzle of the incinerator, atomize it with compressed air, and send it into the incinerator, where the combustion air and Fuel gas and raw material slurry are incinerated in two stages at a temperature of about 1000-1200 ℃, one stage is for good combustion, an...

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Abstract

The invention relates to a technology for preparing sulfuric acid, in particular to a technology for preparing sulfuric acid by taking low-quality sulfur and a waste salt liquid containing sulfur that are generated by a coke oven gas wet oxidation desulfurization technology which takes ammonia as an alkali source and takes quinone, cobalt and ferrum compositions such as HPF as catalysts as raw materials, and through processes of incineration, waste heat recovery, wet purification, wet contact method conversion, and condensation into acid. The technology thoroughly solves the problem of treatment of a waste desulfurization liquid and low-quality sulfur that are generated by the coke oven gas wet oxidation desulfurization technology which takes the quinone, cobalt and ferrum compositions such as HPF, PDS and ZL as the catalysts, so that the desulfurization technology is completed; produced sulfuric acid can serve as a raw material for deamination of coal gas of a factory, and for production of ammonium sulfate, can be exported as sulfuric acid goods; and double purposes of resource recycle and environmental protection are achieved.

Description

technical field [0001] The invention relates to a process for producing sulfuric acid, especially the low-quality sulfur and sulfur-containing sulfur produced by the coke oven gas wet oxidation desulfurization process using ammonia as the alkali source and HPF and other quinone, cobalt, and iron compositions as catalysts. The salt waste liquid is used as raw material, and sulfuric acid is produced through incineration, waste heat recovery, wet purification, wet contact conversion and condensation into acid. Background technique [0002] Hydrogen sulfide contained in gas is a harmful substance. When undesulfurized gas is used for steelmaking and civil use, it will not only reduce the quality of steel, but also the sulfur dioxide produced by combustion will damage the environment and affect human health. Therefore, in order to meet the needs of the metallurgical industry and reduce the pollution to the atmosphere after gas combustion, it is necessary to remove the hydrogen su...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B17/775
CPCY02P20/129Y02P20/10
Inventor 白玮戴成武蔡承祐于义林张素利吕成苑松柏刘卓
Owner ACRE COKING & REFRACTORY ENG CONSULTING CORP
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