Preparation method of hydrocracking catalyst

A hydrocracking and catalyst technology, applied in physical/chemical process catalysts, molecular sieve catalysts, chemical instruments and methods, etc., can solve the problems of limited metal content in the preparation of catalysts, low effective utilization of active metals, and limited catalyst pore structure, etc. Achieve the effect of weakening capillary resistance, reducing pore size and specific surface area, and stable properties

Active Publication Date: 2013-05-15
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Through the above analysis, the impregnation method can be used to prepare the catalyst, which can give full play to the performance of the hydrogenation metal, but the metal content of the catalyst is greatly limited; although the co-precipitation method can prepare a hydrogenation catalyst with a high metal content, the utilization of the metal The rate is not high, and the pore structure of the catalyst is also limited
The kneading method can also prepare catalysts with various active metal contents, but the performance of the catalyst prepared by the kneading method is relatively poor, the effective utilization rate of the active metal is low, and the hydrogenation catalyst is rarely prepared by the kneading method in industrial production.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Taking the tungsten-nickel system as an example, the preparation of the catalyst is carried out.

[0037] Prepare a metal impregnation solution, in which the concentration of metal is 25.6g metal (calculated as oxide) / 100mL solution, the concentration of ammonium citrate is 4g / 100mL solution, the impregnation temperature is 30°C, and the liquid-solid ratio is 6mL solution / g powder, Immerse the mixed powder of 66 grams of silicon-modified alumina and 200 grams of Y-1 molecular sieve for 2.5 hours, and dry at 120°C for 8 hours, and pulverize into 180 meshes to obtain a mixed material containing metal components (dry base is 76.6wt%).

[0038] Take 370 grams of the above-mentioned metal-containing component mixture and 259 grams of binder (5.8wt% on a dry basis, the molar ratio of nitric acid to small-pore alumina is 0.5) and put them into a roller compactor for mixing and rolling to form a paste. Extrude into a cylinder with a diameter of 1.8 mm. After drying at 120°C f...

Embodiment 2

[0040] Taking the tungsten-nickel system as an example, the preparation of the catalyst is carried out.

[0041] Prepare a metal impregnation solution, in which the metal concentration is 25.6g metal (calculated as oxide) / 100mL solution, the ammonium citrate concentration is 6g / 100mL solution, the immersion temperature is 30°C, and the liquid-solid ratio is 6mL solution / g powder, Immerse the mixed powder of 66 grams of silicon-modified alumina and 200 grams of Y-2 molecular sieves for 2.5 hours, and dry at 120°C for 8 hours, and pulverize into 180 meshes to obtain a mixed material containing metal components (dry base is 76.6wt%).

[0042] Take 370 grams of the above-mentioned metal-containing component mixture and 259 grams of binder (5.8wt% on a dry basis, the molar ratio of nitric acid to small-pore alumina is 0.5) and put them into a roller compactor for mixing and rolling to form a paste. Extrude into a cylinder with a diameter of 1.8 mm. After drying at 120°C for 5 hou...

Embodiment 3

[0044] Taking the tungsten-nickel system as an example, the preparation of the catalyst is carried out.

[0045] Prepare a metal impregnation solution, wherein the metal concentration is 27.2g metal (calculated as oxide) / 100mL solution, the ammonium citrate concentration is 8g / 100mL solution, the immersion temperature is 40°C, and the liquid-solid ratio is 8mL solution / g powder, Immerse the mixed powder of 133 grams of silicon-modified alumina and 134 grams of Y-1 molecular sieves for 4 hours, and dry at 120°C for 8 hours, and pulverize into 180 meshes to obtain a mixed material containing metal components (dry base is 75.1wt%).

[0046] Take 380 grams of the above-mentioned metal-containing component mixture and 259 grams of binder (5.8wt% on a dry basis, the molar ratio of nitric acid to small-pore alumina is 0.5) and put them into a roller compactor for mixing and grinding to form a paste. Extrude into a cylinder with a diameter of 1.8 mm. After drying at 120°C for 5 hour...

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Abstract

The invention discloses a preparation method of a hydrocracking catalyst. The method comprises: first selecting a solution containing a hydrogenation active metal and an organic reagent to dip mixed powder of a molecular sieve and alumina, conducting drying, then subjecting the obtained material and a peptizing agent or a binder together to rolling, molding, drying and roasting, thus obtaining the catalyst. Only through one time high temperature roasting can the catalyst product be obtained. The preparation method is simple, and the preparation cost is obviously reduced. In addition, the hydrogenation activity center and the cracking activity center of the catalyst coordinate, so that the catalyst has very high catalytic activity. Also with a large specific surface area and pore volume, the hydrocracking catalyst is more suitable for a catalytic process of treating high dry point inferior vacuum distillate oil by hydrocracking for high production of naphtha.

Description

technical field [0001] The invention relates to a method for preparing a hydrocracking catalyst, in particular to a method for preparing a hydrocracking catalyst suitable for processing inferior raw materials and having high activity and high naphtha production. Background technique [0002] Hydrocracking technology has the characteristics of strong adaptability of raw materials, great flexibility of product schemes, high selectivity of target products, good product quality, and high added value. It can directly convert various heavy and low-quality raw materials into clean fuel oil and high-quality chemical raw materials , has become one of the most important heavy oil deep processing processes in modern oil refining and petrochemical industries, and has been increasingly widely used. As the quality of crude oil is deteriorating year by year, the import of high-sulfur crude oil has increased significantly, environmental protection has increasingly stringent requirements on ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/16C10G47/20
Inventor 刘昶王凤来杜艳泽赵红关明华
Owner CHINA PETROLEUM & CHEM CORP
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