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A kind of large proportion methanol gasoline catalyst and its preparation method

A methanol gasoline and catalyst technology, which is applied in the petroleum industry, fuel additives, liquid carbon-containing fuels, etc., can solve the problems of metal corrosion and rubber swelling, restricting the development of methanol gasoline, and small replacement ratio, and achieves overcoming high temperature non-air resistance, Overcome swelling and metal corrosion problems, clean exhaust emissions

Inactive Publication Date: 2016-05-18
杨军
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Methanol gasoline has a high octane number, is clean and environmentally friendly, and has good combustibility. It is the best alternative energy source for gasoline. However, there are still technical problems such as small replacement ratio, poor stability, moisture stratification, metal corrosion and rubber swelling, which restrict the use of methanol gasoline. Development, in which the substitution ratio and stability are key issues, including the compatibility of methanol and gasoline, water resistance and low temperature stability, etc.

Method used

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  • A kind of large proportion methanol gasoline catalyst and its preparation method
  • A kind of large proportion methanol gasoline catalyst and its preparation method
  • A kind of large proportion methanol gasoline catalyst and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A kind of large-scale methanol gasoline catalyst, its volume percent composition is as follows:

[0041] A. Mutual solvent: 20-40% (isopropanol, n-butanol)

[0042] B. Combustion catalyst: 10-20% carbon 5 (C 5 h 12 )

[0043] C. Calorific value enhancer: 10-20% (isopropanolamine)

[0044] D. Core complex agent: 25-30% (diphosphate, dimethyl carbonate)

[0045] E. Antioxidant anti-adhesive agent: 1~5% (T-501)

[0046] F. Metal passivation agent: 1~5% (T1201)

[0047] G. Vapor pressure regulator: 1-5% (cyclohexane)

[0048] H. Rubber swelling inhibitor: 0.1~0.5%

[0049] Preparation method of the present invention:

[0050] (1) First, the diphosphate solution and the dimethyl carbonate solution are mixed in a primary mixer in a ratio of 1:1 and then mixed with isopropanol and n-butanol in an equal ratio of 1:1;

[0051] (2) carbon 5 (C 5 h 12 ) into the primary mixer;

[0052] (3) isopropanolamine is added in the primary mixer;

[0053] (4) Add T-50 in the pr...

Embodiment 2

[0059] A kind of large-scale methanol gasoline catalyst, its volume percent composition is as follows:

[0060] A. Mutual solvent: 20-40% (isopropanol, cyclohexanol)

[0061] B. Combustion catalyst: 10-20% carbon 6 (C 6 h 14 )

[0062] C. Calorific value enhancer: 10-20% (methylaniline, o-toluidine)

[0063] D. Core compounding agent: 25-30% (methyl tert-amyl ether, diisopropyl ether)

[0064] E. Antioxidant anti-adhesive agent: 1~5% (T-501)

[0065] F. Metal passivation agent: 1~5% (T1201)

[0066] G. Vapor pressure regulator: 1-5% (methyl propionate)

[0067] H. Rubber swelling inhibitor: 0.1~0.5%

[0068] Preparation method of the present invention:

[0069] (1) First, the methyl tert-amyl ether solution and the diisopropyl ether solution are mixed in a primary mixer in a ratio of 1:1 and then mixed with isopropanol and cyclohexanol in an equal ratio of 1:1;

[0070] (2) carbon 6 (C 6 h 14 ) into the primary mixer;

[0071] (3) Add methylaniline and o-toluidine ...

Embodiment 3

[0078] A kind of large-scale methanol gasoline catalyst, its volume percent composition is as follows:

[0079] A. Mutual solvent: 20-40% (isopropanol, undecyl alcohol)

[0080] B. Combustion catalyst: 10-20% carbon 8 (C 8 h 18 )

[0081] C. Calorific value enhancer: 10-20% (tetrahydrofuran)

[0082] D. Core complex agent: 25-30% (dimethyl malonate, methylene dimethyl ether)

[0083] E. Antioxidant anti-adhesive agent: 1~5% (T-501)

[0084] F. Metal passivation agent: 1~5% (T1201)

[0085] G. Vapor pressure regulator: 1 to 5% (ethylene glycol monomethyl ether)

[0086] H. Rubber swelling inhibitor: 0.1~0.5%

[0087] Preparation method of the present invention:

[0088] (1) First, the dimethyl malonate solution and the methylene dimethyl ether solution are mixed in a primary mixer in a ratio of 1:1, and then mixed with isopropanol and undecyl alcohol in an equal ratio of 1:1;

[0089] (2) carbon 8 (C 8 h 18 ) into the primary mixer;

[0090] (3) tetrahydrofuran is a...

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Abstract

The invention provides a large-proportion methanol gasoline catalyst and a preparation method thereof. A product mark of the large-proportion methanol gasoline can be expressed by M50 and M85, wherein M represents a first letter of methanol; 50 and 85 respectively represent 50% of methanol and 85% of methanol are added in the gasoline The large-proportion methanol gasoline catalyst is obtained by mixing refined methanol with a purity of 99.9% and national standard gasoline or naphtha and component oil in presence of a special catalyst. A preparation method of the special catalyst is composed of high alcohols (C3-C11), alkanes (C5(C5H12), C6(C6H14), C7(C7H16), C8(C8H18) or CH3NO2), an organic amine, a plurality of esters and auxiliary inhibitors. The large-proportion methanol gasoline produced by the invention passes through a road test longer than 10,000 KM, without changing an engine structure. The large-proportion methanol gasoline is powerful, can be easily started at a low temperature, has no gas block at a high temperature, is not stratified when being contacted with water, can resist rubber swelling, and is low in production cost and flexible in operations. Besides, all project technical indicators are superior to those of national standard gasoline for vehicles. Practice proves that the large-proportion methanol gasoline catalyst has the advantages in a plurality of aspects such as technology, economy, feasibility for large-scale application, and the like, and has obvious competitive advantages as alternative energy.

Description

technical field [0001] The invention relates to an alternative energy source for vehicles, and more specifically, belongs to a large-proportion methanol-gasoline additive and a preparation method thereof. Background technique [0002] Since the emergence of the second oil crisis in the 1970s, many scholars and entrepreneurs around the world have conducted extensive trial research on methanol gasoline, an alternative fuel for vehicles. The United States, Germany, Japan, Sweden and other countries have developed methanol gasoline And applications have given a lot of financial support and policy preference. my country has actively developed methanol gasoline since the 1980s, and has entered the promotion and practical stage of M15-M30. The world is about to enter the post-oil era. According to the predictions of the U.S. Department of Energy and the World Energy Council, the global petroleum energy can be exploited for more than 30 years, and China's exploitable life is less t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L1/26C10L1/16C10L1/223C10L1/02C10L10/04C10L10/00
Inventor 杨军
Owner 杨军
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