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Extracting method of D-xylose and L-arabinose

An extraction method, the technology of arabinose, applied in the field of functional sugar preparation, can solve the problems of reducing the crystallization yield of D-xylose, high water consumption and resin consumption, and long hydrolysis cycle, so as to improve the quality and crystallization yield, equipment The effect of reduced investment and short cycle

Active Publication Date: 2013-07-10
FUTASTE PHARM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The existing D-xylose extraction process is mainly acid hydrolysis of hemicellulose in agricultural and forestry wastes to obtain xylose hydrolyzate, which has the following disadvantages: (1) acid solution and sugar solution are mixed together, resulting in high acid consumption; (2 ) needs to be neutralized with an additional alkali, and the acid salt is removed by means of ion exchange. The burden of separation is heavy, resulting in high water consumption and resin consumption; (3) The hydrolysis temperature is 120°C, and the hydrolysis time is 120 minutes , the cycle of hydrolysis is longer, and the efficiency of hydrolysis is lower; (4) Since the temperature of the acid solution and the material must be raised at the same time when the temperature of the hydrolysis is raised, the steam consumption is very high
(5) The process of extracting D-xylose first and then extracting L-arabinose in the mother liquor reduces the crystallization yield of D-xylose, and the process is cumbersome and inefficient

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Take 200g of corn cobs with a size of about 1 cm square, put them into a 2L beaker, add 1500ml of oxalic acid 0.9% by weight, soak at room temperature for 17 hours, and separate the corn cobs from the acid solution with a filter bag , the water content of the obtained acidified corn cob is about 46% of its dry weight, and the separated acid solution can be reused;

[0027] (2) Put the obtained acidified corncobs into the prepared intermittent steam explosion equipment, boost the steam pressure to 1.2Mpa, keep the pressure for 5 minutes, open the discharge solenoid valve, and discharge the material steam explosion by the high pressure inside the system;

[0028] (3) Add water equivalent to 10 times its dry weight to the obtained steam-exploded corncob mud, stir at 80°C for 60 minutes, and obtain 1820ml of extract by suction filtration; put the obtained filter residue into a beaker, and then add equivalent Carry out secondary extraction in the water of 5 times of ...

Embodiment 2

[0031] (1) Take 200g of ground bagasse, put it into a 2L beaker, add 1500ml of sulfuric acid 0.1% by weight, soak it at 70°C for 0.3h, and separate the corn cob from the acid solution with a filter bag to obtain The water content of acidified bagasse is about 40% of its dry weight, and the separated acid can be reused;

[0032] (2) Put the obtained acidified bagasse into the prepared intermittent steam explosion equipment, boost the steam pressure to 0.6Mpa, keep the pressure for 20 minutes, open the discharge solenoid valve, and discharge the material steam explosion by the high pressure inside the system;

[0033] (3) Add water equivalent to 15 times its dry weight to the obtained steam-exploded bagasse mud, stir and extract at 80°C for 20 minutes, and obtain 1460ml of extract by suction filtration; put the obtained filter residue into a beaker, and then Add water equivalent to 3 times its dry weight for secondary extraction. During continuous production, this extraction...

Embodiment 3

[0036] (1) Take 200g of cane pith, put it into a 2L beaker, add 1500ml of sulfuric acid 1.0% by weight, soak it at 20°C for 20h, separate the cane pith from the acid solution with a filter bag, and obtain the acidified cane pith The water content is about 80% of its dry weight, and the separated acid can be reused;

[0037] (2) Put the obtained acidified cane pith into the prepared intermittent steam explosion equipment, boost the steam pressure to 0.6Mpa, keep the pressure for 3 minutes, open the discharge solenoid valve, and discharge the material by steam explosion by the high pressure inside the system;

[0038] (3) Add water equivalent to 5 times its dry weight to the obtained steam-exploded sugarcane pith mud, stir and extract at 20°C for 80 minutes, and obtain 1000ml of extract by suction filtration; put the obtained filter residue into a beaker, and then Add water equivalent to 6 times its dry weight for secondary extraction. During continuous production, this extr...

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PUM

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Abstract

The invention provides an extracting process of D-xylose and L-arabinose. The extracting process comprises the following steps of: acidizing forestry and agricultural residues, carrying out steam explosion on the acidized forestry and agricultural residues to obtain the forestry and agricultural residues subjected to steam explosion, and finally carrying out aqueous extraction, separation and crystallization to obtain the D-xylose and L-arabinose. According to the technical scheme of the invention, the extracting method has the following advantages that an acid solution is recycled, and therefore the acid consumption is reduced; as the acid in an extracting solution is low in content, the load of a later-peroid purifying treatment is lightened; the peroid is short, continuous steam explosion production can be achieved, and the equipment investment is reduced when the capacity is unchanged; steam is not heated together with the acid solution in the boosting process, so that the steam consumption is greatly reduced, and energy sources are saved; and as the process of separating the D-xylose and the L-arabinose first and then respectively crystallizing is adopted, the purity of massecuite during crystallization of the D-xylose is improved, and the quality and crystallization yield of the D-xylose are improved.

Description

technical field [0001] The invention belongs to the technical field of functional sugar preparation, in particular to a method for extracting xylose and arabinose. Background technique [0002] D-xylose has the function of promoting the growth of bifidobacteria and intestinal peristalsis. It has been used as a food ingredient in Japan for decades and is an excellent representative of functional sugar. It can also be directly used as a healthy coloring agent in the baking industry, and is also a raw material for the production of xylitol. At present, although the existing xylose production process has been improved, it generally continues the technology of the former Soviet Union in the 1950s. [0003] L-arabinose has the function of inhibiting the absorption of sucrose and is a healthy food ingredient for weight management. It was selected into the list of new resource foods by the Ministry of Health in 2008 and is a star product among functional sugars. L-arabinose is a b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07H3/02C07H1/00C07H1/06
Inventor 李雨邱学良高永旭秦海青梁莉曹玉华
Owner FUTASTE PHARM CO LTD
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