Acrylate copolymer emulsion paper-plastic composite adhesive and manufacturing method thereof

A technology of acrylate and copolymer emulsion, which is applied in the direction of ester copolymer adhesive, adhesive type, etc., can solve the problems of inability to combine ink with BOPP film, weak adhesion, slow drying speed, etc., and achieve production The process is simple and stable, the mechanical adaptability is good, and the latex particle size is small.

Active Publication Date: 2013-08-14
海南赛高新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, both at home and abroad are committed to the research and development of acrylic acid copolymer emulsions, but the emulsion composite films currently on the market still have poor stability, weak cohesive force, slow drying speed, low transparency, and cannot make the ink and BOPP film very compatible in application. good combination of shortcomings

Method used

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  • Acrylate copolymer emulsion paper-plastic composite adhesive and manufacturing method thereof
  • Acrylate copolymer emulsion paper-plastic composite adhesive and manufacturing method thereof
  • Acrylate copolymer emulsion paper-plastic composite adhesive and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Prepared according to the following weight ratio of raw materials (%):

[0029]

[0030] (1) Washing and pre-emulsification of monomers: Add 200kg of butyl acrylate, 80kg of acrylic acid, 50kg of methyl methacrylate, 30kg of acrylonitrile, 50kg of itaconic acid, and 150kg of deionized water into the pre-emulsification device, decompressed distillation to remove the polymerization inhibitor, and washed with 2kg of 10% sodium hydroxide solution, started stirring for 30min, the appearance of the mixed solution was uniform milky white, stopped stirring, and obtained pre-emulsion A.

[0031] (2) Preparation of compound emulsifier: put 6kg of anionic emulsifier sodium lauryl sulfate and 4kg of nonionic emulsifier octylphenol polyoxyethylene ether in a clean container at a ratio of 3:2, and stir for 15 minutes to make Mix them evenly to obtain compound emulsifier B.

[0032] (3) Seed emulsion polymerization: Add 400kg of deionized water, all of the compound emulsifier B, 3...

Embodiment 2

[0036] Prepared according to the following weight ratio of raw materials (%):

[0037]

[0038]

[0039] (1) Washing and pre-emulsification of monomers: Add 160kg of butyl acrylate, 120kg of acrylic acid, 5kg of methyl methacrylate, 3kg of acrylonitrile, 10kg of itaconic acid, and 120kg of deionized water into the pre-emulsification device, remove the polymerization inhibitor by distillation under reduced pressure, and wash with 1kg of 10% sodium hydroxide solution, start stirring for 30 minutes, the appearance of the mixed solution is uniform milky white, stop stirring to obtain pre-emulsion A.

[0040] (2) Preparation of compound emulsifier: put 0.6kg of anionic emulsifier sodium lauryl sulfate and 0.4kg of nonionic emulsifier octylphenol polyoxyethylene ether in a clean container at a ratio of 3:2, and stir for 15 minutes to make Mix them evenly to obtain compound emulsifier B.

[0041](3) Seed emulsion polymerization: add 450kg of deionized water, all of the compoun...

Embodiment 3

[0045] Prepared according to the following weight ratio of raw materials (%):

[0046]

[0047] (1) Washing and pre-emulsification of monomers: Add 370kg of butyl acrylate, 10kg of acrylic acid, 5kg of methyl methacrylate, 3kg of acrylonitrile, 10kg of itaconic acid, and 100kg of deionized water into the pre-emulsification device , remove the polymerization inhibitor by distillation under reduced pressure, wash with 1kg10% sodium hydroxide solution, start stirring for 30min, the appearance of the mixed solution is uniform milky white, stop stirring to obtain pre-emulsion A.

[0048] (2) Preparation of compound emulsifier: put 0.6kg of anionic emulsifier sodium lauryl sulfate and 0.4kg of nonionic emulsifier octylphenol polyoxyethylene ether in a clean container at a ratio of 3:2, and stir for 15 minutes to make Mix them evenly to obtain compound emulsifier B.

[0049] (3) Seed emulsion polymerization: Add 330kg of deionized water, all of the compound emulsifier B, 2kg of i...

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Abstract

The invention relates to an acrylate copolymer emulsion paper-plastic composite adhesive which is prepared from the following raw materials in percentage by weight: 16-37% of butyl acrylate, 8-16% of acrylic acid, 5-11% of methyl methacrylate, 3-8% of acrylonitrile, 1-5% of itaconic acid, 0.1-0.3% of sodium hydroxide, 0.4-0.6% of initiator, 0.1-2% of composite emulsifier, 0.05-0.1% of ammonia water, 0.05-0.1% of defoaming agent, 2-6% of stabilizer and 15-64% of deionized water. The invention also relates to a preparation method of the acrylate copolymer emulsion paper-plastic composite adhesive. The invention has the advantages of abundant raw material sources, low synthesis cost and simple and stable production technique; and the prepared acrylate copolymer emulsion paper-plastic composite adhesive has the advantages of small and uniform particles, high drying rate and favorable storage stability, and is suitable for compounding paper-base presswork and plastics.

Description

technical field [0001] The invention relates to an acrylic ester copolymer emulsion paper-plastic composite glue and a manufacturing method thereof, belonging to the field of new polymer materials. Background technique [0002] Paper-plastic composite is a layer of plastic film on the surface of paper-based printed matter, which is a commonly used composite material in the printing industry. As an intermediate link between the two, the paper-plastic composite adhesive requires good adhesion to non-polar, low-surface-energy plastic film surfaces and polar paper surfaces; it also needs to have good affinity for ink. At present, there are three main types of paper-plastic composite adhesives on the market: solvent-based, emulsion-based, and pre-coated (hot-melt) types. Solvent adhesives often produce pollution and flammability problems during production, and are restricted by strict environmental protection regulations; while pre-coated films (hot-melt type) consume more power...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/08C08F220/18C08F220/06C08F220/14C08F220/46C08F222/02C08F2/30C08F2/26
Inventor 胡连芹王恩飞洪景利邢青涛
Owner 海南赛高新材料有限公司
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