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Anti-reflection and self-cleaning glass and manufacturing method thereof

A manufacturing method and self-cleaning technology, which is applied in the field of glass surface processing and micro-nano manufacturing, can solve the problems of being difficult to have anti-reflection and self-cleaning at the same time, poor adaptability to ambient temperature and humidity, and high production costs, and achieve high efficiency and low cost. Advanced production, strong adaptability to harsh environments, and good consistency of embossed graphics

Active Publication Date: 2013-08-21
QINGDAO BONA PHOTOELECTRIC EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these structures and methods usually make the glass only have a single function of anti-reflection or self-cleaning. On the one hand, it is difficult to have the functions of anti-reflection and self-cleaning at the same time.
And there are still many defects and deficiencies
For example, multi-layer coatings face the following problems: ① Due to the introduction of different materials, thermodynamic mismatch or poor adhesion reduce its stability; ② Although this kind of film usually has better anti-reflection performance in a certain wavelength band, However, it cannot reduce the loss of reflected light in a wide range of wavelengths; ③The types of materials in nature are limited and cannot meet actual needs, especially the requirement of continuous refractive index, such as: the refraction of magnesium fluoride, silicon nitride, and silicon dioxide The coefficients are all around 1.4, and there are almost no materials with a refractive index between 1 and 1.2; ④The two main techniques for preparing anti-reflective films—physical vapor deposition (PVD) and chemical vapor deposition (CVD) have high production costs
There are also many problems such as poor adhesion, poor timeliness, and poor adaptability to the environment when pasting anti-reflective films on the surface.
Therefore, there are many problems in the traditional multi-layer coating and anti-reflection film sticking on the surface: the adhesion of the film layer to the substrate surface and the adhesion between the film layers; the chemical corrosion resistance, durability and stability of the film layer Sexuality problems; expansion mismatch and condensation delamination problems caused by different thermal expansion coefficients; component permeation and diffusion problems between film layers and between film layers and substrates; cannot find suitable film materials; Band reflectivity; poor adaptability to ambient temperature and humidity, there are problems such as easy to fall off and thermal impact
[0004] Therefore, the existing solutions and manufacturing methods are still difficult to meet the performance and actual production requirements of anti-reflection and self-cleaning glass, which has become a bottleneck restricting the widespread promotion and application of anti-reflection and self-cleaning glass. There is an urgent need for clean glass structures and methods for their efficient and low-cost mass production

Method used

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  • Anti-reflection and self-cleaning glass and manufacturing method thereof
  • Anti-reflection and self-cleaning glass and manufacturing method thereof
  • Anti-reflection and self-cleaning glass and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] A subwavelength nano-cone array structure is formed on the exposed glass surface.

[0056] Such as figure 1 As shown, a sub-wavelength nanocone array structure is etched on the exposed glass surface. The shape of the nanocone is conical, the diameter of the bottom surface is 180nm, and the aspect ratio is 4 (the height of the nanocone is 880nm). The center of the bottom surface of the nanocone The pitch (period) between them is 220nm.

[0057] The specific preparation steps are as follows ( Figure 2~3 ):

[0058] (1) Pretreatment

[0059] ① Clean the glass substrate 2, respectively use acetone, ethanol, and deionized water to ultrasonically clean the glass sheet for 5 minutes, blow dry it with nitrogen, and dry it, such as image 3 a;

[0060] 2. Deposit a hard mask layer, and deposit 300nm silicon dioxide on the glass substrate 2 as a hard mask layer, such as image 3 b.

[0061] (2) Liquid imprint material 3 coating

[0062] A slit coating method is used to u...

Embodiment 2

[0078] The sub-wavelength nano-cone array structure is directly imprinted on the liquid imprint material coating of the glass substrate.

[0079] Such as Figure 5 As shown, the surface of the glass substrate 2 is coated with a coating of liquid imprinting material, and a sub-wavelength nano-cone array structure is directly imprinted on the coating. The aspect ratio is 5 (the height of the nanocones is 1000nm), and the spacing (period) between the centers of the bottom surfaces of the nanocones is 260nm.

[0080] The coating described in this example is a nano-titanium dioxide-based UV-curable transparent liquid imprinting material (such as an imprinting material formed by adding titanium dioxide nanoparticles to an epoxy polymer matrix KATIONBOND OMVE 110707).

[0081] Specific steps are as follows( Figure 6~7 ):

[0082] (1) Pretreatment

[0083] ① The glass substrate 2 is cleaned, and the glass sheet is ultrasonically cleaned with acetone, ethanol, and deionized water ...

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PUM

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Abstract

The invention discloses anti-reflection and self-cleaning glass and a manufacturing method of the glass. A nanocone array structure with sub-wavelength is formed on an impressing material on the glass surface by a nanometer impressing process based on a band soft mould or a nanocone array structure with sub-wavelength is etched on the glass surface by a hard mask, a nanometer impressing with an impressing material based on a band soft mould and a hard mask transferring etching process. The anti-reflection and self-cleaning glass can be applied to the fields of solar battery panels, glass curtain walls, automobile windshields, optical elements and instruments, large-size high-definition panel displays, infrared detectors and the like. The anti-reflection and self-cleaning glass disclosed by the invention has the advantages of high anti-reflection and self-cleaning performance, good durability, high stability, strong severe environment adaptation and low cost, and in particular, the efficient and low-cost mass production of the anti-reflection and self-cleaning glass with extra-large area can be realized.

Description

technical field [0001] The invention belongs to the technical field of glass surface processing and micro-nano manufacturing, and in particular relates to an anti-reflection and self-cleaning glass and a manufacturing method thereof. Background technique [0002] Anti-reflection (anti-reflection) and self-cleaning glass can effectively reduce the reflection of the glass itself and increase the transmittance of the glass (that is, reduce the full-spectrum reflection of incident light, increase transmission, and improve transparency; reduce the mirror effect of the glass surface, with anti-glare function), and has the advantages of anti-pollution and self-cleaning, it can effectively improve solar panels, glass curtain walls, car windshields, optical components (lenses, microscope lenses, camera lenses, etc.), flat panel displays (touch screens, TV screen, smart phone screen, etc.) and other products’ performance and quality. For example, the use of anti-reflection and self-c...

Claims

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Application Information

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IPC IPC(8): C03C17/00
Inventor 兰红波
Owner QINGDAO BONA PHOTOELECTRIC EQUIP
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