Lithium-ion secondary battery cathode material and application of a class of aromatic heterocyclic ketones
A positive electrode material, secondary battery technology, applied in secondary batteries, battery electrodes, non-aqueous electrolyte batteries, etc., can solve the problems of low capacity, limited application scope, etc., and achieve easy preparation, good cycle stability, and structure. rich effects
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Embodiment 1
[0078] Example 1, using quinacridone violet (micron-sized rod-shaped particles) as the positive electrode material to test the performance of lithium-ion secondary batteries: 60 mg of quinacridone as the positive electrode material, 30 mg of carbon black and 10 mg of polybias Vinyl fluoride (PVDF) mixed, after adding enough N-methylpyrrolidone, and then coated on aluminum foil. The coated electrodes were placed in a vacuum oven and dried at 373K for 12 hours. Finally, the electrodes are cut with a tablet machine. In a glove box filled with argon, use the electrode sheet as the positive electrode, polyethylene as the diaphragm, lithium hexafluorophosphate / dimethyl carbonate as the electrolyte (1mol / L), and the lithium sheet as the negative electrode to assemble a lithium-ion secondary battery.
[0079] The battery is charged and discharged at a constant current under the condition of a current density of 50mA / g, and the discharge voltage range is 1.5-4.5V. The cycle discharge...
Embodiment 2
[0081] Example 2, using diindoloquinacridone (nano-sized powder particles) as the positive electrode material to test the performance of lithium-ion secondary batteries: 60 mg of diindoloquinacridone as the positive electrode material, 30 mg Carbon black and 10 mg of polyvinylidene fluoride (PVDF) were mixed, after adding a sufficient amount of N-methylpyrrolidone, and then coated on aluminum foil. The coated electrodes were placed in a vacuum oven and dried at 373K for 12 hours. Finally, the electrodes are cut with a tablet machine. In a glove box filled with argon, use the electrode sheet as the positive electrode, polyethylene as the diaphragm, lithium hexafluorophosphate / dimethyl carbonate as the electrolyte (1mol / L), and the lithium sheet as the negative electrode to assemble a lithium-ion secondary battery.
[0082] The battery is charged and discharged at a constant current under the condition of a current density of 50mA / g, and the discharge voltage range is 1.5-4.5V....
Embodiment 3
[0084] Embodiment 3, use quinacridone quinone powder as positive electrode material to carry out the test of lithium ion secondary battery performance: 60 mg quinacridone quinone is used as positive electrode material, 30 mg carbon black and 10 mg polyvinylidene fluoride (PVDF) Mix, add enough N-methylpyrrolidone, and spread on aluminum foil. The coated electrodes were placed in a vacuum oven and dried at 373K for 12 hours. Finally, the electrodes are cut with a tablet machine. In a glove box filled with argon, use the electrode sheet as the positive electrode, polyethylene as the diaphragm, lithium hexafluorophosphate / dimethyl carbonate as the electrolyte (1mol / L), and the lithium sheet as the negative electrode to assemble a lithium-ion secondary battery.
[0085] The battery is charged and discharged at a constant current under the condition of a current density of 50mA / g, and the discharge voltage range is 1.5-4.5V; the cycle discharge capacity retention curve of the batt...
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