Solvent-free UV (ultraviolet) curing glue for optical transparent adhesive tape and preparation method and application thereof

An optically transparent and curing glue technology, applied in the direction of adhesives, adhesive types, adhesive additives, etc., can solve the problems of difficult control of product batch stability, high content of volatile organic compounds, and inability to produce thick OCA, etc. Achieve the effect of maintaining batch stability, high colloidal strength and high cohesion

Active Publication Date: 2014-04-16
广州慧谷功能材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

OCA products produced by thermal curing are limited by the activation period of glue, with high volatile organic compound (VOC) content and long production cycle. Sub-stability is not easy to control, and it is impossible to produce thick OCA (thick OCA generally refers to the effective adhesive layer thickness ≧ 175um) products. At the same time, there are defects such as high production energy consumption, which seriously restricts the development of related domestic industries.

Method used

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  • Solvent-free UV (ultraviolet) curing glue for optical transparent adhesive tape and preparation method and application thereof
  • Solvent-free UV (ultraviolet) curing glue for optical transparent adhesive tape and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Embodiment 1: Preparation of solvent-free UV curing glue for optical scotch tape

[0039] Mix 60g mass parts of aliphatic urethane acrylate (Sartomer-CN965NS), 5g hyperbranched polyester acrylate (Sartomer-CN2303), then add 1g tackifying resin (E-5600BR), 20g acrylate monomer (Sartomer-SR395NS ), 5g of acrylate monomer (Eternal Chemical EM2411), mix well; then add 1g of ether-containing structure mercaptan (Nippon Synthetic Lecad803), mix well; add 0.5g of leveling agent (BYK-UV3570), 0.5g of defoaming agent Agent (BYK-057) and 1g photoinitiator (Irgacure127), mixed evenly, to obtain solvent-free UV curing glue for optical scotch tape.

Embodiment 2

[0040] Embodiment 2: Preparation of solvent-free UV curing glue for optical scotch tape

[0041] Mix 20g mass parts of aliphatic urethane acrylate (Sartomer-966J75NS), 5g hyperbranched polyester acrylate (Changxing Chemical 6361-100), then add 1g tackifying resin (E-5600BR), 5g acrylate monomer (Sartomer -454NS), 5g acrylate monomer (Eternal Chemical EM241), mix well; then add 1g ether-containing structure mercaptan (Nippon Synthetic Lecad804), mix well; add 0.5g leveling agent (BYK-UV3530), 0.5g Defoamer (BYK-088) and 2g photoinitiator (Irgacure2022), mixed evenly, to obtain solvent-free UV curing glue for optical scotch tape.

Embodiment 3

[0042] Embodiment 3: Preparation of solvent-free UV curing glue for optical scotch tape

[0043]Mix 50g mass parts of aliphatic polyurethane acrylate (Changxing 641), 5g hyperbranched polyester acrylate (Sartomer-CN2302), then add 1g tackifying resin (DS99), 10g acrylate monomer (Sartomer-506NS), 5g Acrylate monomer (Eternal Chemical EM265), mix evenly; then add 1g of ether-containing structure mercaptan (Japan Xibixi TMPT), mix evenly; add 0.5g leveling agent (BYK-UV3500), 0.5g defoamer (BYK-067A) and 2g photoinitiator (Irgacure184), mix well to get solvent-free UV curing glue for optical scotch tape.

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Abstract

The invention belongs to the technical field of UV (ultraviolet) curing glue, and discloses solvent-free UV curing glue for an optical transparent adhesive tape and a preparation method and application thereof. The glue comprises the following components in parts by mass: 20-60 parts of aliphatic polyurethane acrylate, 5-15 parts of hyperbranched polyester acrylate, 10-25 parts of acrylate monomer, 1-10 parts of thiol, 1-10 parts of tackifying resin, 0.1-1 part of leveling agent, 0.5-2 parts of antifoaming agent and 0.5-2 parts of photoinitiator. In the invention, the colloid crosslinking density and colloid strength are improved by preferentially adopting aliphatic polyurethane acrylate with low functionality degree and adding hyperbranched polyester acrylate; the acrylate monomer adjusts the viscosity and enhances the colloid strength; the caking property is improved by adding the thiol containing an ether structure; the prepared non-solvent UV curing glue for an optical transparent adhesive tape has high toughness, high light transmittance, low haze, high colloid strength, high viscosity, high thickness and low VOC (volatile organic compound) content.

Description

technical field [0001] The invention belongs to the technical field of UV curable glue, in particular to a solvent-free UV curable glue for optical scotch tape and its preparation method and application. Background technique [0002] Optical Transparent Tape (OCA) is a double-sided adhesive tape with optical properties and no matrix material. Optically transparent tape (OCA) is used in a wide variety of applications. At present, it is mainly used in the bonding of materials in three types of fields, including: thin film (TP) materials for touch screens, protective films, and materials for liquid crystal displays (LCD). [0003] At present, the curing method of optical transparent tape is mainly heat curing. OCA products produced by thermal curing are limited by the activation period of the glue, with high volatile organic compound (VOC) content and long production cycle. The sub-stability is difficult to control, and it is impossible to produce thick OCA (thick OCA genera...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/14C09J167/06C09J11/06C09J11/08C09J7/02
Inventor 乔立根吴鹏飞陈勇黄链
Owner 广州慧谷功能材料有限公司
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