Grinding particle system and polishing liquid for CMP (Chemical Mechanical Polishing)

A technology of abrasive particles and systems, applied to polishing compositions containing abrasives, other chemical processes, chemical instruments and methods, etc., can solve the problems of difficult control of inorganic particle distribution, complicated preparation process, high production cost, etc., and reduce the surface area. Scratch, simple preparation process and low manufacturing cost

Inactive Publication Date: 2014-04-16
SHANGHAI INTEGRATED CIRCUIT RES & DEV CENT
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

For example, Chinese patent application CN1616573A discloses that inorganic particles are adsorbed to the surface of organic resin particles (such as Figure 2A ), but its process is complex, and the distribution of inorganic particles on the surface of organic particles is difficult to control; and the Chinese patent application CN1982400A discloses that organic nanoparticles are used as the core, and a cerium oxide shell is formed on the surface of the organic particles through solution reaction to form a composite abrasive ( like Figure 2B ), but its production cost is high
The preparation process of this type of composite abrasive particles is complex and the production cost is high

Method used

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  • Grinding particle system and polishing liquid for CMP (Chemical Mechanical Polishing)
  • Grinding particle system and polishing liquid for CMP (Chemical Mechanical Polishing)
  • Grinding particle system and polishing liquid for CMP (Chemical Mechanical Polishing)

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no. 1 example

[0029] see image 3 and Figure 4 , the abrasive particle system of this embodiment contains organic particles, inorganic particles and chemical solutions.

[0030] Among them, this embodiment uses the suspension polymerization method to prepare polyvinyl chloride (PVC). The polyvinyl chloride monomer is spherical. By adding different polymerization initiators, the spherical polyvinyl chloride monomers are connected together to form a long chain structure. The length of the chain is 10-200 spherical polyvinyl chloride monomers, and the weight concentration of the chain organic particles in the grinding particle system is 20wt%. Compared with single-spherical organic particles, long-chain polyvinyl chloride particles can greatly increase the contact area between the particles and the wafer surface during the polishing process, improving the polishing rate and efficiency. The polyvinyl chloride particles have good elasticity and will not cause scratches on the surface of the w...

no. 2 example

[0034] see image 3 and Figure 5 , the abrasive particle system of this embodiment contains organic particles, inorganic particles and chemical solution.

[0035] Among them, this embodiment uses bulk polymerization to prepare high-impact polystyrene, which is a polymer of styrene and butadiene. By adding different polymerization initiators, polystyrene forms a nebula-like structure, and the molecular weight of the particles is between 1000- 50000, the weight concentration of organic particles in the grinding particle system is 10wt%. Compared with single-spherical organic particles, polystyrene particles with a nebular structure can greatly increase the contact area between particles and the wafer surface during polishing, increase mild friction, and improve polishing rate and efficiency. The material composition is different at different positions, and its elasticity can be adjusted without scratching the surface of the wafer. This high-impact polystyrene is chemically r...

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Abstract

The invention discloses a grinding particle system and polishing liquid. The grinding particle system comprises organic particles, inorganic particles and a chemical solution, wherein the content of the organic particles is 3-10 times as much as that of the content of the inorganic particles. According to the grinding particle system, the control of a mixing ratio and the distribution of the particles is carried out so that the content of the inorganic particles in the grinding particle system is greatly reduced, and furthermore, the surface scratches and the particle residues caused by polishing are reduced; the shape of the organic particles is designed so as to enlarge the contact area of the particles in a polishing process and improve the polishing efficiency. The respective advantages of the inorganic particles and the organic particles are sufficiently expressed; the preparation process is simple and the manufacturing cost is low; the grinding particle system is particularly suitable for a surface polishing process of materials with ultra-low k values and metal materials with low rigidity, such as copper and aluminum.

Description

technical field [0001] The invention relates to the technical field of integrated circuit manufacturing, in particular to an abrasive particle system and a polishing liquid for CMP. Background technique [0002] Chemical Mechanical Polishing (CMP) is one of the important processes in semiconductor manufacturing. It achieves global flatness of the wafer surface by grinding and removing materials from semiconductor materials, insulating materials and metal materials with patterned wafer surfaces. A process of chemicalization. During the polishing process, the wafer to be polished is fixed on the polishing carrier, and the polishing liquid with abrasive particles and chemical solution is applied on the polishing pad, and the chemical substance in the polishing liquid oxidizes the material on the surface of the wafer to form a softer oxide layer. Then, through the contact friction between the polishing pad, the abrasive particles in the polishing liquid and the wafer, the oxide...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/14C09G1/02C23F3/00
CPCC09G1/02C09K3/1463C23F3/00
Inventor 钟旻
Owner SHANGHAI INTEGRATED CIRCUIT RES & DEV CENT
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