Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

High-thermal-conductivity polymer composite and preparation method thereof

A composite material and polymer technology, applied in the field of high thermal conductivity polymer composite material and its preparation, can solve the problems of further improvement of thermal conductivity, loss of mechanical properties, high processing cost, and achieve suitable large-scale production, good mechanical properties, The effect of improving compatibility

Active Publication Date: 2014-04-30
ZHONGSHAN DIANSHI PLASTIC
View PDF3 Cites 25 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional materials can no longer solve the above problems. This is because although metal materials have good heat dissipation, they are good conductors of electricity, which will affect the operation of circuits. The emergence of polymer materials that have both thermal conductivity and insulation can well solve the above problems
Moreover, the electrolysis and electroplating processes of aluminum, the most widely used heat dissipation material, cause environmental pollution, and the metal density is high, the processing cost is high, and the degree of freedom in design is low.
However, the existing polymer materials have low thermal conductivity and cannot be a good substitute for aluminum as a heat dissipation material.
At present, technicians mainly increase the thermal conductivity of polymer materials by adding nitrides, carbides, metal powders, graphite, etc. The disadvantages of this method are that the addition amount is large, the compatibility with the matrix is ​​poor, the mechanical properties are seriously The performance is not ideal, and the thermal conductivity needs to be further improved

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High-thermal-conductivity polymer composite and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0026] A method for preparing a high thermal conductivity polymer composite material, comprising the following steps:

[0027] 1) Prepare the coupling agent into 1-3wt% ethanol solution;

[0028] 2) After etching the carbon fiber, soak it with an appropriate amount of coupling agent ethanol solution, and then volatilize to remove the ethanol;

[0029] 3) The polyphenylene sulfide with a formulation amount of 32-78% and the carbon fiber treated in step 2) are melt-extruded and pelletized through a twin-screw extruder to obtain a polyphenylene sulfide / carbon fiber masterbatch;

[0030] 4) Melt, extrude and granulate nylon and glass fiber with a formula amount of 50-72% through a twin-screw extruder to obtain nylon / glass fiber masterbatch;

[0031] 5) Melting and extruding the remaining nylon, remaining polyphenylene sulfide, elastomer and compatibilizer through a twin-screw extruder, and granulating to obtain nylon / polyphenylene sulfide / elastomer masterbatch;

[0032] 6) Mix l...

Embodiment 1

[0039] High thermal conductivity polymer composite material, including the following components: 22 parts of polyphenylene sulfide, 9.5 parts of nylon 66, 1 part of carbon fiber (average aspect ratio of 20, thermal conductivity of 500W / mk), 56 parts of large particle size thermal conductive filler (23 parts of carbonyl iron powder with a particle size of 56 microns, 2.5 parts of copper powder with a particle size of 38 microns, 5 parts of aluminum powder with a particle size of 25 microns, and 25.5 parts of graphite with a particle size of 75 microns), 4 parts of small particle size thermally conductive fillers ( 1.3 parts of multi-walled carbon nanotubes with a particle size of 70 nm, 1.6 parts of graphene with a particle size of 25 nm, 1.1 parts of diamond powder with a particle size of 105 nm), 4 parts of glass fiber, 2 parts of POE, and 1 part of POE-g-MAH , 0.2 parts of coupling agent KH560, 0.12 parts of antioxidant 445 and 0.18 parts of antioxidant 619.

[0040] The pre...

Embodiment 2

[0050] High thermal conductivity polymer composite material, composed of the following components: 10.5 parts of polyphenylene sulfide, 25 parts of nylon 66, 5 parts of carbon fiber (average aspect ratio of 50, thermal conductivity of 600W / mk), 49 parts of large particle size thermal conductive filler Parts (18 parts of carbonyl iron powder with a particle size of 35 microns, 2 parts of copper powder with a particle size of 46 microns, 5 parts of aluminum powder with a particle size of 68 microns, and 24 parts of graphite with a particle size of 77 microns), 5 parts of small particle size thermally conductive fillers (2.3 parts of multi-walled carbon nanotubes with a particle size of 12 nm, 1.6 parts of graphene with a particle size of 88 nm, and 1.1 parts of diamond powder with a particle size of 165 nm), 3 parts of glass fiber, 1 part of POE, and 1 part of POE-g-MAH parts, 0.2 parts of coupling agent KH560, 0.12 parts of antioxidant 445 and 0.18 parts of antioxidant 619.

[...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Thermal conductivityaaaaaaaaaa
Thermal conductivityaaaaaaaaaa
Login to View More

Abstract

The invention discloses a high-thermal-conductivity polymer composite and a preparation method thereof. The high-thermal-conductivity polymer composite comprises the following components: 25-60 parts of matrix resin, 0.5-10 parts of carbon fiber, 30-60 parts of large-particle size heat conducting filler with particle size of 10-150 microns, 3-10 parts of small-particle size heat conducting filler with particle size of 1-500nm, 3-8 parts of glass fiber, 1-5 parts of elastomer, 1-5 parts of compatilizer, 0.2-0.4 parts of coupling agent KH560 and 0.2-0.4 part of antioxidant. In the invention, the raw materials are reasonably matched, and the synergistic effect among the fiber, large-particle size heat conducting filler and small-particle size heat conducting filler is fully played; by virtue of surface treatment on the heat conducting filler and the preparation process of masterbatch, the compatibility between the heat conducting filler and the matrix is effectively improved, and the prepared polymer composite has good mechanical property and high thermal conductivity.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a high thermal conductivity polymer composite material and a preparation method thereof. Background technique [0002] Thermally conductive materials are widely used in various sectors of the national economy and industrial fields. Traditional thermal conductive materials are mainly metal materials and inorganic materials, such as Al, Cu, Ag, etc., and inorganic materials such as graphite, carbon black, SiC, AlN, etc. With the advancement of industrial development and technology, people put forward more new requirements for thermal conductive materials, such as electrical insulation, corrosion resistance, light weight, easy processing and molding, etc., and high-tech electronic products are developing in the direction of small, light and thin , the number of internal integration of electronic components is increasing, and its heat dissipation problem needs ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L81/02C08L77/02C08L77/06C08K13/06C08K9/06C08K7/06C08K7/14C08K3/04C08K3/18C08K3/08C08K7/00C08J3/22
Inventor 王可王毅侯筱华
Owner ZHONGSHAN DIANSHI PLASTIC
Features
  • Generate Ideas
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More