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Super-hydrophobic and anti-pollution flashover one-component adhesive, and preparation method and application thereof

A single-component, adhesive technology, applied in the direction of adhesives, non-polymer adhesive additives, adhesive additives, etc., can solve the problems of inconvenient transportation and storage, low hydrophobic recovery, low hydrophobicity, etc., to weaken the influence of static electricity , low surface energy, and the effect of reducing fouling

Inactive Publication Date: 2014-08-06
TIANJIN HANGRUI FENGYUAN TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Commonly used RTV anti-fouling flashover coatings are mostly two-component, which need to be prepared on site when used, which is troublesome to operate. At the same time, there are disadvantages such as low hydrophobicity, low hydrophobic recovery, and no flame retardancy.
Commonly used RTV antifouling flashover coatings contain a large amount of solvents, and there are technical problems such as inconvenient transportation and storage

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A super-hydrophobic antifouling anti-flash one-component adhesive, comprising the mass parts of each component: 100 parts of hydroxyl-terminated polysiloxane, 20 parts of fumed silica, 50 parts of calcium carbonate, 70 parts of aluminum hydroxide, 5 parts of decabromodiphenylethane, 3 parts of hydrophobic enhancer dihydroxydiphenylsilane, 0.5 parts of structure regulator KH-550 silane coupling agent, 7 parts of vinyl tributylketoxime silane and catalyst dilauric acid di 0.5 part of butyl tin.

example 2

[0035] The preparation method of the superhydrophobic antifouling anti-flash one-component adhesive described in embodiment 1, its preparation process is: with 100 parts (weight parts) of hydroxyl-terminated polysiloxane, 20 parts of fumed silica, 50 parts of calcium carbonate, After mixing 70 parts of aluminum hydroxide, 5 parts of decabromodiphenylethane, 3 parts of hydrophobic enhancer, and 0.5 part of structure regulator, they were vacuum-dried at 130 °C at minus 0.8 MPa for 2 hours, and then vinyl tributanone was added 7 parts of oxime silane and 0.5 parts of catalyst are superhydrophobic antifouling anti-flash one-component adhesive. After the mixture is uniform, it is sealed and packaged in an air-insulated container under nitrogen protection.

[0036] The anti-fouling flashover coating obtained has a flame retardant grade of FV-0, a water contact angle of 115°, a peel strength of 18 N / cm, a surface-drying time of 45 minutes, and a viscosity of 12000 mPa.s. Adding 50 pa...

Embodiment 3

[0038] A super-hydrophobic antifouling anti-flash one-component adhesive, comprising the following components in parts by mass: 100 parts of hydroxyl-terminated polysiloxane, 20 parts of precipitated white carbon black, 50 parts of calcium carbonate, 60 parts of magnesium hydroxide, 5 parts of decabromodiphenylethane, 4 parts of hydrophobic enhancer small molecular weight hydroxyl silicone oil, 0.5 parts of structure regulator KH-560 silane coupling agent, 10 parts of crosslinking agent methyltriacetoxysilane and 0.5 parts of catalyst stannous octoate share.

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PUM

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Abstract

The invention relates to super-hydrophobic and anti-pollution flashover one-component adhesive, and a preparation method and application thereof, and belongs to the technical field of adhesives and coatings. The adhesive comprises the following components in part by mass: 100 parts of hydroxyl-terminated polysiloxane, 50 to 150 parts of fire retardant, 1 to 5 parts of hydrophobic enhancer, 0.2 to 2 parts of structure modifier, 3 to 15 parts of cross-linking agent, and 0.2 to 5 parts of catalyst. The method comprises the steps of performing vacuum drying treatment to the hydroxyl-terminated polysiloxane, reinforcing filler, the fire retardant, the hydrophobic enhancer and the structure modifier which are mixed for 1 to 3 hours at 80 to 150 DEG C, cooling the mixture, feeding the cross-linking agent and the catalyst to the mixture, uniformly mixing, and then obtaining the adhesive. The adhesive can be dissolved in organic solvent and then is served as coating. The adhesive has the advantages that the adhesive can be directly used, the bonding strength is high, the flame retardant rating is high, the pollution prevention effect is good, the technology is simple, the controllability is good, the adhesive can be directly used and can also be dissolved in solvent to perform coating operation, and the like.

Description

technical field [0001] The invention belongs to the technical field of adhesives and coatings, and in particular relates to a superhydrophobic antifouling anti-flash one-component adhesive and its preparation method and application. Background technique [0002] At present, during the long-term use of power transmission and transformation equipment, the surface will be covered with a lot of solid particles such as dust, so that the surface of the power transmission and transformation equipment has a certain conductivity, so electricity will leak during use, which wastes resources and brings Certain security risks. The power required by the electric locomotive is the high-voltage single-phase power-frequency alternating current on the catenary wire, and the current enters the locomotive through the pantograph and the main circuit breaker to provide power for the locomotive. In recent years, the smog weather environment that often occurs in many places in China, the air conta...

Claims

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Application Information

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IPC IPC(8): C09J183/06C09J11/04C09J11/06C09D183/06C09D5/00C09D7/12
Inventor 唐波
Owner TIANJIN HANGRUI FENGYUAN TECH
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