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Iron-based alloy premix for metal injection forming

An iron-based alloy, injection molding technology, applied in the field of powder metallurgy, can solve the problems of narrow particle size distribution, structure segregation, increased binder ratio, etc., and achieve the effect of uniform composition without segregation, uniform structure without segregation, and stable product size.

Active Publication Date: 2014-08-27
杭州屹通新材料股份有限公司
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  • Abstract
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  • Application Information

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Problems solved by technology

[0002] At present, the powder metallurgy industry has higher and higher performance requirements for metal injection molding iron-based products. An important way to solve the problem is to improve the performance of the product by adding new alloying elements to the raw material powder. The usual alloying elements are carbon, nickel, Copper, chromium, molybdenum, etc. At present, the raw materials of metal injection molding iron-based products are carbonyl iron powder and carbonyl nickel powder. Although the carbonyl method can produce metal powders with a particle size below 10 microns, it cannot form powders with multiple alloying elements. , the vast majority of product manufacturers often use iron powder, nickel powder, copper powder and other powders mixed together, so that the mixed powder cannot fully diffuse the alloy elements at the subsequent sintering temperature, forming a so-called "pseudo-alloy" , structure segregation, uneven composition, product performance is difficult to meet the requirements, and the injection molding powder produced by the carbonyl method is generally below 10 microns, and the particle size distribution is narrow, D10 is between 1 and 3 microns, and D50 is between 2 and 5 microns. D90 is between 4 and 7 microns, so powders with particle size distribution also have great disadvantages. If the powder particle size is too fine, the injection billet cannot form a good skeleton support in the process of solvent degreasing and thermal degreasing, so the green body after degreasing Easy to deform, and the narrow particle size distribution leads to low tap density of the powder, an increase in the required binder ratio, large dimensional deformation of the product after sintering, and low yield
[0003] The existing iron-based alloy powder needs to be mixed and processed with a binder before it can be used for injection molding, which is inconvenient to use and increases the processing steps and required equipment. In addition, due to the particle size of the iron-based alloy powder It is fine, easy to agglomerate, and mixed with molten binder unevenly, resulting in sintered product structure segregation, uneven composition, easy deformation, and poor product performance

Method used

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  • Iron-based alloy premix for metal injection forming

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] An iron-based alloy premix for metal injection molding is prepared through the following steps:

[0038] (1) The weight percent composition of each component of the iron-based alloy powder is as follows: carbon content 0.2-0.5%, nickel content 1.5-2.5%, copper content 1-2%, molybdenum content 0.2-0.8%, chromium content 0.2-0.8%, The iron content is 94.7%.

[0039] Put the raw materials into the electric furnace according to the ratio of the components of the iron-based alloy powder. After heating up and melting into molten steel, add a deoxidizer to the molten steel and keep stirring for 10 minutes under the condition of 1650 ° C. The amount of deoxidizer is the weight of molten steel. 0.5%, the composition of the deoxidizer is: Mn: 15wt%, Al: 5wt%, B: 5wt%, Ca: 2wt%, Si: 73wt%. Remove slag (reduced slag generated after adding deoxidizer) to molten steel, and then continue to keep warm for 2 minutes.

[0040] (2) if figure 1 As shown, the molten steel obtained in ...

Embodiment 2

[0052] An iron-based alloy premix for metal injection molding is prepared through the following steps:

[0053] (1) The weight percentage of each component of iron-based alloy powder is as follows: carbon content 0.5%, nickel content 2.5%, copper content 1%, molybdenum content 0.2%, chromium content 0.2%, iron content 95.6%.

[0054] Put the raw materials into the electric furnace according to the ratio of the components of the iron-based alloy powder. After heating up and melting into molten steel, add a deoxidizer to the molten steel and keep stirring for 5 minutes under the condition of 1750 ° C. The amount of deoxidizer is the weight of the molten steel 1%, the composition of the deoxidizer is: Mn: 25wt%, Al: 15wt%, B: 10wt%, Ca: 5wt%, Si: 45wt%. Remove slag from the molten steel, and then continue to keep warm for 1min.

[0055] (2) if figure 1 As shown, the molten steel obtained in step (1) flows down through the leakage hole at the bottom of the leakage bag 1 at a flo...

Embodiment 3

[0066] An iron-based alloy premix for metal injection molding is prepared through the following steps:

[0067] (1) The weight percentage of each component of iron-based alloy powder is as follows: carbon content 0.3%, nickel content 2%, copper content 1.5%, molybdenum content 0.5%, chromium content 0.5%, iron content 95.2%; The ratio of the alloy powder components is put into the electric furnace, and after the temperature rises and melts into molten steel, a deoxidizer is added to the molten steel and stirred continuously for 8 minutes under the condition of 1700 ° C. The amount of the deoxidizer is 0.8% of the weight of the molten steel. The deoxidizer The composition is: Mn: 20wt%, Al: 10wt%, B: 8wt%, Ca: 3wt%, Si: 59wt%. Remove slag from the molten steel, and then continue to keep warm for 1.5 minutes.

[0068] (2) if figure 1 As shown, the molten steel obtained in step (1) flows down through the leakage hole at the bottom of the leakage bag 1 at a flow rate of 40kg / min...

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Abstract

The invention discloses an iron-based alloy premix for metal injection forming. The iron-based alloy premix is obtained by preparing iron-based alloy powder composed of the following ingredients in percentage by weight: 0.2-0.5% of carbon, 1.5-2.5% of nickel, 1-2% of copper, 0.2-0.8% of molybdenum, 0.2-0.8% of chromium and the balance of iron at first; and then carrying out surface treatment on the iron-based alloy powder, and finally mixing with an adhesive, extruding and granulating, and crushing. The iron-based alloy premix disclosed by the invention can be directly used for injection forming without the need of mixing processing treatment with the adhesive during use, and convenient to use; the processed product is uniform in ingredients, uniform and segregation-free in organization, stable in dimensions, not liable to deform, and excellent in mechanical property.

Description

technical field [0001] The invention relates to the technical field of powder metallurgy, in particular to an iron-based alloy premix for metal injection molding. Background technique [0002] At present, the powder metallurgy industry has higher and higher performance requirements for metal injection molding iron-based products. An important way to solve the problem is to improve the performance of the product by adding new alloying elements to the raw material powder. The usual alloying elements are carbon, nickel, Copper, chromium, molybdenum, etc. At present, the raw materials of metal injection molding iron-based products are carbonyl iron powder and carbonyl nickel powder. Although the carbonyl method can produce metal powders with a particle size below 10 microns, it cannot form powders with multiple alloying elements. , the vast majority of product manufacturers often use iron powder, nickel powder, copper powder and other powders mixed together, so that the mixed po...

Claims

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Application Information

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IPC IPC(8): B22F3/22C22C38/44B22F9/08B22F1/00
Inventor 崔毅汪志荣方旭何薇占建伟
Owner 杭州屹通新材料股份有限公司