Method for separating icariine from herba epimedii
A technology of icariin and epimedium, applied in chemical instruments and methods, preparation of sugar derivatives, sugar derivatives, etc., can solve the problems that the microscopic mechanism of action needs to be further studied, and the active ingredients of epimedium are not deep enough, etc. Achieve good development prospects, treat cardiovascular and cerebrovascular diseases, enhance immune function and immune regulation effects
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Embodiment 1
[0023] The method for isolating icariin from epimedium, comprises the following steps:
[0024] 1) 70kg of Epimedium, icariin content 1.0%, placed in an extraction tank, 780L of 20% ethanol for the first extraction, 130L of 20% ethanol for the second time, each time for 2 hours, boiled for extraction, the temperature is about 90 degrees, combined The filtrate was concentrated until the density reached 1.12 to obtain 56Kg of extract;
[0025] 2) After adding 100Kg of ethanol for alcohol precipitation, remove Epimedium polysaccharide, concentrate the filtrate again to a density of 1.12 or more to obtain 36Kg of extract, extract the obtained extract with 500L of ethyl acetate in 6 times, until the water phase is detected by TLC less than icariin;
[0026] 3) All the ethyl acetate extracts were combined, dehydrated with anhydrous sodium sulfate, and concentrated to dryness to obtain 1.8Kg of a brown solid, which was added to 5L of anhydrous methanol and boiled to dissolve;
[00...
Embodiment 2
[0029] The method for isolating icariin from epimedium, comprises the following steps:
[0030] 1) 80kg of Epimedium, icariin content 1.0%, placed in an extraction tank, 1100L 20% ethanol for the first extraction, 1200L 20% ethanol for the second time, each time 1h, boiled for extraction, the temperature is about 90 degrees, combined The filtrate was concentrated until the density reached 1.12 to obtain 87Kg of extract;
[0031] 2) After adding 200Kg of ethanol for alcohol precipitation, remove Epimedium polysaccharide, concentrate the filtrate again to a density of 1.12 or more, and obtain 63Kg of extract, extract the obtained extract with 300L of ethyl acetate in 6 times, until the water phase is detected by TLC less than icariin;
[0032] 3) All the ethyl acetate extracts were combined, dehydrated with anhydrous sodium sulfate, and then concentrated to dryness to obtain 2.3Kg of a brown solid, which was added to 5L of anhydrous methanol and boiled to dissolve;
[0033] 4)...
Embodiment 3
[0035] The method for isolating icariin from epimedium, comprises the following steps:
[0036] 1) 60kg of Epimedium, icariin content 1.0%, placed in an extraction tank, 800L 20% ethanol for the first extraction, 900L 20% ethanol for the second time, each time for 3 hours, boiled for extraction, the temperature is about 90 degrees, combined The filtrate was concentrated until the density reached 1.12 to obtain 62Kg of extract;
[0037] 2) After adding 200Kg of ethanol for alcohol precipitation, remove Epimedium polysaccharide, concentrate the filtrate again to a density of 1.12 or more to obtain 46Kg of extract, extract the obtained extract with 300L of ethyl acetate in 6 times, until the water phase is detected by TLC less than icariin;
[0038] 3) All the ethyl acetate extracts were combined, dehydrated with anhydrous sodium sulfate, and concentrated to dryness to obtain 0.9Kg of a brown solid, which was added to 5L of anhydrous methanol and boiled to dissolve;
[0039] 4)...
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