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A kind of lead-acid storage battery and preparation method thereof

A lead-acid battery, lead powder technology, applied in the direction of lead-acid battery, lead-acid battery construction, battery electrodes, etc. Chemically active surface, the effect of reducing self-discharge and improving charge-discharge capacity

Inactive Publication Date: 2017-01-25
SOUTH CHINA NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The Chinese patent "Lead-Acid Battery Electrolyte and Preparation Method" with application number 201310668012.7 discloses a lead-acid battery electrolyte and a preparation method. ~2g, 1~2g sodium tetraborate, 0.1~0.5g stannous sulfate, 32~36g sulfuric acid and 58~65g pure water. The refinement of lead sulfate particles generated during the process, but because it is added to the electrolyte, sodium polyaspartate does not participate in the reaction process during the paste process, and the sulfuric acid generated during the paste process cannot be refined Lead particles, so it does not play a role in the conversion of lead sulfate into active substances during the chemical formation process
In addition, there is another disadvantage when adding it to the electrolyte, because sodium polyaspartate prevents or delays the formation of lead sulfate, which is not conducive to the discharge process, that is, the discharge capacity is low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A lead-acid battery includes a positive plate and a negative plate, and the paint of the negative plate of the lead-acid battery includes the following raw material components in parts by weight:

[0045] 1000 parts of lead powder,

[0046] 1 part of polyaspartic acid,

[0047] 26 parts of silica,

[0048] 6 parts of barium sulfate,

[0049] 12 parts of expanding agent,

[0050] 80 parts of acid,

[0051] 10 parts of mixed carbon,

[0052] 106 parts of water.

[0053] Further, the expansion agent is a mixture of sodium lignosulfonate and humic acid in a mass ratio of 1:3; the mixed carbon is graphite, acetylene black, activated carbon, and artificial carbon in a mass ratio of 4:3:2 :1 mixed; the acid is dilute sulfuric acid with a density of 1.4g·mL-1.

[0054] A method for preparing a lead-acid battery is characterized in that it comprises the following steps:

[0055] S1. Preparation of negative plate coating: mix lead powder, polyaspartic acid, silicon dioxide, barium sulfate, expa...

Embodiment 2

[0060] Except that the coating of the negative plate of the lead-acid battery contains 10 parts of polyaspartic acid, the other conditions are the same as in Example 1;

Embodiment 3

[0062] Except that the coating of the negative plate of the lead-acid battery contains 20 parts of polyaspartic acid, the other conditions are the same as in Example 1;

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Abstract

The invention discloses a lead-acid storage battery and a preparation method thereof, which comprises a positive plate and a negative plate. The coating of the negative plate of the lead-acid battery comprises the following raw material components in parts by weight: 1000 parts of lead powder, polyasparagus 1~20 parts of acid or polyaspartate, 2~50 parts of silicon dioxide, 2~10 parts of barium sulfate, 4~20 parts of expansion agent, 80 parts of acid, 10 parts of mixed carbon, 106 parts of deionized water , the present invention effectively delays the battery failure caused by the sulfation of the negative electrode, and controls the hydrogen evolution of the negative electrode caused by the addition of a large amount of carbon, so as to achieve the purpose of improving the capacity and cycle life of the lead-acid battery, and can increase the carbon content of the negative electrode of the battery to a certain extent.

Description

Technical field [0001] The invention relates to a battery, in particular to a lead-acid battery and a preparation method thereof. Background technique [0002] The plates of lead-acid batteries are divided into positive and negative. In order to improve the performance of the positive and negative plates of lead-acid batteries, it is necessary to add positive and negative additives respectively when manufacturing the positive and negative plates. Generally speaking, the positive plate additives are relatively single. The additives of the negative plate are more complicated, including expansion agents, corrosion inhibitors and hydrogen evolution inhibitors. For example, commonly used expansion agents can be divided into inorganic expansion agents and organic expansion agents. Inorganic expansion agents include barium sulfate, carbon black, strontium sulfate, etc., which are beneficial to the diffusion of electrolyte in the battery and the deep discharge of the battery; at the same...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/06H01M4/62H01M10/12C09D179/08C09D5/38
CPCC09D5/38C09D7/61C09D7/63C09D7/65C09D179/08H01M4/62H01M4/625H01M4/628H01M10/06H01M10/12Y02E60/10Y02P70/50
Inventor 陈红雨张玉凤李中奇蔡俊超刘学
Owner SOUTH CHINA NORMAL UNIVERSITY
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