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Surface treatment method for water electrolysis pole plate capable of forming protective film

A technology of surface treatment and water electrolysis, which is applied in the coating process of metal materials, etc., can solve the problems of threatening the safety of personnel and equipment, interlinking of hydrogen and oxygen gas, explosion, etc., so as to ensure the quality of film formation, improve corrosion resistance, reduce The effect of production costs

Active Publication Date: 2015-03-25
BEIHAI CHENGDE METAL ROLLING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Once the plates are severely corroded, it will lead to hydrogen and oxygen gas interconnection, alkali leakage and electrical short circuit, which may cause an explosion and threaten the safety of personnel and equipment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The surface treatment method of the water electrolysis plate of the present embodiment, the specific steps are as follows:

[0025] A. Clean the surface of the carbon steel plate: degreasing, water washing, and pickling in sequence to remove oil, dust, rust, etc. attached to the surface of the plate.

[0026] B. Acid corrosion treatment is carried out on the surface of the plate. Soak the pole plate in an acid corrosion solution at a temperature of 60°C for 10 minutes, so that the surface of the pole plate is initially corroded to form tiny pits, the diameter of which is less than 10 μm. The composition of the acid etching solution is 10wt% nitric acid, 5wt% oxalic acid, and the rest is water.

[0027] C. Ion replacement treatment is performed on the surface of the plate. Soak the pole plate in a copper ion solution at a temperature of 40°C for 5 minutes, so that part of the iron on the surface of the pole plate and in the pits undergoes a substitution reaction wit...

Embodiment 2

[0032] The surface treatment method of the water electrolysis plate of the present embodiment, the specific steps are as follows:

[0033] A. Clean the surface of the carbon steel plate: degreasing, water washing, and pickling in sequence to remove oil, dust, rust, etc. attached to the surface of the plate.

[0034] B. Acid corrosion treatment is carried out on the surface of the plate. Soak the polar plate in the acid corrosion solution at a temperature of 50°C for 15 minutes. The composition of the pre-corrosion solution is 8wt% nitric acid, 8wt% oxalic acid, and the rest is water.

[0035] C. Ion replacement treatment is performed on the surface of the plate. Soak the pole plate in a copper ion solution at a temperature of 40°C for 8 minutes, so that part of the iron on the surface of the pole plate and in the pits undergoes a substitution reaction with copper ions, and copper is precipitated. Described copper ion solution is the copper sulfate solution of 200mg / L.

...

Embodiment 3

[0040] The surface treatment method of the water electrolysis plate of the present embodiment, the specific steps are as follows:

[0041] A. Clean the surface of the carbon steel plate: degreasing, water washing, and pickling in sequence to remove oil, dust, rust, etc. attached to the surface of the plate.

[0042]B. Acid corrosion treatment is carried out on the surface of the plate. Soak the plate in the acid corrosion solution at a temperature of 55°C for 8 minutes. The composition of the pre-corrosion solution is 15wt% nitric acid, 3wt% oxalic acid, and the rest is water.

[0043] C. Ion replacement treatment is performed on the surface of the plate. Soak the polar plate in a copper ion solution at a temperature of 40°C for 5 minutes, so that part of the iron on the surface of the polar plate and in the pits undergoes a substitution reaction with copper ions, and copper is precipitated. Described ion solution is the cupric chloride solution of 300mg / L.

[0044] D. ...

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Abstract

The invention relates to a surface treatment method for a water electrolysis pole plate capable of forming a protective film. The method comprises the following specific steps: A, cleaning the surface of a pole plate made of a carbon steel material; B, soaking the pole plate into an acid corrosion solution at 55 DEG C for 8 minutes, wherein the acid corrosion solution comprises 15wt% of nitric acid, 3wt% of oxalic acid and the balance of water; C, soaking the pole plate into a copper ion solution at 40 DEG C for 5 minutes; D, soaking the pole plate in an alkaline corrosion solution at 40 DEG C for 8 minutes; E, putting the pole plate into a constant-temperature strong acid solution, stirring, and removing impurities on the surface of the pole plate; and F, soaking the pole plate into a treating fluid at 35 DEG C for 12 minutes, taking out, cleaning with clean water, and drying, thereby forming an anti-corrosion protective film on the surface of the pole plate.

Description

[0001] This application is a divisional application. The invention and creation name of the original application: water electrolysis plate surface treatment method, application number: 201210538399.X, application date: 2012-12-13. technical field [0002] The invention relates to a process method for corroding the surface of a carbon steel pole plate and forming a protective film, belonging to the technical field of metal surface treatment. Background technique [0003] Water electrolysis is to decompose water into hydrogen or oxygen under the action of direct current. The electrolyzer is one of the core devices in the whole set of water electrolysis equipment. The water electrolyzers commonly used in industry are composed of dozens to hundreds of electrolysis chambers stacked according to the rules. Each electrolysis cell is composed of an anode plate, an oxygen catalytic electrode, a gas barrier diaphragm, an insulating sealing gasket, a hydrogen catalytic electrode, and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F17/00C23G1/08C23G1/19C23C22/50
Inventor 不公告发明人
Owner BEIHAI CHENGDE METAL ROLLING CO LTD