High-efficiency solar cell module structure
A solar cell and module structure technology, applied in circuits, photovoltaic power generation, photovoltaic modules, etc., can solve problems such as increased time and cost, poor matching or adhesion, unusable light, etc., to improve conversion efficiency, increase The effect of photoelectric conversion efficiency
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example 1
[0076] Example 1: Preparation of SPS
[0077] Compound S (2.11g, 4.8mmol), compound P (0.72g, 2mmol), Pd(PPh 3 ) 4 (0.24g, 0.2mmol) and a stirrer were placed in a 250mL double-necked bottle, and the condenser tube was set up to evacuate, and the gas in the bottle was replaced with argon, and the dehydrated toluene (100ml), 0.05M P t Bu 3 (4mL, 2mmol) and 2M K 2 CO 3 Aqueous solution (5.5mL, 8mmol), stirred under reflux heating (120°C) for three days, filtered the solid and washed with methanol, pure water, ethyl acetate (Ethyl Acetate) and carbon dichloride respectively until golden yellow to obtain golden yellow solid (SPS) (1.02g, 62%).
[0078] 1 H NMR (CDCl 3 ,400MHz)δ8.00(d,J=2.4Hz,4H),7.98(t,J=8.0Hz,4H),7.81~7.77(m,8H),7.62(d,J=8.0Hz,2H), 7.41(t,J=8.0Hz,2H),7.34(t,4H),7.14(s,J=8.0Hz,6H),6.97(d,J=8.0Hz,2H),6,87(d,J =8.0Hz, 4H), 6.78 (d, J=8.0Hz, 2H); HRMS (m / z, FAB+) molecular formula: C66H38, actual molecular weight: 830.2965.
example 2
[0079] Example 2: Preparation of FPF
[0080] Compound F (0.55g, 1.2mmol), Compound P (0.18g, 0.5mmol), Pd(PPh 3 ) 4 (0.06g, 0.05mmol) and a stirrer were placed in a 50mL double-necked bottle, and the condenser was set up to evacuate, and the gas in the bottle was replaced with argon, and the dehydrated toluene (20mL), 0.05M P t Bu 3 (1mL, 0.1mmol) and 2M K 2 CO 3 Aqueous solution (1.375mL, 2mmol), stirred under reflux heating (120°C) for three days, dissolved in chloroform (CHCl 3 ) and water extraction, the organic layer was collected with anhydrous magnesium sulfate (MgSO 4) after removing water, remove the solution with a cyclone concentrator, and carry out column chromatography with a thin gel of the eluent with a mixing ratio of chloroform / n-hexane / toluene of 1 / 8 / 1 to obtain a golden yellow liquid, and use a cyclone concentrator Golden yellow solid (FPF) (0.34g, 78%) was obtained after pumping dry
[0081] 1 H NMR (CD 2 Cl 2 ,400MHz)δ8.15(d,J=4.0Hz,4H),7.98~7...
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