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Multi-phase dual-scale structure aluminum-tin-based composite bearing strip and its preparation method

A composite bushing and dual-scale technology, applied in chemical instruments and methods, metal processing equipment, metal material coating technology, etc. Oxidation and other problems, to achieve the effect of improving the mechanical and tribological properties of the alloy, improving the sintering density, and improving the tribological properties

Active Publication Date: 2017-01-18
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are two main problems in the Al-Sn alloy obtained by casting: (1) the strength of the alloy (HV30~50) is low, and it is difficult to meet the current demand for high strength of the bearing bush; (2) it is easy to serious problems such as gravity segregation
However, for Al-Sn bearings, cast aluminum-tin-based alloys are mainly used to compound steel backs, which is mainly due to the poor sintering performance between powder and powder, powder and steel backs due to the easy oxidation of aluminum, poor bonding strength, and There are three technical deficiencies in the industrial application process of the Al-Sn-based bearing alloy prepared by mechanical alloying: (1) the nanocrystalline powder has high hardness and poor fluidity, and is difficult to be rolled and compounded with the steel back; 2) Since the Al powder particles are easy to oxidize, it is difficult to use the hot rolling method, and at the same time, it is difficult to obtain a high bonding strength with the steel back in cold rolling; (3) The surface of the Al powder particles is easy to absorb water, and more water is produced during the composite rolling process. Bubbles, which seriously affect the bonding strength between the alloy layer and the steel back, etc.

Method used

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  • Multi-phase dual-scale structure aluminum-tin-based composite bearing strip and its preparation method

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preparation example Construction

[0045] The preparation process of the multi-phase double-scale structure aluminum-tin / pure aluminum / steel bearing pad strip of the present invention, such as figure 1 As shown, the preparation method adopts mechanical alloying + cold rolling + sintering process, and the process includes the preparation of multi-phase dual-scale alloy powder, surface treatment of steel back, primary rolling compound, annealing, secondary re-rolling and sintering, etc. The specific process steps are as follows:

[0046] Step (1), utilize mechanical alloying to prepare the Al-12%Sn-Si alloy powder of nanostructure, then mix with the micron coarse-grained Al-12%Sn powder without ball milling and the trace Mg of the nanocrystalline structure of pretreatment, Cu and Si elements are mixed to obtain Al-12%Sn-Si-Mg-Cu mixed powder with multi-phase dual-scale composite structure;

[0047] Step (2), using the flame spraying method to prepare a pure Al layer with a thickness of 50-200 μm on the back surf...

Embodiment 1

[0061] Step 1. Preparation of multiphase dual-scale Al-12%Sn alloy powder

[0062] (1) Mix aluminum powder and tin powder with a particle size of 200 mesh and a purity of 99.5% according to the mass percentage of Al-12% Sn, and use a QM-2SP planetary ball mill for ball milling under the protection of argon, and the ball milling speed is 150rpm / min , the ball milling time is 40h, and the ball-to-material ratio is 20:1 to obtain NC Al-12% Sn alloy powder;

[0063] (2) the particle size is 200 orders, and the aluminum powder and tin powder that purity is 99.5% are uniformly mixed according to the mass percentage of Al-12%Sn, obtains CG Al-12%Sn alloy powder;

[0064] (3) Under argon protection, the magnesium powder with a particle size of 200 mesh and a purity of 99.5% is ball-milled using a QM-2SP planetary ball mill. The ball-milling speed is 250rpm / min, the ball-milling time is 2h, and the ball-to-material ratio is 20: 1. Obtain uniformly refined Mg powder;

[0065] (4) The ...

Embodiment 2

[0081] The steps of this embodiment are basically the same as those in Example 1, except that the NC Al-Sn powder, CGAl-Sn powder and pretreated Mg powder in step one (4), wherein Mg is 0.5% by mass percentage, and the remaining powder The mass percentage is NC:CG=7:3, and the heterogeneous dual-scale structure Al-12%Sn-0.5%Mg mixed powder is obtained. The multi-phase dual-scale structure Al-12%Sn-0.5%Mg mixed powder is evenly spread on the thermal sprayed aluminum steel back, and the multi-phase dual Standard Altin alloy / pure aluminum / steel backed bearing pad strip.

[0082] The multi-phase double-scale aluminum-tin-based alloy / pure aluminum / steel back bearing pad strip cross-sectional structure diagram and microstructure metallographic diagram of the present invention, see Figure 4 with Figure 5 .

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Abstract

The invention provides a multi-phase dual-scale structure Al-Sn-based alloy powder / pure aluminum / steel back composite bearing pad strip, which comprises an upper multi-phase dual-scale structure Al-Sn-based alloy layer, a middle transition pure A three-layer structure consisting of an Al layer and a lower carbon steel back layer; the Al-Sn-based alloy layer is prepared by mechanical alloying and has a multi-phase dual-scale structure Al-Sn-Si-Mg-Cu mixed The powder is composed of: nanocrystalline Al-Sn-Si alloy powder + micron coarse-grained Al-Sn alloy powder + nanocrystalline Cu, Mg, Si and other trace components. The present invention also provides a preparation method of a multi-phase double-scale aluminum-tin-based alloy powder / pure aluminum / steel back composite bearing strip. Preparation of scale alloy powder, surface treatment of steel back, primary rolling compound, annealing, secondary rolling and sintering and other processes. It solves the problems arising in the industrial application process of Al-Sn-based bearing alloy prepared by mechanical alloying in the bearing bush strip, and realizes industrial production.

Description

technical field [0001] The invention belongs to the technical field of powder metallurgy manufacturing, and relates to a processing technology for synthesizing lead-free bearing bush alloy by mechanical alloying method and replacing copper-lead bearing bush strip with high-strength aluminum-tin base, in particular to a multi-phase double-scale structure aluminum-tin-base mixed Powder / pure aluminum / steel back composite bearing pad strip and its preparation method. Background technique [0002] With the development of automobiles in the direction of high performance, the engine is also developing in the direction of high speed, high power, low energy consumption, light weight and high pressure enhancement, and the bearing pad materials of automobiles are also facing high-performance development. At the same time, people's awareness of environmental protection and their own health requirements are increasing day by day. For the toxic lead element, the deleading of bearing produ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B15/01C23C24/06B22F7/04
CPCB22F7/04B32B15/013B32B15/18B32B15/20B32B38/18C23C4/08B32B2255/06B32B2255/205B32B2250/03B22F1/052B32B15/01C23C24/06
Inventor 朱敏曾美琴鲁忠臣高岩欧阳柳章
Owner SOUTH CHINA UNIV OF TECH
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