High-temperature Zr-based brazing filler metal for brazing of W-Cu alloy and stainless steel, as well as preparation method and welding method

A technology of tungsten-copper alloy and stainless steel, which is applied in welding equipment, metal processing equipment, welding/welding/cutting articles, etc., can solve the problem of brittle solid solution phase and brittle compound, which cannot meet the strength requirements of welded joints and affect welded joints Performance and other issues, to achieve the effect of convenient and quick implementation, improved wetting and spreading ability, stable and reliable welded joints

Inactive Publication Date: 2015-08-26
江门市新会区华科电器制品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Patent No.: 201210158935.3 (a tungsten-copper alloy and stainless steel brazing filler metal and brazing process) introduces a tungsten-copper alloy and stainless steel brazing filler metal and a welding process, but the wetting of the brazing filler metal on the surface of tungsten-copper alloy and stainless steel Wetness and fluidity are poor; during the brazing process, element diffusion is uneven, the structure is coarse, and brittle solid solution phases and brittle compounds are prone to appear. The strength of the joint after welding can only reach about 100MPa, which seriously affects the performance of the welded joint.
In the field of modern defense, the use of this solder cannot meet the strength requirements of welded joints

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Vacuum brazing of tungsten copper alloy and austenitic stainless steel butt joint: W-Cu alloy sample size is 20mm×20mm×5mm, austenitic stainless steel is 1Cr18Ni9 stainless steel, size is 20mm×20mm×5mm, the surface to be brazed is 20mm×5mm section.

[0034] The composition and mass percentage ratio of solder are: V: 10%; Nb: 4.0%; Si: 3.2%; Cu: 10%; Ni: 10%; Cr: 11%; Sn: 3.5%; The thickness of the solder is 20 μm.

[0035] The preparation method of the above-mentioned high-temperature zirconium-based solder for brazing tungsten-copper alloy and stainless steel comprises the following steps:

[0036] 1) Weigh 100gV powder, 40gNb powder, 32gSi flakes, 100gCu flakes, 100gNi flakes, 110gCr granules, 35gSn powder and 483gZr granules to make a mixture, and the volume of the mixture is measured to be about 150cm3;

[0037] 2) Add 400ml of acetone to the container containing the mixture, stir to obtain a suspension, and then seal the container;

[0038] 3) Ultrasonic cleanin...

Embodiment 2

[0051] Vacuum brazing of tungsten-copper alloy and austenitic stainless steel butt joints: the size of the tungsten-copper alloy sample is 20mm×20mm×5mm, the austenitic stainless steel is 1Cr18Ni9 stainless steel, the size is 20mm×20mm×5mm, and the surface to be brazed is 20mm ×5mm section.

[0052] The composition of solder: V: 110g; Nb: 80g; Si: 38g; Cu: 150; Ni: 120g; Cr: 130g; Sn: 45g; The thickness is 80 μm.

[0053] The brazing process steps are:

[0054] (1) First clean the surface to be welded of tungsten-copper alloy and stainless steel to remove impurities, oil stains and oxide films on the surface. Grind tungsten-copper alloy and 1Cr18Ni9 stainless steel with metallographic sandpaper, and tungsten-copper alloy, 1Cr18Ni9 stainless steel and solder The foils are placed together in pure acetone and cleaned by ultrasonic method for 15 minutes and then dried;

[0055] (2) Place the cleaned brazing material foil between the tungsten-copper alloy and the 1Cr18Ni9 stainl...

Embodiment 3

[0059] Vacuum brazing of tungsten-copper alloy and austenitic stainless steel butt joints: the size of the tungsten-copper alloy sample is 20mm×20mm×5mm, the austenitic stainless steel is 1Cr18Ni9 stainless steel, the size is 20mm×20mm×5mm, and the surface to be brazed is 20mm ×5mm section.

[0060] The composition and mass percentage ratio of solder are: V: 110g; Nb: 60g; Si: 35g; Cu: 120g; Ni: 105g; Cr: 125g; Sn: 40g; The thickness of the solder prepared by the method is 50 μm.

[0061] The brazing process steps are:

[0062] (1) First: clean the surface to be welded of tungsten-copper alloy and stainless steel to remove impurities, oil stains and oxide films on the surface, grind tungsten-copper alloy and 1Cr18Ni9 stainless steel with metallographic sandpaper, and tungsten-copper alloy, 1Cr18Ni9 stainless steel and solder The foils are placed together in pure acetone and cleaned by ultrasonic method for 10 minutes and then dried;

[0063] (2) Place the cleaned brazing ma...

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Abstract

The invention discloses high-temperature Zr-based brazing filler metal for brazing of W-Cu alloy and stainless steel, as well as a preparation method and a welding method. The high-temperature Zr-based brazing filler metal comprises the following elements by weight: 10 to 12 percent of V, 3.0 to 9.0 percent of Nb, 3.0 to 4.0 percent of Si, 8.0 to 16 percent of Cu, 9.0 to 12 percent of Ni, 11 to 14 percent of Cr, 3.0 to 5.0 percent of Sn, and the balance of Zr. The brazing temperature of the brazing filler metal is 1010 to 1090 DEG C and moderate, so that the brazing filler metal is uniformly melted; tinsel made of the brazing filler metal can accelerate atomic diffusion and interface reaction in a high-temperature connection process, so that the wetting and spreading capabilities of the brazing filler metal are improved, the residual stress in a joint is reduced, and the mechanical property of the joint is improved. Through the adoption of the preparation method of the brazing filler metal, the preparation of the brazing filler metal can be reproduced repeatedly, so as to facilitate popularization and application; through the adoption of the brazing technology provided by the invention, sample pieces are connected through vacuum brazing, wherein the sample pieces are in a vacuum atmosphere while being heated, so that problems such as oxidation and pollution are solved, the surface wetting and spreading capabilities are relatively high, convenience is brought for filling of a brazing seam, the strength of the joint is improved, and the obtained welded joint can be stable and reliable.

Description

technical field [0001] The invention relates to a solder for connecting dissimilar materials, in particular to a zirconium-based high-temperature solder for brazing tungsten-copper alloy and stainless steel, a preparation method and a brazing process, and belongs to the field of welding technology. Background technique [0002] Tungsten-copper alloy material is compatible with the excellent performance of tungsten element and the same element, not only has high thermal conductivity and low thermal expansion coefficient, but also shows good high-temperature strength, thermal shock resistance, ablation resistance and dimensional stability, etc. , often used as high-temperature resistant connectors, heat dissipation substrates, heat sink materials and contact materials, widely involved in electronic packaging, integrated circuits, vacuum switches, processing electrodes, wireless communication devices and other components; in aerospace and national defense military fields, It ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/32B23K35/40B23K1/008B23K1/19B23K1/20B23K103/18
CPCB23K1/008B23K1/19B23K1/206B23K35/30B23K2103/22
Inventor 许祥平王锡岭杨骏杨家旺夏春智邹家生
Owner 江门市新会区华科电器制品有限公司
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