High molecular nano composite film and preparing method thereof
A nano-composite and polymer technology, applied in the field of polymer nano-composite film and its preparation, can solve the problems of small particle size and large surface atomic ratio, easy agglomeration, unstable energy, etc., and achieves stable film-making performance, The effect of low cost and short production cycle
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Embodiment 1
[0043]A kind of macromolecule nanocomposite film of the present invention, comprises polymethyl methacrylate matrix (being PMMA matrix) and the nanometer Cu and [emim] BF dispersed in PMMA matrix 4 (The molecular formula is shown in formula I), that is, the polymer nanocomposite film is specifically Cu / [emim]BF 4 / PMMA film.
[0044]
[0045] A kind of preparation method of the above-mentioned polymer nanocomposite film of the present embodiment, flow process see figure 1 , including the following steps:
[0046] (1) Weigh 1mg of nano-copper powder with an electronic balance. The average particle size of the nano-copper powder is 10nm~30nm, and add it to 10mL[emim]BF 4 In the ionic liquid, under the conditions of air isolation and argon protection, ultrasonically disperse for 2 hours to make it evenly mixed to obtain the first dispersion liquid, namely [emim]BF 4 -Cu sol.
[0047] (2) Weigh 0.06975g of PMMA with an electronic balance and add it into 1ml of dichlorometha...
Embodiment 2
[0057] A polymer nanocomposite film of the present invention, comprising polystyrene matrix (i.e. PS matrix) and nano Cu and [emim] BF dispersed in PS matrix 4 (The molecular formula is shown in formula I), that is, the polymer nanocomposite film is specifically Cu / [emim]BF 4 / PS film.
[0058]
[0059] A preparation method of the polymer nanocomposite film of the above-mentioned present embodiment, comprising the following steps:
[0060] (1) Weigh 1mg of nano-copper powder with an electronic balance. The average particle size of the nano-copper powder is 10nm~30nm, and add it to 10mL[emim]BF 4 In the ionic liquid, under the conditions of air isolation and argon protection, ultrasonically disperse for 2 hours to make it evenly mixed to obtain the first dispersion liquid, namely [emim]BF 4 -Cu sol.
[0061] (2) 0.06975 g of PS was weighed with an electronic balance and added to 1 mL of dichloromethane solvent, ultrasonically dispersed for 2 hours, and mixed uniformly to ...
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