Soap-free polyacrylate textile sizing agent and method for preparing same
A technology of polyacrylate and textile size, which is applied in textiles and papermaking, fiber type, fiber treatment, etc., and can solve the effects of water resistance, poor adhesion, toxic degradation metabolites, and poor biodegradability of the size film. problems, to meet the weaving requirements of water jet looms, easy desizing, and good biodegradability
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Embodiment 1
[0033] Raw materials: acrylic acid, methacrylic acid, methyl methacrylate, methyl acrylate, ethyl acrylate, butyl acrylate, dodecyl mercaptan, water-based polyester, ammonium persulfate, ammonia water, deionized water, of which:
[0034] Acrylic acid 1.5 parts
[0035] 8.5 parts of methacrylic acid
[0036] 28.0 parts of methyl methacrylate
[0037] 34.0 parts of methyl acrylate
[0038] Propylene ethyl ester 13.0 parts
[0039] 15.0 parts of butyl acrylate
[0040] 0.2 parts of dodecyl mercaptan
[0041] 7.0 parts of water-based polyester
[0042] 0.6 parts of ammonium persulfate
[0043] Ammonia 9.15 parts
[0044] 430 parts of deionized water
[0045] resolve resolution:
[0046] (1) Add deionized water into the reaction kettle equipped with a stirrer, thermometer, and reflux condenser at room temperature, start stirring, add water-based polyester, and heat up to 90°C;
[0047] (2) Pump acrylic acid, methacrylic acid, methyl methacrylate, methyl acrylate, ethyl ac...
Embodiment 2
[0050] Raw materials: acrylic acid, methacrylic acid, methyl methacrylate, methyl acrylate, ethyl acrylate, butyl acrylate, dodecyl mercaptan, water-based polyester, ammonium persulfate, ammonia water, deionized water, of which:
[0051] Acrylic acid 3.5 parts
[0052] 6.5 parts of methacrylic acid
[0053] 33.0 parts of methyl methacrylate
[0054] 28.0 parts of methyl acrylate
[0055] 8.0 parts of ethyl acrylate
[0056] 21.0 parts of butyl acrylate
[0057] 0.3 parts of dodecyl mercaptan
[0058] 5.0 parts of water-based polyester
[0059] 0.8 parts of ammonium persulfate
[0060] Ammonia 9.5 parts
[0061] 410 parts of deionized water
[0062] resolve resolution:
[0063] (1) Add deionized water into the reaction kettle equipped with a stirrer, thermometer, and reflux condenser at room temperature, start stirring, add water-based polyester, and heat up to 92°C;
[0064] (2) Pump acrylic acid, methacrylic acid, methyl methacrylate, methyl acrylate, ethyl acrylate...
Embodiment 3
[0067] Raw materials: acrylic acid, methacrylic acid, methyl methacrylate, methyl acrylate, ethyl acrylate, butyl acrylate, dodecyl mercaptan, water-based polyester, ammonium persulfate, ammonia water, deionized water, of which:
[0068] Acrylic acid 2.5 parts
[0069] 7.5 parts of methacrylic acid
[0070] 30.0 parts of methyl methacrylate
[0071] 25.0 parts of methyl acrylate
[0072] Propylene ethyl ester 23.0 parts
[0073] 12.0 parts of butyl acrylate
[0074] 0.25 parts of dodecyl mercaptan
[0075] 6.0 parts of water-based polyester
[0076] 0.7 parts of ammonium persulfate
[0077] Ammonia 9.33 parts
[0078] 420 parts of deionized water
[0079] resolve resolution:
[0080] (1) Add deionized water into the reaction kettle equipped with a stirrer, thermometer, and reflux condenser at room temperature, start stirring, add water-based polyester, and heat up to 91.5°C;
[0081] (2) Pump acrylic acid, methacrylic acid, methyl methacrylate, methyl acrylate, ethyl a...
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