Method for preparing lightweight calcium silicate board

A technology of calcium silicate board and sodium calcium silicate, which is applied in the field of building materials, can solve the problems of high raw material cost, energy consumption, high manufacturing cost, and cumbersome process, and achieve the effects of easy operation, shortened production process, and low density

Active Publication Date: 2015-12-30
INST OF PROCESS ENG CHINESE ACAD OF SCI +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, most of the calcium silicate boards produced in industry are of medium and high density, with a density of 1.1g / cm 3 Above, compared with the low-density lightweight calcium silicate board, there are greater deficiencies in sound insulation, heat insulation, construction, etc.
The existing low-density calcium silicate board generally has a density of 0.6-0.9g / cm 3 Between, SiO in siliceous materials during production 2 Tobermullite crystals are produced by hydrothermal synthesis with CaO in calcareous materials, which usually requires secondary steam curing, and the cost of raw materials, energy consumption and manufacturing costs are relatively high. For such preparation methods, please refer to the patent document CN103449773A, which A disclosed lightweight calcium silicate board and its preparation method; patent document CN102584116A, which discloses an asbestos-free lightweight calcium silicate board and its manufacturing method
[0005] Patent document CN1350993A discloses a kind of manufacturing method like light calcium silicate, and this method can make density in 0.8-1.0g / cm 3 Calcium silicate plate, but it still needs high-temperature steam curing link; patent document CN103449773 discloses a low-density, high-strength, asbestos-free lightweight calcium silicate board preparation method, but the preparation method still includes light The process of sending the body of calcium silicate board into the autoclave for steaming is relatively cumbersome.

Method used

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  • Method for preparing lightweight calcium silicate board

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] see figure 1 , the fly ash is chemically converted to obtain solid slag with sodium calcium silicate as the main component, and its main component is 18.62% Na 2 O, 31.24% SiO 2 and 33.56% CaO. The solid slag is mixed with dilute alkali solution with a NaOH concentration of 1g / L at a mass ratio of 1:30, and then undergoes a dynamic hydrothermal decomposition reaction in a reactor at a reaction temperature of 250°C and a reaction time of 4 hours. The reacted slurry is filtered and washed to obtain a calcium silicate slag. The formula (mass ratio) of each component for preparing the calcium silicate board: the dry weight of the prepared calcium silicate slag is 70wt%, cement is 20wt%, and paper fiber is 10wt%. Accurately weigh each material, add water and mix and stir at 90°C. After the fibers are loosened and the mixture is uniform, the slurry is separated from the liquid to the solid, and the filter cake is pressed into a plate with a designated mold. The molding pr...

Embodiment 2

[0032] The solid slag with sodium calcium silicate as the main component is prepared by chemical transformation from red mud, and its main component is 14.58% Na 2 O, 29.74% SiO 2 and 31.05% CaO. The solid slag is mixed with dilute alkali solution with a NaOH concentration of 10g / L at a mass ratio of 1:15, and then undergoes a dynamic hydrothermal decomposition reaction in a reactor with a reaction temperature of 160°C and a reaction time of 6 hours. The reacted slurry is filtered and washed to obtain a calcium silicate slag. The formula (mass ratio) of each component for preparing the calcium silicate board: dry weight of the prepared calcium silicate slag 50wt%, fly ash 20wt%, gypsum 20wt%, cotton fiber 7wt%, bentonite 3wt%. Accurately weigh each material, add water and mix and stir at 70°C. After the fibers are loosened and the mixture is uniform, the slurry is separated from the liquid to the solid, and the filter cake is pressed into a plate with a designated mold. The...

Embodiment 3

[0034] Using bentonite as raw material to prepare solid slag with sodium calcium silicate as the main component through chemical transformation, the main component is 17.39% Na 2 O, 32.63% SiO 2 and 34.19% CaO. The solid slag is mixed with dilute alkali solution with a NaOH concentration of 50g / L at a mass ratio of 1:10, and then undergoes dynamic hydrothermal decomposition reaction in a reactor with a reaction temperature of 70°C and a reaction time of 40h. The reacted slurry is filtered and washed to obtain a calcium silicate slag. The formula (mass ratio) of each component for preparing the calcium silicate board: the dry weight of the prepared calcium silicate slag is 90wt%, cement 4wt%, paper fiber 3wt%, cotton fiber 3wt%. Accurately weigh each material, add water and mix and stir at 20°C. After the fibers are loosened and the mixture is uniform, the slurry is separated from the liquid to the solid, and the filter cake is pressed into a plate with a designated mold. Th...

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Abstract

The invention discloses a method for preparing a lightweight calcium silicate board. The method comprises the following steps: (1) treating raw materials: mixing calcium sodium silicate raw materials and a dilute alkali solution to obtain mixed slurry; carrying out alkaline hydrolysis on the mixed slurry; after the hydrolysis reaction, separating the solid from liquid to obtain solid calcium silicate slag, wherein the calcium sodium silicate raw materials include one or more of fly ash, red mud, coal gangue, diatomite and bentonite; (2) preparing a mixed material, adding water and mixing uniformly, wherein the mixed material includes calcium silicate slag and reinforced fibers, and the reinforced fibers are paper fibers or cotton fibers; (3) debonding the reinforced fibers, mixing with the mixed material uniformly, and then separating solid from liquid to obtain the filter cake; (4) pressing the filter cake into a board, after formation, demolding the product, so as to obtain wet blank. The calcium silicate board prepared by using the method provided by the invention is small in density, high in strength, not liable to deform, and excellent in fireproof and thermal insulating properties; the method can realize high-valued utilization of high silica raw materials, such as fly ash, is simple and environment-friendly, and adopts a non-pressure steaming process which is economic and easy to implement.

Description

technical field [0001] The invention relates to a method for preparing a calcium silicate board, in particular to a new method for preparing a lightweight calcium silicate board, which belongs to the field of building materials. Background technique [0002] The development trend of the building materials industry is to produce light, high-strength, energy-saving and environmentally friendly building materials, use light and high-strength building materials to reduce the weight of buildings, and improve the level of mechanization and assembly of construction. As a new type of environmentally friendly building material, calcium silicate board has the characteristics of fire prevention, moisture resistance, durability, low deformation rate, and heat insulation. [0003] At present, the traditional calcium silicate board is made of siliceous materials, calcareous materials and adding reinforcing fibers and additives, and is made through mixing pulping, blanking, high-temperatur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/04C04B28/14
Inventor 马淑花马海军刘中凯郑诗礼张懿李重阳
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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