Indoor efficient formaldehyde removing photocatalyst varnish
A photocatalyst and varnish technology, applied in coating, organic compound/hydride/coordination complex catalyst, organic chemistry, etc., can solve the problems of insufficient natural light, low proportion of ultraviolet light, no use value, etc., and reach the contact surface Large, high formaldehyde degradation efficiency, easy to adhere to the effect
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Embodiment 1
[0048] Embodiment 1, the first, the synthesis of four (p-mercaptophenyl) porphyrins;
[0049] (1) Synthesis of tetraphenylporphyrin: Add 0.101mol of benzaldehyde and 250mL of propionic acid into a round-bottomed flask, sonicate until uniform, and heat to reflux at 145°C; add 0.101mol of pyrrole into 30mL of propionic acid , dropwise into the above solution, 20-30min dropwise, reflux for 1h; rotary steaming, remove about 100mL propionic acid, add 100mL ethanol to the bottle, place at 0°C for 12h, suction filter, and collect tetraphenyl by column chromatography base porphyrin.
[0050] (2) Synthesis of tetrakis(p-sulfonylchloridephenyl)porphyrin: put 10mL of chlorosulfonic acid in a round bottom flask, add 0.5g of tetraphenylporphyrin, stir at 0°C for 5h, and rotate at 500r / min; Pour dropwise into a beaker containing 137 grams of ice, neutralize pH = 7 with NaOH solution, remove water by rotary evaporation, dissolve the solid with absolute ethanol, filter with suction, and spin...
Embodiment 2
[0057] Embodiment 2, the synthetic method of tetrakis (p-mercaptophenyl) porphyrin is identical with the method for preparing TiO2-Ag-mercapto porphyrin photocatalyst; Accurately measure 70mL dehydrated alcohol and place it in a 500mL beaker, At a stirring speed of 2000r / min, 30 mL of tetraethyl orthosilicate was added, and the pH of the solution was adjusted to 2 with hydrochloric acid. After stirring for 10 min, 18 mL of distilled water was added, and stirring was continued for 30 min to obtain a silica sol.
[0058] Prepare indoor high-efficiency formaldehyde-removing photocatalyst varnish as follows: (1) Take 150 grams of distilled water, 1.4 grams of ink dispersion aid, TiO 2 -8 grams of Ag-mercaptoporphyrin photocatalyst, 40 grams of silica sol, 0.3 grams of 35% acetic acid solution; (2) Put distilled water in a high-speed disperser, and add 1.4 grams of ink wetting and dispersing agent at a stirring speed of 3000r / min , stir and disperse for 15min; adjust the speed to 3...
Embodiment 3
[0059] Embodiment 3, the synthetic method of tetrakis (p-mercaptophenyl) porphyrin and preparation TiO 2 The method of -Ag-mercaptoporphyrin photocatalyst is the same as that of Example 1; Accurately measure 70mL of absolute ethanol and place it in a 500mL beaker, add 20mL of tetraethyl orthosilicate at a stirring speed of 2000r / min, and adjust with hydrochloric acid The pH value of the solution was 1.1. After stirring for 10 min, 15 mL of distilled water was added, and the stirring was continued for 30 min to obtain silica sol.
[0060] Prepare indoor high-efficiency formaldehyde-removing photocatalyst varnish as follows: (1) Take 180 grams of distilled water, 2 grams of ink dispersion aids, TiO 2 - 10 grams of Ag-mercaptoporphyrin photocatalyst, 50 grams of silica sol, 0.48 grams of 35% acetic acid solution; (2) Put distilled water in a high-speed disperser, and add 2 grams of ink wetting and dispersing agent at a stirring speed of 4000r / min , stir and disperse for 18min; a...
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