A method for strengthening anaerobic dry fermentation of dewatered sludge to produce methane

A technology for dewatering sludge and dry fermentation, applied in dehydration/drying/concentrated sludge treatment, chemical instruments and methods, water/sludge/sewage treatment, etc. Inhibition of the biological functions of the oxygen-methanogenic flora, etc., to reduce the formation and emission of odors, increase the content of soluble nucleic acids, and avoid system crashes

Inactive Publication Date: 2019-05-10
BIOGAS SCI RES INST MIN OF AGRI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Although anaerobic digestion technology has the advantages of reduction, harmlessness, energy recovery and resource recycling for the treatment of municipal sludge, there are still some deficiencies in the treatment of municipal sludge in the prior art: 1. For organic components The utilization rate is not high; 2. It needs a long reaction time; 3. It can only bear a low organic load rate
[0009] However, some problems may arise during the anaerobic digestion process of anaerobic dry fermentation: 1. The pH value of the anaerobic digestion system is lowered due to the rapid acid production stage at the start-up stage, which exceeds the tolerance range of the anaerobic methanogenic bacteria and causes the system to collapse; 2. The tolerable ammonia nitrogen concentration is low, generally only 2500mg / L, such as (Feng Lei, Li Rundong. Journal of Agricultural and Environmental Sciences, 2011, 30(11): 2374-2378), the ammonia nitrogen concentration in the middle and late stages of anaerobic digestion If it is too high, the biological function of the anaerobic methanogenic flora of the system will be inhibited, and the amount of methane produced will decrease
The anaerobic dry fermentation technology of dewatered sludge has not yet been practically applied due to the high difficulty of system operation, difficulty in controlling the anaerobic process, and insufficient research.

Method used

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  • A method for strengthening anaerobic dry fermentation of dewatered sludge to produce methane
  • A method for strengthening anaerobic dry fermentation of dewatered sludge to produce methane
  • A method for strengthening anaerobic dry fermentation of dewatered sludge to produce methane

Examples

Experimental program
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Effect test

Embodiment 1

[0042] Fully mix the dewatered sludge with a water content of 80% and CaO whose weight is 1% of the weight of the dewatered sludge, put it into a steam explosion kettle, and close the valve. Raise the temperature to 180°C, raise the pressure to 1Mpa, and maintain it for 15 minutes. Open the discharge valve, collect the material after instantaneous pressure release, and let it stand for 10 minutes to separate the sediment to obtain pretreated sludge.

[0043] After the steam explosion pretreatment method, the pretreated sludge and the untreated sludge have enhanced solubility and increased hydrolysis degree. The specific results are shown in Table 1:

[0044] Table 1

[0045]

[0046]

[0047] Feed the material proportionally to CO 2 (200L / kgTS), stir well until pH=8.5. Introduce 1% untreated sludge, place it at 30°C for 24 hours under facultative aerobic conditions, and feed 10L / kgTS air at the same time to acidify it.

[0048] Take out the material after acidificati...

Embodiment 2

[0055] Set up an experimental group (hereinafter referred to as CaO steam explosion): fully mix dewatered sludge with a moisture content of 60% and CaO with a weight of 5% of the weight of the dewatered sludge, put it into a steam explosion kettle, and close the valve. Raise the temperature to 200°C, increase the pressure to 1Mpa, and maintain it for 30 minutes. Open the discharge valve, collect the material after instantaneous pressure release, and let it stand for 30 minutes to separate the sediment to obtain pretreated sludge.

[0056] References (C.Park, C.Lee, S.Kim, Y.Chen, H.A.Chase, Upgrading of anaerobic digestion by incorporating two different hydrolysis processes, J.Biosci.Bioeng.100(2)(2005)164–167.) , set up a control group (hereinafter referred to as NaOH high temperature): the same dewatered sludge was mixed with NaOH, maintained at 121 ° C for 30 minutes, and collected after the temperature cooled to obtain NaOH high temperature pretreated sludge.

[0057] Aft...

Embodiment 3

[0075] Set up an experimental group (hereinafter referred to as CaO steam explosion): fully mix dewatered sludge with a moisture content of 70% and CaO with a weight of 3% of the weight of the dewatered sludge, put it into a steam explosion kettle, and close the valve. Raise the temperature to 190°C, increase the pressure to 1.5Mpa, and maintain it for 30 minutes. After the reaction is finished, open the discharge valve, collect the material after instantaneous pressure release, and let it stand for 20 minutes to separate the sediment to obtain pretreated sludge.

[0076] With reference to the method of Chinese patent CN103172237A, a control group (hereinafter referred to as steam explosion) is set up: the same dewatered sludge is directly subjected to steam explosion under the same temperature, pressure and reaction time conditions as the experimental group to obtain steam explosion pretreated sludge.

[0077] The solubility of the pretreated sludge was enhanced, and the degr...

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Abstract

The invention provides a method for strengthening the anaerobic dry fermentation of dewatered sludge to produce methane. The method comprises the following steps: 1) placing the dewatered sludge in a steam explosion kettle, and adding 1-5% of the weight of the dewatered sludge Calcium oxide and stirred evenly, maintained at a temperature of 180-200 °C and a pressure of 1-1.5 MPa for 10-30 minutes, and then released the pressure instantaneously to collect the result; 2) Inoculate the result of step 1), the inoculum was The dewatered sludge that has not been treated in step 1) is subjected to acidogenic fermentation under facultative conditions; 3) adding dry fermentation inoculum and a nutrient solution composed of phosphate and trace elements to the result of step 2), stirring evenly , for anaerobic dry fermentation. The invention can greatly improve the biodegradability of the sludge and greatly increase the methane gas production, the process is simple, no pollution, and has very huge application prospects.

Description

technical field [0001] The invention belongs to the technical field of solid waste treatment, and in particular relates to a method for strengthening anaerobic dry fermentation of dewatered sludge to produce methane. Background technique [0002] With the growth of population, the consumption of urban domestic water is gradually increasing, and the pressure of domestic sewage treatment is also increasing. The activated sludge method is the most efficient and efficient treatment method for sewage treatment plants, but a large amount of municipal sludge will be produced in the process. In order to facilitate post-treatment such as transportation and landfill, these sludges are dehydrated into dewatered sludge with a high solid content. As early as 2007, China's dewatered sludge production reached 4.54×10 6 tons, and this figure is growing at a rate of about 10% per year. Dewatered sludge not only contains a variety of bacterial cells, organic debris and other organic matter...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/00C02F11/04C02F11/13C02F11/145
CPCC02F11/00C02F11/04C02F11/14C02F11/18Y02E50/30Y02W10/20
Inventor 尹小波耿宇聪李强唐治周正邓雅月代莉蓉
Owner BIOGAS SCI RES INST MIN OF AGRI
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