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Microcrystalline glass produced from fly ash through all-electric melting calendaring process and production method thereof

A technology of glass-ceramic and production method, which is applied in glass molding, glass rolling, glass manufacturing equipment, etc., can solve the problems of low production process efficiency, high production cost, and poor flatness of sintering method, and achieve reduction of times Effects of production disasters and secondary pollution, improvement of market competitiveness, and increase in product variety

Active Publication Date: 2016-09-07
四川一名微晶科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The traditional glass-ceramic production mostly adopts the sintering process. The high energy consumption of the sintering process in the production of glass-ceramics has always been a key bottleneck restricting the rapid development and large-scale production of glass-ceramics.
The production of glass-ceramic by sintering process and the use of expensive non-ferrous metal zinc oxide raw materials have kept the production cost of many glass-ceramic enterprises at a high level. At the same time, the production process efficiency of sintering method is low, and the products have pores and poor flatness. , sintering process glass-ceramic enterprises operating conditions have always been difficult

Method used

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  • Microcrystalline glass produced from fly ash through all-electric melting calendaring process and production method thereof

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Experimental program
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Effect test

Embodiment 1

[0046] A preparation method of glass-ceramic, it comprises the following steps:

[0047](1) Weigh 322.2kg of fly ash, 114.3kg of light burnt magnesium, 58.2kg of heavy calcium, 43kg of soda ash and 2.2kg of titanium dioxide. After mixing evenly, add 10.75kg of water and mix for 6 minutes to obtain a mixture; send the mixture to Melted in an all-electric melting furnace, the melting temperature is 1430 ° C, the melted glass is clarified and homogenized at 1380 ° C, and the total time of melting, clarification and homogenization is 8 hours;

[0048] (2) The clarified and homogenized mixture enters the material channel through the liquid flow hole and the ascending channel of the all-electric melting furnace, and the temperature is controlled at 1250-1300 °C; then after cooling down through the material channel, it enters the calender at a forming temperature of Calendering at 1100°C;

[0049] (3) The formed glass ribbon enters the annealing kiln for annealing through the convey...

Embodiment 2

[0054] A preparation method of glass-ceramic, it comprises the following steps:

[0055] (1) Weigh 344.8kg of fly ash, 109.8kg of light burnt magnesia, 57.2kg of heavy calcium, 43.5kg of soda ash and 2.2kg of titanium dioxide. After mixing evenly, add 11.1kg of water and mix for 6 minutes to obtain a mixture; Send it into an all-electric melting furnace for melting, the melting temperature is 1400°C, the melted glass is clarified and homogenized at 1350°C, and the total time of melting, clarification and homogenization is 6 hours;

[0056] (2) The clarified and homogenized mixture enters the material channel through the liquid flow hole and the ascending channel of the all-electric melting furnace, and the temperature is controlled at 1250-1300 °C; then after cooling down through the material channel, it enters the calender at a forming temperature of Calendering at 1150°C;

[0057] (3) The formed glass ribbon enters the annealing kiln for annealing through the conveying roll...

Embodiment 3

[0062] A preparation method of glass-ceramic, it comprises the following steps:

[0063] (1) Weigh 323.2kg of fly ash, 98.7kg of light burnt magnesium, 64.9kg of heavy calcium, 43.5kg of soda ash and 2.2kg of titanium dioxide. After mixing evenly, add 10.75kg of water and mix for 6 minutes to obtain a mixture; Send it into an all-electric melting furnace for melting, the melting temperature is 1430°C, the melted glass is clarified and homogenized at 1330°C, and the total time of melting, clarification and homogenization is 9 hours;

[0064] (2) The clarified and homogenized mixture enters the material channel through the liquid flow hole and the ascending channel of the all-electric melting furnace, and the temperature is controlled at 1250-1300 °C; then after cooling down through the material channel, it enters the calender at a forming temperature of Calendering at 1090°C;

[0065] (3) The formed glass ribbon enters the annealing kiln for annealing through the conveying rol...

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Abstract

The invention discloses a microcrystalline glass produced from fly ash through an all-electric melting calendaring process, and a production method thereof. The microcrystalline glass is prepared from 320 to 350 parts by weight of fly ash used as a main raw material and accessory materials consisting of 98 to 115 parts by weight of light-burnt magnesia, 55 to 66 parts by weight of ground calcium carbonate, 42 to 44 parts of sodium carbonate and 2 to 3.5 parts by weight of titanium dioxide by using the all-electric melting calendaring process. The production method mainly comprises the following steps: mixing and melting of the raw materials; calendaring and molding; annealing; nucleation and crystallization; and surface treatment. The production method provided by the invention can consume a great amount of slag waste, turn the waste into the valuable, improve the environment and promote economic development; the production method also realizes green manufacturing, broadens the application space of the calendared microcrystalline glass as a base material and guides consumers to carry out green consumption; and the production method increases the varieties of microcrystalline glass products, improves market competitiveness of microcrystalline glass products and maximally meets consumption demands of different industries and different populations.

Description

technical field [0001] The invention relates to a building material and a production method thereof, in particular to a glass-ceramic produced by using fly ash as a raw material by an all-electric melting calendering process and a production method thereof. Background technique [0002] Glass-ceramics, also known as glass-ceramics, has become the focus of new inorganic materials research because it has both the physical and chemical characteristics of glass and ceramics. A wide variety of glass-ceramic products can be prepared through different technological means, which are widely used in the fields of aerospace, biomedicine, chemical industry, and architectural decoration. Glass-ceramics has excellent physical properties and stable chemical properties, meeting the environmental protection and health needs in the field of architectural decoration; the needs of wear resistance, corrosion resistance, and impact resistance in the industrial field, and the application needs of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C10/14C03B13/00
CPCC03B13/00C03C10/0045C03C10/0063
Inventor 秦刚秦小平姜小元王刚琳徐国梁熊冰峰彭文钢
Owner 四川一名微晶科技股份有限公司
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