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Polypropylene film split fiber, preparation method and air filter material prepared therefrom

A polypropylene film and fiber technology, applied in fiber treatment, fiber chemical characteristics, rayon manufacturing, etc., can solve the problems of low elongation at break, poor film toughness, easy fluffing, etc., and achieve elongation at break and fibril The degree of fiberization is large, the strength and elongation at break are improved, and the effect of promoting fiber fibrillation

Active Publication Date: 2018-01-23
SHENZHEN SELEN SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Since the polypropylene material is a highly crystalline material, the film prepared with it has poor toughness, low elongation at break, and significant tensile fracture phenomenon. It is easy to produce wool and broken filaments during fiber opening, and it is difficult to open fibers continuously. Thinner films and microfibers are produced, so they need to be modified to toughen and promote their fibrillation
Commonly used toughening modification methods such as adding inorganic powder, polyethylene or other polymer elastomers, these toughening modification methods are difficult to improve the fiber strength, toughness and processing conditions while improving the fibril properties of polypropylene fibers. The prepared membrane split fiber web has a dense structure, and as an air filter material, the airflow resistance is large, and the effect of high efficiency and low resistance cannot be achieved.
The film-split fiber prepared by the traditional film-split method has poor uniformity and stability of the fiber product fineness, and the degree of fibrillation is low. At the same time, the fibrillation process is prone to fluff, breakage, and winding rolls.

Method used

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  • Polypropylene film split fiber, preparation method and air filter material prepared therefrom
  • Polypropylene film split fiber, preparation method and air filter material prepared therefrom
  • Polypropylene film split fiber, preparation method and air filter material prepared therefrom

Examples

Experimental program
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Effect test

Embodiment 1

[0039] Prepare the polypropylene membrane split fiber of this embodiment according to the following steps:

[0040] (1) Surface modification of nano-silica powder with hyperbranched polyurethane resin to obtain modified nano-silica;

[0041] (2) Preparation of film masterbatch:

[0042] Layer A film masterbatch: 100 parts of PP pellets, 25 parts of POE particles, 0.5 parts of compatibilizer PP-g-MAH, 10 parts of modified nano-silica, 0.4 parts of antioxidant 1010, 0.1 parts of antioxidant 168 , light stabilizer GW-540 0.15 parts, the above-mentioned ingredients are fully mixed in a high-speed mixer at a low speed, and then melted and plasticized by a twin-screw extruder, extruded, water-cooled, air-dried, pelletized, and dried to obtain a layer of film mother grain;

[0043] B-layer film masterbatch: 100 parts of POE granules, 10 parts of modified nano-silica, 0.2 parts of antioxidant Irganox1010, 0.05 parts of light stabilizer GW-540, fully mix the above ingredients in a hi...

Embodiment 2

[0052] (1) surface modification of nano titanium dioxide and nano tourmaline powder with hyperbranched polyether resin to obtain modified nano titanium dioxide and nano tourmaline;

[0053] (2) Preparation of film masterbatch:

[0054] Layer A film masterbatch: 100 parts of PP granules, 45 parts of POE particles, 1.5 parts of compatibilizer POE-g-MAH, 10 parts of modified nano titanium dioxide, 10 parts of modified nano tourmaline powder, 0.8 parts of antioxidant 1076, 0.2 parts of antioxidant 1035, 0.3 parts of light stabilizer 770, the above ingredients are fully mixed in a high-speed mixer at a low speed, and then melted and plasticized by a twin-screw extruder, extruded, water-cooled, air-dried, pelletized, and dried to obtain A-layer film masterbatch;

[0055] B-layer film masterbatch: 100 parts of POE granules, 10 parts of modified nano-titanium dioxide, 0.4 parts of antioxidant 1076, and 0.4 parts of light stabilizer. The extruder is melted and plasticized, extruded, ...

Embodiment 3

[0064] (1) surface modification of nano-titanium dioxide and nano-silicon dioxide with hyperbranched polyamide resin to obtain modified nano-titanium dioxide and nano-silicon dioxide;

[0065] (2) Preparation of film masterbatch:

[0066] Layer A film masterbatch: 100 parts of PP granules, 75 parts of POE granules, 3.5 parts of compatibilizer PP-g-GMA, 5 parts of modified nano titanium dioxide, 10 parts of modified nano silicon dioxide, 1.2 parts of antioxidant 2246 , 0.3 parts of antioxidant 626, 9440.5 parts of light stabilizer, the above-mentioned ingredients are fully mixed in a high-speed mixer at a low speed, and then melted and plasticized by a twin-screw extruder, extruded, water-cooled, air-dried, pelletized, and dried to obtain A-layer film masterbatch;

[0067] Layer B film masterbatch: 100 parts of POE particles, 5 parts of modified nano titanium dioxide, 10 parts of modified nano silicon dioxide, 0.8 parts of antioxidant 2246, 0.2 parts of antioxidant 626, 0.05 p...

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Abstract

The invention discloses polypropylene film splitting fibers and a preparation method thereof. The polypropylene film splitting fibers are mainly prepared from raw materials including PP (Polypropylene) granular materials, POE (Polyolefin Elastomer) granular materials, a compatibilizer, modified nano powder, an antioxidant, a light stabilizer and the like. The polypropylene film splitting fibers are prepared through processes: grafting the modified nano powder on the surface of a hyperbranched polymer; then, sequentially preparing a thin film master batch and a modified thin film material; then, coextruding double layers or three layers of thin film materials to form a composite thin film; carrying out multi-roller stretching, heating by an infrared drying oven, mechanically splitting films and splitting fibers, carrying out heat setting and the like; the prepared film splitting fibers have higher fibrillation degree, breaking strength and initial modulus and have a large-pore-diameter and multi-channel fluffy structure. The polypropylene film splitting fibers disclosed by the invention can be used as a matrix material for preparing an air filtering material and the high efficiency and low resistance effects can be realized.

Description

technical field [0001] The invention relates to the field of thermoplastic polyolefin fibers, in particular to a high-strength, high-fibrillation degree thermoplastic polypropylene film fiber capable of electrostatic electret treatment and a preparation method thereof. Background technique [0002] The manufacturing process of fiber nonwoven materials is divided into 6 processes of fiber preparation, web forming, bonding, heat setting, finishing and packaging. The production process includes dry method, wet method, spinning method, acupuncture method, stitching method , spunbond method, melt blown method, film splitting method and electrospinning method, etc. Among them, the non-woven materials produced by the dry process are prone to electrostatic charge accumulation and are not resistant to alkali; the wet process consumes a lot of water and the possibility of variety change is small; the non-woven materials produced by the spinning process cannot be degraded and are easy ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/06D01F1/10D01D5/42D01D1/04
CPCD01D1/04D01D5/426D01F1/10D01F8/06
Inventor 胡树郭辉
Owner SHENZHEN SELEN SCI & TECH CO LTD
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