Conductive adhesive composition
A conductive and bonding agent technology, applied in the direction of conductive adhesives, adhesive types, adhesive additives, etc., can solve the problems of electronic parts damage, printed substrate distortion, etc., and achieve the effect of strong adhesion
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[0168] The present invention will be specifically described below based on examples, but the present invention is not limited by these examples. In addition, "part" and "%" in an Example and a comparative example represent a mass standard unless otherwise indicated.
[0169] (1) Production of polyurethane (polyurea) resin (F)
Synthetic example 1
[0171] A stirrer, a reflux condenser, a thermometer, a nitrogen sparging tube, and a reaction vessel with a manhole were prepared. The inside of the reaction vessel was replaced with nitrogen, and then 1.4 g of dimethylolpropionic acid (DMPA) and polyhexamethylene carbonate diol (trade name "Praccel CD220", DAICEL Co., Ltd.) were added. Produced by the company, the number average molecular weight obtained by quantifying the terminal functional group (terminal functional group) is 200.0g, and dimethylformamide (DMF) 83.5g, and then add isophorone diisocyanate (isophorone diisocyanate) (IPDI) 49.0g (with respect to OH group, NCO group is 2 times equivalent (equivalent)), heated to 90°C, and reacted until NCO% reached 2.8%, to obtain urethane Prepolymer (prepolymer). Next, DMF83.5g was added, and it cooled to below 40 degreeC.
[0172] Then, 17.5 g of isophorone diamine (IPDA) was diluted with 175 g of a mixed solvent obtained by mixing DMF / Isopropyl Alcohol (IPA) at a ratio of...
Synthetic example 2
[0175] Dimethylolpropionic acid (DMPA), isophorone diisocyanate (IPDI), dimethylformamide (DMF) and dimethylformamide (DMF ) / Isopropyl alcohol (Isopropyl alcohol) was added in the amount described in Table 1. Others were synthesized in the same manner as in Synthesis Example 1 to obtain an acid value of 26.4 mgKOH / g and a weight average molecular weight of 65,000. , A polyurethane (polyurea) resin (F-2-1) with a solid content of 30% (DMF / Isopropyl Alcohol).
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