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Composite super capacitor diaphragm material with good isolation performance

A technology for supercapacitors and diaphragm materials, which is applied in the manufacture of hybrid capacitor separators and hybrid/electric double-layer capacitors, etc., can solve the problems of technical difficulties in the manufacture of high-performance diaphragm paper, poor electrolyte affinity, and low porosity. Improved mechanical strength, uniform discharge current, and high porosity

Inactive Publication Date: 2016-11-16
ANHUI JIANGWEI PRECISION IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the materials used for supercapacitor separators mainly include cellulose separator paper and traditional battery separators. High-performance separator paper is difficult to manufacture and expensive; The manufacturing technology of spun nanofiber membrane is simple, low cost, the porosity of the diaphragm is as high as 90%, and the affinity to the electrolyte is good, but the disadvantage is that the strength is not high

Method used

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Embodiment Construction

[0016] A composite supercapacitor diaphragm material with good isolation performance, made of the following raw materials in parts by weight (kg): polyvinyl alcohol fiber 35, polypropylene fiber 33, polyacrylonitrile powder 10, acetone 30, N, N dimethyl Formamide 72, 70°C water-soluble PVA fiber 8, cationic starch 4, glass wool 4, liquid paraffin 2, polydimethylsiloxane 1.5, clay 9, palmitic acid 2, polyester rubber powder 3.

[0017] According to claim 1, a composite supercapacitor diaphragm material with good isolation performance is prepared by the following specific methods:

[0018] (1) Mix acetone and N, N dimethylformamide evenly at room temperature, add polyacrylonitrile powder, and stir at room temperature for 3 hours at a speed of 100 rpm to form a polyacrylonitrile spinning solution. Electrospinning was carried out for 2 hours under the conditions of a distance of 20 cm, a voltage of 25 kV, and a liquid supply rate of 1 mL / h, and a polyacrylonitrile nanofiber membra...

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PUM

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Abstract

The invention discloses a composite super capacitor diaphragm material with good isolation performance. The composite super capacitor diaphragm material is prepared from the following raw materials in parts by weight: 35-40 parts of polyvinyl alcohol fibers, 33-35 parts of polypropylene fibers, 10-13 parts of polyacrylonitrile powder, 30-32 parts of acetone, 72-75 parts of N,N-dimethyl formamide, 8-10 parts of water-soluble PVA fibers at 70 DEG C, 4-5 parts of cationic starch, 4-5 parts of glass wool, 2-3 parts of liquid paraffin, 1.5-2 parts of dimethylsiloxane, 9-11 parts of clay, 2-3 parts of palmitic acid and 3-4 parts of polyester adhesive powder. The ingredients of the glass wool, the clay and the like are also added to preparation of a product through a series of modified additives, so that the breathability is good; the mechanical strength of the product is improved; the high-temperature tolerance is improved; the super capacitor material can also keep a good isolating state at a high temperature; and the service lifetime of a super capacitor is prolonged.

Description

technical field [0001] The invention relates to the technical field of capacitor diaphragms, in particular to a composite supercapacitor diaphragm material with good isolation performance. Background technique [0002] Supercapacitor is a highly competitive energy storage device. Because it can realize fast charging, high current discharge, and has a charging life of more than 100,000 times, it plays an important role in some applications that require short-term high-rate discharge. . The power supply requirements of hybrid electric vehicles and electric vehicles have also aroused worldwide attention to supercapacitors, a new type of energy storage device. In the composition of supercapacitors, electrodes, electrolyte and separator paper play a decisive role in the performance of supercapacitors. At present, the electrodes and electrolytes of supercapacitors are research hotspots, but the research and attention on separators is not high. [0003] The separator paper of th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/52H01G11/84
CPCH01G11/52H01G11/84Y02E60/13
Inventor 赵鑫鲍启兵褚诗泉
Owner ANHUI JIANGWEI PRECISION IND
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