This invention provides a composite
nanofiltration membrane, its preparation method, and its application, belonging to the field of
pollutant removal technology. The invention first coats the surface of a macroporous base membrane with a high molecular weight
polyelectrolyte system to cover the macropores, then fills the micropores of the base membrane with a low molecular weight
polyelectrolyte. This improves the
retention rate of micropollutants in the layer-by-layer self-assembled membrane, reducing pore size while maintaining high permeability. This invention prepares a multilayer composite
nanofiltration membrane by
coating polyelectrolyte systems of different molecular weights onto a high-
porosity base membrane and repeating the
coating process. The prepared composite
nanofiltration membrane achieves a removal rate of over 90% for micropollutants with a molecular weight of around 200 Da, with a maximum removal rate of 99.8%.