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Lithium battery graphene conductive paste and preparation method thereof

A technology of conductive paste and graphene, which is applied in the direction of battery electrodes, circuits, electrical components, etc., can solve the problems of difficult dispersion of conductive agents and poor conductivity, so as to improve charge and discharge efficiency, increase carrier concentration, and protect integrity Effect

Active Publication Date: 2016-12-07
上海银浆科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Aiming at the defects that the conductive agent used in the current power lithium battery is difficult to disperse and the conductivity is poor, the present invention provides a graphene conductive paste that is easy to disperse, which not only has a simple preparation process, but also has stable storage and has the same Good dispersion and compatibility, so as to form a conductive network and improve the charge and discharge efficiency of active materials

Method used

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  • Lithium battery graphene conductive paste and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] (1) Mix 10 parts by weight of graphite powder and 0.5 parts by weight of activator lithium carboxylate evenly at 200-250°C, then send them into a high-speed centrifugal jet mill, and generate high-speed swirling flow in the pulverization chamber of the jet micromachine , causing intense collision and friction between the graphite powder particles, thereby pulverizing and homogenizing, and making the graphite powder particles undergo activation modification;

[0058] (2) Combine the material obtained in step (1) with 0.1 parts by weight of carbon nanotubes, 1 part by weight of dispersant styrene maleimide resin, 0.1 parts by weight of micron-scale accelerator vanadium pentoxide, 0.2 parts by weight The colloidal material gelatin in parts by weight is dispersed and stripped in a sand mill, and is circularly ground under the shear force and friction of the sand mill. The micron-scale accelerator acts as a microscopic force transmission medium to make graphite be stripped in...

Embodiment 2

[0063] (1) Mix 10 parts by weight of natural flake graphite and 2 parts by weight of activator sodium carboxylate evenly at 200-250°C, then send them into a flat jet mill, and generate high-speed whirl in the flat jet mill pulverization chamber. The flow causes intense collision and friction between the graphite powder particles, thereby pulverizing and homogenizing, so that the graphite powder particles can be activated and modified;

[0064] (2) The material obtained in step (1) is mixed with 0.2 parts by weight of carbon nanotubes, 0.5-1 parts by weight of dispersant sodium lauryl sulfate, and 0.05 parts by weight of accelerator 2-5 micron diboride Titanium and 0.2 parts by weight of the colloidal material xanthan gum are dispersed and stripped in a planetary ball mill, and are cyclically ground under the shear force and friction of the grinding unit. The micron-scale accelerator acts as a microscopic force transmission medium to make the graphite stripped into graphene. At...

Embodiment 3

[0069] (1) Mix 8 parts by weight of expanded graphite and 1 part by weight of activator lithium carboxylate evenly at 200-250°C, and then send them into a circulating tube jet mill, where high-speed The swirling flow causes intense collision and friction between the graphite powder particles, thereby pulverizing and homogenizing the graphite powder particles for activation and modification;

[0070] (2) Combine the material obtained in step (1) with 0.3 parts by weight of carbon nanotubes, 0.5 parts by weight of dispersant sodium dodecylbenzenesulfonate, 0.04 parts by weight of accelerator micron-sized boron oxide, 0.2 parts by weight Part of the colloidal material guar gum is dispersed and stripped in the agitating grinder, and is circularly ground under the action of the shear force and friction of the agitating grinder. The micron-scale accelerator acts as a microcosmic force transmission medium to make the graphite be stripped into graphene, and at the same time Micron-sca...

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Abstract

The invention provides a lithium battery graphene conductive paste. The lithium battery graphene conductive paste is characterized by consisting of 10 to 15 parts of graphite power, 0.5 to 2 parts of active agent, 0.5 to 1 part of dispersing agent, 0.2 to 0.3 parts of colloid material, 0.1 to 0.5 parts of carbon nano tube, 0.01 to 0.1 part of accelerant, 85 to 90 parts of solvent, and moderate viscosity modifier. By refining and activating graphite and further dispersing, grinding and stripping the graphite, and under the action of shear force and friction force of a grinding unit, a micron-grade accelerant is used as a micro force transfer medium, so that the graphite is stripped into the graphene, and meanwhile, the micron-grade accelerant, the graphene and the carbon nano tube are interweaved by the colloid material in the grinding process to form a composite micro colloidal particle; the composite micro colloidal particle has an excellent dispersibility in lithium battery anode and cathode active materials, so that the charge discharge efficiency of the active materials is substantially improved; and besides, the composite micro colloidal particle is compounded with the graphene and used for a lithium battery conductive agent, thus the carrier concentration can be remarkably improved, and the conductivity and discharge capacity of the battery active materials can be improved.

Description

technical field [0001] The invention relates to the field of lithium battery conductive materials, in particular to graphene conductive paste, and further relates to a preparation method of graphene conductive paste. Background technique [0002] At present, the positive electrode active materials used in lithium-ion batteries are mostly transition metal oxides or transition metal phosphates (lithium iron phosphate), which are semiconductors or insulators with poor conductivity, so conductive agents must be added to improve conductivity; The conductivity of the negative electrode graphite material is slightly better, but during repeated charge and discharge, the expansion and contraction of the graphite material reduces the contact between the graphite particles, increases the gap, and even some of them separate from the collector, becoming a dead active material and no longer participating Electrode reaction, so it is also necessary to add a conductive agent to maintain the...

Claims

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Application Information

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IPC IPC(8): H01M4/133H01M4/1393
CPCH01M4/133H01M4/1393Y02E60/10
Inventor 陈庆曾军堂
Owner 上海银浆科技有限公司
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