Surface-treated metal, surface treatment method of metal and metal and resin composite body

A surface treatment and metal technology, which is applied in the field of metal and resin composites, can solve the problems of large product size, reduce the bonding strength of aluminum alloy and resin, and fall off, so as to increase the contact probability, improve the connection strength, and enhance the bonding force Effect

Active Publication Date: 2016-12-14
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional solution is to use adhesives or create a large number of rivets, undercuts, holes, etc. However, these methods have some problems: for example, the adhesive has poor acid and alkali resistance, and the composite cannot be subjected to subsequent surface treatment; Using methods such as riveting will not only increase the process flow, but also produce larger products, and the bonding strength of the metal-resin composite obtained later is not high
[0003] With the continuous development of technology, a new metal and resin integration method appeared later, that is, through soaking, etching and other methods, nano-scale holes are corroded on the surface of metal (such as aluminum alloy), and finally injection molding combines resin and aluminum Alloys are combined together to obtain an aluminum-plastic integrated product with a certain tensile and shear strength. The corrosion liquid u

Method used

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  • Surface-treated metal, surface treatment method of metal and metal and resin composite body
  • Surface-treated metal, surface treatment method of metal and metal and resin composite body
  • Surface-treated metal, surface treatment method of metal and metal and resin composite body

Examples

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Example Embodiment

[0046] Example 1

[0047] Pre-treatment: Cut a commercially available 1mm thick 5052 aluminum alloy plate into 450mm*150mm rectangular pieces, put it in an acetone solution, ultrasonically clean for 15 minutes, and rinse with deionized water to obtain pre-treated aluminum Alloy sheet.

[0048] Multi-stage anodic oxidation treatment:

[0049] 1. Put the aluminum sheet with conventional surface pretreatment as the anode into the electrolytic cell for polishing. The electrolyte is a mixed solution of perchloric acid and ethanol with a volume ratio of 1:3, and electrolysis at a constant voltage of 40V for 3 minutes;

[0050] 2. Use the metal substrate as the anode in 0.8M oxalic acid solution, voltage 40V, temperature 50°C, treatment for 0.6h;

[0051] 3. The composition is 2% H 2 CrO 4 +10%H 3 PO 4 Soak in the chromium-phosphorus mixed acid solution for 25min, maintain the temperature at 50℃ during soaking, and then rinse with deionized water;

[0052] 4. Continue to use the metal substrat...

Example Embodiment

[0058] Example 2

[0059] Pre-treatment: Cut a commercially available 1mm thick 5052 aluminum alloy plate into 450mm*150mm rectangular pieces, put it in an acetone solution, ultrasonically clean for 15 minutes, and rinse with deionized water to obtain pre-treated aluminum Alloy sheet.

[0060] Multi-stage anodic oxidation treatment:

[0061] 1. Put the aluminum sheet with conventional surface pretreatment as the anode into the electrolytic cell for polishing. The electrolyte is a mixed solution of perchloric acid and ethanol with a volume ratio of 1:3, and electrolysis at a constant voltage of 40V for 3 minutes;

[0062] 2. Use the metal substrate as the anode in 0.8M oxalic acid solution, voltage 40V, temperature 50°C, treatment for 0.6h;

[0063] 3. The composition is 2% H 2 CrO 4 +10%H 3 PO 4 Soak in the chromium-phosphorus mixed acid solution for 25min, maintain the temperature at 50℃ during soaking, and then rinse with deionized water;

[0064] 4. Continue to use the metal substrat...

Example Embodiment

[0070] Example 3

[0071] Pre-treatment: Cut a commercially available 1mm thick 5052 aluminum alloy plate into 450mm*150mm rectangular pieces, put it in an acetone solution, ultrasonically clean for 15 minutes, and rinse with deionized water to obtain pre-treated aluminum Alloy sheet.

[0072] Multi-stage anodic oxidation treatment:

[0073] 1. Put the aluminum sheet with conventional surface pretreatment as the anode into the electrolytic cell for polishing. The electrolyte is a mixed solution of perchloric acid and ethanol with a volume ratio of 1:3, and electrolysis at a constant voltage of 40V for 3 minutes;

[0074] 2. Use the metal substrate as the anode in 0.8M oxalic acid solution, voltage 40V, temperature 50°C, treatment for 0.6h;

[0075] 3. The composition is 2% H 2 CrO 4 +10%H 3 PO 4 Soak in the chromium-phosphorus mixed acid solution for 25min, maintain the temperature at 50℃ during soaking, and then rinse with deionized water;

[0076] 4. Continue to use the metal substrat...

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Abstract

The invention discloses surface-treated metal, a surface treatment method of the metal and a metal and resin composite body. A hole used for filling of resin perpendicularly extends towards the interior of the metal from the surface of the metal, any position of the hole is expanded outwards or shrunk inwards, a cavity structure with the unequal hole diameter is formed, and through the cavity structure, the metal and the resin can form a better nano anchor bolt effect, and the connecting strength of the metal and resin composite body can be effectively improved; a multistage anodic oxidation method is adopted in the metal to treat the surface of the metal, the method is efficient, environment-friendly, reliable and high in repeatability, bonding force between a resin layer and a metal base material of the metal resin composite body is good, the excellent tensile shear strength is achieved, the resin source is wide, the method is suitable for industrial large-scale production, and the problem that according to an existing method, the defective percentage stays at a high level is solved.

Description

technical field [0001] The invention relates to a metal and its surface treatment method, as well as a composite body of the metal and resin after surface treatment. Background technique [0002] At present, in practical applications, it is often necessary to solve the problem of combining metal and resin. The traditional solution is to use adhesives or create a large number of rivets, undercuts, holes, etc. However, these methods have some problems: for example, the adhesive has poor acid and alkali resistance, and the composite cannot be subjected to subsequent surface treatment; The use of methods such as riveting will not only increase the process flow, but also produce a larger product size, and the bonding strength of the metal-resin composite obtained subsequently is not high. [0003] With the continuous development of technology, a new metal and resin integration method appeared later, that is, through soaking, etching and other methods, nano-scale holes are corrod...

Claims

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Application Information

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IPC IPC(8): B29C45/14B29C45/17C25D11/02
CPCB29C45/14B29C45/17C25D11/02
Inventor 陈葳薛奇刘婧雯王晓亮周东山
Owner NANJING UNIV
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