Production method of polystyrene multi-component copolymerization ion exchange resin for removing anionic dye

A technology of ion exchange resin and anionic dye, applied in the direction of ion exchange water/sewage treatment, chemical instruments and methods, water pollutants, etc. Insufficient strength, limited application range, etc., to achieve the effect of improving heat resistance, high mechanical strength, and wide application range

Inactive Publication Date: 2016-12-21
ANHUI WANDONG CHEM
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  • Abstract
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Problems solved by technology

However, this type of resin has low thermal stability and is greatly affected by the use temperature, which limits its application range. It also has poor chemical stability, poor mechanical strength, and especially poor compression resistance, which also affects its service life. , so it is necessary to improve its comprehensive performance
CN201310172597 introduces the copolymerization of long-chain flexible monomer octadecyl methacrylate and styrene, thereby improving the compressive strength of ion exchange resin microspheres, but this method can only improve the compressive performance of polystyrene resin, and cannot comprehensively improve Its uniformity, thermal stability, chemical stability and other comprehensive properties are difficult to meet the current demand for higher quality ion exchange resins, and its application range is limited

Method used

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Embodiment Construction

[0013] A production method for removing anionic dyes with polystyrene multi-component copolymerization ion exchange resin, the method comprises the following specific steps:

[0014] (1) Preparation of the water phase, the water phase is prepared from the following raw materials in parts by weight: polyethylene glycol 0.5, nano-magnesium oxide 0.5, polysorbate-80 0.1, gelatin 0.5, hexadecyl trimethyl Ammonium bromide 0.1, water 80, the preparation process of the water phase is to mix and grind nano-magnesium oxide, polysorbate-80 and cetyltrimethylammonium bromide evenly, then add water and stir and disperse for 5min, and finally Add the rest of the raw materials and mix and dissolve evenly to obtain the water phase;

[0015] (2) Preparation of the oil phase, the oil phase is prepared from the following raw materials in parts by weight: styrene 40, divinylbenzene 5, benzoyl peroxide 0.5, methyl methacrylate 3, vinyl trimethoxy base silane 3, liquid paraffin 2,3-aminopropyltri...

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Abstract

The invention discloses a production method of polystyrene multi-component copolymerization ion exchange resin for removing anionic dye. The method comprises the specific steps of preparation of a water phase and an oil phase, preparation of composite resin microspheres and synthesis of the ion exchange resin, wherein a resin microsphere framework is prepared by crosslinking styrene, methyl methacrylate and vinyl trimethoxy silane. The polystyrene multi-component copolymerization ion exchange resin has the good high temperature resistance and chemical stability resistance and is wide in application range, high in mechanical strength, good in pore size uniformity, high in ion exchange capacity, especially good in adsorptive property on anionic dye contaminants and suitable for treatment of wastewater containing the anionic dye.

Description

technical field [0001] The invention relates to a production method of an ion exchange resin, in particular to a production method of a polystyrene multi-component copolymerization ion exchange resin for removing anionic dyes. Background technique [0002] Ion exchange resin is an important class of adsorption and separation materials. It is a porous spongy solid polymer substance in structure. Each resin particle is composed of a cross-linked network skeleton with a three-dimensional three-dimensional structure, and many movable particles are connected to the skeleton. functional base. It is insoluble in general acid-base solutions and organic solvents, and can be used in various fields such as water treatment, food, pharmaceutical, petrochemical and environmental protection, and is playing an increasingly important role in modern industry. [0003] At present, the most widely used ion exchange resin is polystyrene-based resin, which has the advantages of easy-to-obtain ra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F212/08C08F212/36C08F220/14C08F230/08C08F8/32C08F8/24C08F2/44C08K3/22C02F1/42C02F101/30
CPCC02F1/42C02F2101/308C08F8/24C08F8/32C08F212/08C08K3/22C08K2003/222C08K2201/011C08F212/36C08F220/14C08F230/08C08F2/44
Inventor 姚能平梅德华陈建国林伟王海宽王玉兰
Owner ANHUI WANDONG CHEM
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