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A method of controlling heterotrophic bacteria in circulating cooling water

A technology of circulating cooling water and controlling circulation, which is applied in the direction of oxidation water/sewage treatment, sterilization/microdynamic water/sewage treatment, etc., which can solve the problem of increasing water supply production cost, increasing water cost, and reducing heat exchange efficiency of cold exchange equipment And other issues

Active Publication Date: 2019-06-14
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The biological slime will lead to: (1) reduce the heat transfer efficiency of the cold exchange equipment; (2) increase the corrosion of the cold exchange equipment; (3) block the pipeline, increase the resistance of water delivery, and reduce the energy efficiency; (4) increase the water supply Cost of production
[0006] 2. Corrosion caused by microorganisms themselves
[0013] In addition to the normal consumption caused by sterilization, the bactericide in the circulating cooling water system also has abnormal consumption caused by other aspects. On the one hand, in order to compensate for the consumption of the agent, it is necessary to continuously replenish the agent; on the other hand, in order to reduce the cost of the agent, It is also necessary to control the abnormal consumption of medicine
CN1535250A discloses a method for controlling the growth of microorganisms or killing microorganisms in aqueous solution, the method mentions halogen stabilizers, such as ureide, urea, sulfonamide, sulfuramide, pyrrole, indole, imidazoline, Melamine, amino acid ester, pyrimidine, phosphoramide, thiazole, pyrrolidone, sulfamic acid, ammonia, ammonium bromide, etc., use these halogen stabilizers to improve the photolysis and oxidation stability of fungicides, but in open cycle These halogen stabilizers are not always effective when cooling water systems, and there is also the problem of "loss of halogen source due to interaction with ammonium salts or urea and halogen stabilizers such as sulfamic acid or sulfamate"
[0014] In some cases, such as when the circulating water contains NH 4 + At this time, nitrosating bacteria are very easy to reproduce, which often leads to microbial loss of control and a significant increase in the corrosion of circulating water (alkalinity and pH values ​​drop sharply)
At this time, measures are generally taken to increase the frequency and dosage of fungicides or increase the amount of sewage to replace the water body. In addition to the increase in nitrosative bacteria, sometimes it is still impossible to effectively control the reproduction of nitrosating bacteria (such as using chlorine-based fungicides, even if the amount of bactericides is increased, it is difficult to detect residual chlorine), and it may also cause other problems (such as The use of quaternary ammonium salt non-oxidizing fungicides will lead to a significant increase in the turbidity of the circulating water system)

Method used

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  • A method of controlling heterotrophic bacteria in circulating cooling water
  • A method of controlling heterotrophic bacteria in circulating cooling water
  • A method of controlling heterotrophic bacteria in circulating cooling water

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0105] Weigh 2g of ethylenediamine and add 98g of scale and corrosion inhibitor II to obtain the first mixture, and use Beijing tap water to make a solution with the content of the first mixture of 25mg / L as water replenishment for the moving model; trichloroisocyanuric acid with 85% available chlorine Use deionized water to make an oxidative fungicide mother liquor with 1mg / mL of available chlorine, and use a constant flow pump to continuously add it to the moving tower pool at a flow rate of 1mL / min; after reaching the concentration multiple on the third day, sample and analyze the residual chlorine every day. The test results are shown in Table 2.

Embodiment 2

[0107] Weigh 3g of ethanolamine and add 97g of scale and corrosion inhibitor II to obtain the first mixture, use Beijing tap water to make a solution with the content of the first mixture of 25mg / L, and then add 2.5mg / L NH 4 + As the water replenishment of the movable mold; the NaClO with 10% available chlorine is made into the oxidative fungicide mother liquor of available chlorine 1mg / mL with deionized water, and is continuously added in the movable mold tower pool with a constant flow pump at a flow rate of 1mL / min; the third After Tianda was concentrated multiple times, samples were taken and analyzed for residual chlorine every day. The test results are shown in Table 2.

Embodiment 3

[0109] Weigh 5g of triethylenetetramine and add 95g of scale and corrosion inhibitor II to obtain the first mixture, use Beijing tap water to make a solution with the content of the first mixture of 25mg / L, and then add 2.5mg / L NH 4 + As water replenishment for the moving mold; dichloroisocyanuric acid with 65% available chlorine is made into an oxidative fungicide mother liquor with 1mg / mL available chlorine with deionized water, and is continuously added to the moving mold tower pool with a constant flow pump at a flow rate of 1mL / min Middle; after reaching the concentration multiple on the third day, samples were taken and analyzed for residual chlorine every day, and the test results are shown in Table 2.

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Abstract

The invention relates to a method for controlling heterotrophic bacteria in circulating cooling water. The method includes the steps that 1, chlorine bactericide and an effective quantity of residual chlorine stabilizer are continuously added into the circulating cooling water, and the residual chlorine stabilizer is amine and / or alcohol amine with the boiling point larger than 100 DEG C; 2, when the content of the heterotrophic bacteria in the circulating cooling water is larger than a control index value, quaternary ammonium salt non-oxidative bactericide is added in an impacted mode. By means of the method, the heterotrophic bacteria in the circulating cooling water can be effectively controlled.

Description

technical field [0001] The invention relates to a method for controlling heterotrophic bacteria in circulating cooling water. Background technique [0002] The circulating cooling water system is a special water body environment, its temperature (generally 25 ℃ ~ 40 ℃) and pH value (generally 6.5 ~ 9.0), sufficient dissolved oxygen and light, and rich minerals brought by concentration and organic matter, providing suitable growth conditions for a variety of microorganisms, such as bacteria (such as filamentous fungi, slime-producing fungi, spores, acid-producing bacteria), fungi (such as yeast, mold), algae (such as diatoms, Green algae) and protozoa (such as amoeba, ciliate), etc. can reproduce in the circulating cooling water system. [0003] The proliferation of microorganisms will seriously affect the normal operation of the circulating cooling water system, and its main hazards are manifested in the following three aspects. [0004] 1. Produce biological slime [000...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/50C02F1/76
Inventor 余正齐李亚红
Owner CHINA PETROLEUM & CHEM CORP