Slow-crosslinked high-strength jelly profile control water-plugging agent

A profile control water blocking agent, high-strength technology, applied in the field of hydrophobic association polymer blocking agent, slow cross-linking high-strength jelly, can solve the problems of high toxicity and irritation, weak gelling strength, high cost, etc. Achieve the effects of good injection performance, good shear resistance and reduced construction difficulty

A profile control water blocking agent, high-strength technology, applied in the field of hydrophobic association polymer blocking agent, slow cross-linking high-strength jelly, can solve the problems of high toxicity and irritation, weak gelling strength, high cost, etc. Achieve the effects of good injection performance, good shear resistance and reduced construction difficulty

CN106479463AInactive Publication Date: 2017-03-08CHINA UNIV OF PETROLEUM (EAST CHINA)

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  • Slow-crosslinked high-strength jelly profile control water-plugging agent
  • Slow-crosslinked high-strength jelly profile control water-plugging agent
  • Slow-crosslinked high-strength jelly profile control water-plugging agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Add 0.3g of melamine resin, 0.03g of resorcinol, 0.2g of thiourea, 0.1g of ammonium chloride, 0.1g of sodium malonate to the beaker, add tap water to 50g, stir evenly to fully dissolve, and then add 50g of A hydrophobic associative polymer solution with a mass concentration of 0.6% prepared with tap water was mixed with the above solution, stirred evenly to obtain a gel solution, took 20 ml of it and put it into an ampoule bottle, sintered and sealed, and placed it in an oven at 60 °C for 6 days of aging. That is, the jelly of the present invention is obtained.

[0031] Blocking ability inspection:

[0032] The blocking ability of the jelly provided by the present invention was investigated. The specific experimental process is as follows: Two sand-packing pipes with an inner diameter of 2.5cm and a length of 20cm are filled with quartz sand to obtain high and low permeability simulated cores, denoted as 1# and 2#, and the original permeability is obtained after water ...

Embodiment 2

[0036] Add 0.4g melamine resin, 0.04g resorcinol, 0.3g thiourea, 0.15g ammonium chloride, 0.15g sodium malonate to the beaker, add 1% NaCl aqueous solution to 50g, stir well, make it fully dissolved, and then Mix 50 g of a hydrophobic associative polymer with a mass concentration of 0.6% prepared with a 1% NaCl aqueous solution with the above solution, stir evenly to obtain a gel solution, take 20 ml and put it into an ampoule bottle, sinter and seal it, and place it in an oven at 65°C. After aging for 7 days, the jelly of the present invention is obtained.

[0037] Blocking ability inspection:

[0038] The blocking ability of the jelly provided by the present invention was investigated. The specific experimental process is as follows: Two sand-packing pipes with an inner diameter of 2.5cm and a length of 20cm are filled with quartz sand to obtain high and low permeability simulated cores, denoted as 3# and 4#, and the original permeability is obtained after water flooding un...

Embodiment 3

[0042] Add 0.5g melamine resin, 0.05g resorcinol, 0.3g thiourea, 0.2g ammonium chloride, 0.2g sodium malonate to the beaker, add 3% NaCl aqueous solution to 50g, stir well, make it fully dissolved, and then Mix 50 g of a hydrophobic associative polymer with a mass concentration of 0.8% prepared with a 3% NaCl aqueous solution with the above solution, stir evenly to obtain a gel solution, take 20 ml and put it into an ampoule bottle, sinter and seal, and place it in an oven at 70 ° C. After aging for 7 days, the jelly of the present invention is obtained.

[0043] Blocking ability inspection:

[0044] The blocking ability of the jelly provided by the present invention was investigated. The specific experimental process is as follows: Two sand-packing pipes with an inner diameter of 2.5 cm and a length of 20 cm are filled with quartz sand to obtain high and low permeability simulated cores, denoted as 5# and 6#, and the original permeability is obtained after water flooding unt...

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Abstract

The invention discloses a slow-crosslinked high-strength jelly profile control water-plugging agent. The slow-crosslinked high-strength jelly profile control water-plugging agent comprises, by mass, 0.3% to 0.6% of a hydrophobic associating polymer, 0. 3% to 0.6% of a melamine resin crosslinking agent, 0.03% to 0.05% of a phenol crosslinking agent, 0.2% to 0.4% of an oxygen scavenger, 0.1% to 0.3% of a delayed crosslinking agent, 0.1% to 0.2% of a water loss inhibitor and the balance water. The phenol crosslinking agent comprises one or two of resorcinol and hydroquinone. The oxygen scavenger comprises one or more of thiourea, sodium sulfite and sodium bisulfate. The delayed crosslinking agent comprises one or two of ammonium chloride and sodium trimetaphosphate. The water loss inhibitor comprises one or two of sodium malonate and sodium salicylate. The gelatinization time of the jelly provided by the invention is adjustable and is 6 days or more. After gelatinization, the jelly strength at least reach to level H based on visual inspection. The water-plugging agent has excellent thermal stability, does not lose water after hot treatment at a temperature of 60-90 DEG C for 270 days and can satisfy the requirements on most of deep oil reservoir displacement.

Description

[0001] Technical field: [0002] The invention relates to a hydrophobic associative polymer plugging agent, in particular to a slow-crosslinking high-strength jelly, which belongs to the technical field of oilfield chemistry. [0003] Background technique: [0004] In the process of oilfield development, when the original energy of the oil layer begins to decrease, it is necessary to manually supplement the energy to the formation, that is, inject water into the oil reservoir to improve the oil recovery rate. However, due to the heterogeneity of the formation and the difference in oil-water mobility ratio or improper exploitation methods, the injected water is unevenly advanced along the high-permeability layer or high-permeability zone, resulting in premature water production from the oil well until flooding. At present, most of the oilfields developed by water injection in my country have entered the stage of high water cut. According to statistics, the average water content...

Claims

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Application Information

Patent Timeline
08 Mar 2017
Publication
CN106479463A
IPC
C09K8/512
CPC
C09K8/512
Inventors
韩胜霞; 葛际江