Single-component anti-bacteria anti-yellowing colored silicone sealant for fish tank and preparation method of single-component anti-bacteria anti-yellowing colored silicone sealant

A silicone sealant, a single-component technology, applied in the field of sealants, can solve the problems of reduced mechanical strength and viscosity performance, poor functional progress, affecting appearance and cleaning, etc., and achieves improved bonding strength and maintenance System color, keep clean and beautiful effect

Inactive Publication Date: 2017-03-22
山东宝龙达新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] On the one hand, none of the above-mentioned silicone glues has added pigments. After adding pigments, the mechanical strength and viscosity properties of the silicone glues have been reduced, and due to long-term contact with water, it is very easy to breed mold on the surface of the glue, which affects the appearance and cleanliness. It is especially obvious on the interface between water and air. Therefore, it is necessary to find a suitable composition to ensure the color of the silicone adhesive. The mechanical strength and bonding performance will not be affected. It is not easy to breed bacteria and mildew, and it can keep the color unchanged for a long time. , has become an urgent problem to be solved in the development process of high-end fish tank glue
On the other hand, the current silicone sealants have not made good progress in terms of functionality, especially silicone sealants for fish tanks
Because the silicone glue used for fish tanks is in contact with water for a long time, it is particularly easy to mold and breed bacteria in a humid environment, which affects the appearance, is not easy to clean, and will lead to a decline in water quality. Therefore, it is necessary to develop these special glues for specific environments.
[0007] In the case of product innovation and high quality requirements, continuing to use the original transparent silicone adhesive system can no longer meet the requirements of some high indicators, so the development of high-end fish tank adhesives is urgently needed to achieve product innovation and performance.

Method used

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  • Single-component anti-bacteria anti-yellowing colored silicone sealant for fish tank and preparation method of single-component anti-bacteria anti-yellowing colored silicone sealant
  • Single-component anti-bacteria anti-yellowing colored silicone sealant for fish tank and preparation method of single-component anti-bacteria anti-yellowing colored silicone sealant
  • Single-component anti-bacteria anti-yellowing colored silicone sealant for fish tank and preparation method of single-component anti-bacteria anti-yellowing colored silicone sealant

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] 100 parts of α-ω-dihydroxyl-terminated polysiloxane (107 glue) with a viscosity of 20000 cp, 5 parts of quaternary ammonium salt end-modified dimethylpolysiloxane with a viscosity of 350 cp, and 13 parts of fumed silica , 8 parts of bright red pigment; 8 parts of methyl triacetoxysilane, 1 part of γ-aminopropyl triethoxysilane, 0.1 part of dibutyl tin diacetate.

[0043] The preparation steps are as follows:

[0044] (1) Stir the hydroxyl-terminated polysiloxane, quaternary ammonium salt-terminated modified dimethylpolysiloxane, scarlet pigment, and methyltriacetoxysilane evenly;

[0045] (2) Add fumed white carbon black and disperse evenly;

[0046](3) Add γ-aminopropyltriethoxysilane and dibutyltin diacetate, and stir evenly to obtain the antibacterial and anti-yellowing colored elastic silicone sealant for fish tanks.

Embodiment 2

[0048] 50 parts of α-ω-dihydroxyl-terminated polysiloxane with a viscosity of 20000cp, 50 parts of α-ω-dihydroxyl-terminated polysiloxane with a viscosity of 80000cp, quaternary ammonium salt end-group modified bismuth with a viscosity of 350cp 8 parts of methyl polysiloxane, 12 parts of fumed silica, 7 parts of iron green pigment; 7 parts of methyltriacetoxysilane, 1 part of γ-aminopropyltriethoxysilane, dibutyl diacetic acid Tin 0.1 part.

[0049] The preparation steps are as follows:

[0050] (1) Stir the hydroxyl-terminated polysiloxane, quaternary ammonium salt-terminated modified dimethylpolysiloxane, iron green pigment, and methyltriacetoxysilane evenly;

[0051] (2) Add fumed white carbon black and disperse evenly;

[0052] (3) Add γ-aminopropyltriethoxysilane and dibutyltin diacetate, and stir evenly to obtain the antibacterial and anti-yellowing colored elastic silicone sealant for fish tanks.

Embodiment 3

[0054] 100 parts of α-ω-dihydroxyl-terminated polysiloxane with a viscosity of 80000cp, 9 parts of quaternary ammonium salt-terminated modified dimethylpolysiloxane with a viscosity of 350cp, 11 parts of fumed white carbon black, titanium blue 3 parts of pigment; 6 parts of methyltriacetoxysilane, 1 part of γ-aminopropyltriethoxysilane, 0.1 part of dibutyltin diacetate.

[0055] The preparation steps are as follows:

[0056] (1) Stir the hydroxyl-terminated polysiloxane, quaternary ammonium salt-terminated modified dimethylpolysiloxane, scarlet pigment, and methyltriacetoxysilane evenly;

[0057] (2) Add fumed white carbon black and disperse evenly;

[0058] (3) Add γ-aminopropyltriethoxysilane and dibutyltin diacetate, and stir evenly to obtain the antibacterial and anti-yellowing colored elastic silicone sealant for fish tanks.

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PUM

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Abstract

The invention relates to a single-component anti-bacteria anti-yellowing colored silicone sealant for a fish tank and a preparation method of the single-component anti-bacteria anti-yellowing colored silicone sealant. The sealant is composed of, by weight, 100 parts of dihydroxy polydimethyl siloxane, 5-10 parts of quaternary ammonium salt end group modified dimethyl polysiloxane, 0-10 parts of pigments, 8-15 parts of fillers, 5-10 parts of acyloxy silane crosslinking agent, 1 part of coupling agent and 0.1 part of catalyst. By adding the bright-colored pigments, the attractiveness and practicability of the product are improved, and the product is easier to meet the demands of the market. By selection and matching of the viscosity of the 107 adhesive and addition of the coupling agent, a system is further reinforced, the elongation is controlled within a reasonable range, and the adverse effect on the sealant properties due to addition of the pigments is avoided. The method that an original silicone sealant adopts common dimethicone is changed to the method which adopts quaternary ammonium salt end group modified dimethyl polysiloxane so that the silicone sealant for the fish tank can keep colored for a long time, moreover, mildewing and bacteria breeding are not prone to occurring, the sealant is environmentally friendly, and the fish tank can keep clean and attractive for a long time.

Description

technical field [0001] The invention relates to a single-component antibacterial and anti-yellowing colored silicone sealant for fish tanks and a preparation method thereof, belonging to the technical field of sealants. Background technique [0002] The fish tank is a glassware used to raise tropical fish or goldfish. It plays an ornamental role. It not only creates a warm home for the fish, but also ensures the safety of the overall living environment. The fish tank is an indispensable decoration when it comes to home feng shui and other decorations. It is a perfect combination with the space and is the soul Zen master of home, office and commercial space. The tightness and structural stability of the fish tank system are related to the type and performance of the sealant used. At present, the most widely used fish tank glue in China is silicone glue, mainly due to the excellent aging resistance, sealing performance, compatibility and good bonding performance between silic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J183/06C09J183/08C09J11/04C09J11/06C08G77/388
CPCC09J183/06C08G77/388C08L2201/08C08L2205/02C09J11/04C09J11/06C08L83/08C08K13/02C08K5/5419C08K5/544C08K3/36
Inventor 曾庆铭姚朋建夏鹏飞曹健
Owner 山东宝龙达新材料有限公司
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