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Degradable insulating wire cable material with heat resistance and durability

An insulated wire and durability technology, applied in the direction of organic insulators, insulators, plastic/resin/wax insulators, etc., can solve the problems of poor mechanical properties, poor molding performance, poor compatibility, etc., and achieve physical and mechanical properties. There is performance, the effect of improving durability performance

Inactive Publication Date: 2017-05-17
中广核高新核材科技(苏州)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Chinese Patent Publication No. CN 101423654 discloses a plastic insulation and sheath material for degradable cables and cables. The patent manufactures cables by blending polylactic acid with reinforcing agents, inorganic flame retardants, antioxidants, and copper inhibitors. With insulating materials and sheath materials, the material is filled with a large amount of inorganic flame retardants and fillers without toughening modification, and its mechanical properties are extremely poor. It is still a hard and brittle material with poor formability and no Practical value described in the patent
[0007] Chinese Patent Publication No. CN 104356620A discloses a degradable electrical insulation material, which is prepared by blending polylactic acid with bacterial cellulose, cross-linked polyethylene, polycarbonate, ethylene-propylene rubber, glass fiber, etc. However, the compatibility between polylactic acid and cross-linked polyethylene, polycarbonate, and ethylene-propylene rubber is poor, and the mechanical properties are not good. The development trend of halogen-free flame retardant

Method used

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  • Degradable insulating wire cable material with heat resistance and durability
  • Degradable insulating wire cable material with heat resistance and durability

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Experimental program
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Effect test

Embodiment 1~4

[0029] Embodiments 1 to 4: A degradable insulating wire and cable material with heat resistance and durability, consisting of the following components by weight:

[0030] Table 1

[0031]

[0032] The above-mentioned L-polylactic acid and D-polylactic acid have a weight average molecular weight of 100,000 to 400,000.

Embodiment 1

[0033] Example 1 The metal deactivator is N-salicylamidophthalimide; the flame retardant is polycondensed aryl phosphate, mixed with triphenyl phosphate according to the weight ratio of 1:1; the filler is nano-dioxide A mixture of silicon and nano talcum powder.

Embodiment 2

[0034] Example 2 The metal deactivator is N,N'-bis[β(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl]hydrazine; the flame retardant is cyclic phosphoric acid ester, phosphorus cyanide flame retardant agent to form a mixture; the filler is mixed with nano-layered silicate and nano-calcium carbonate according to the weight ratio of 1:2.

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PUM

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Abstract

The invention discloses a degradable insulating wire cable material with heat resistance and durability. The degradable insulating wire cable material is prepared from the following components in parts by weight: 65 to 85 parts of L-polylactic acid, 20 to 30 parts of D-polylactic acid, 15 to 25 parts of isosorbide diester, 5 to 10 parts of bis(2-(2-butoxyethoxy)ethyl)adipate, 0.02 to 2 parts of a metal passivating agent, 2 to 5 parts of carbodiimide, 0.1 to 0.8 part of isocyanate, 30 to 50 parts of a flame retardant, 5 to 8 parts of triallyl isocyanurate, 1 to 3 parts of trimethallyl isocyanurate and 2 to 20 parts of filling. The degradable insulating wire cable material with the heat resistance and the durability, disclosed by the invention, is degradable with the heat resistance and the durability, is stable in a use process, and has heat resistance, durability and anti-scratching performance; meanwhile, the degradable insulating wire cable material has natural bacterium-inhibiting performance and can be biodegraded after being abandoned; the degradable insulating wire cable material has a very low carbon footprint, and influences on the environment are reduced to the minimum.

Description

technical field [0001] The invention relates to the technical field of cable materials, in particular to a degradable insulating wire and cable material with heat resistance and durability. Background technique [0002] In the known wire or cable insulation or sheath materials, non-degradable petroleum resources such as polyolefin or polyvinyl chloride are generally used as insulators, which have excellent performance and long service life. However, due to its structural characteristics and other reasons, it cannot be degraded basically or it takes hundreds of years to decompose. Severe environmental impact if discarded - if incinerated it will produce large amounts of CO 2 Even toxic and harmful gases endanger environmental safety; landfills occupy land resources, and there is a huge environmental risk of organic matter precipitation in the soil; even recycling can only recover some bulky, easy-to-recycle, unaged and cross-linked materials, most of which are Wires and cab...

Claims

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Application Information

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IPC IPC(8): C08L67/04C08K13/02C08K5/11C08K5/29C08K5/523C08K3/22C08K5/3492C08K3/36C08K3/34C08K3/26H01B3/42
CPCC08L67/04C08K2201/011C08L2201/02C08L2201/06C08L2201/08C08L2203/202C08L2205/025H01B3/421C08K13/02C08K5/11C08K5/29C08K5/523C08K2003/2296C08K5/34928C08K3/36C08K3/34C08K2003/265
Inventor 杨刚
Owner 中广核高新核材科技(苏州)有限公司
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