Acrylic emulsion for PVC (Polyvinyl Chloride) water-based ink and preparation method of acrylic emulsion

A technology of acrylic emulsion and water-based ink, applied in the field of emulsion, can solve the problems of health damage of printing operators and substrate contact personnel, and achieve the effects of good transparency, improved printing gloss, and improved water resistance

Inactive Publication Date: 2017-05-31
GUANGDONG HENGGUANG CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional PVC printing mostly uses solvent-based inks in consideration of printing effects and adhesion, and the volati

Method used

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  • Acrylic emulsion for PVC (Polyvinyl Chloride) water-based ink and preparation method of acrylic emulsion
  • Acrylic emulsion for PVC (Polyvinyl Chloride) water-based ink and preparation method of acrylic emulsion
  • Acrylic emulsion for PVC (Polyvinyl Chloride) water-based ink and preparation method of acrylic emulsion

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0038] Example 1

[0039] An acrylic emulsion for PVC water-based ink, comprising the following components by weight percentage, core structure monomer: 1% methyl methacrylate, 0.2% ethyl acrylate, 0.2% acrylamide, 0.2% silane coupling agent %; shell structure monomer: methyl methacrylate 11%, butyl acrylate 20%, ethyl acrylate 5%, methacrylic acid 1%, acrylic acid 1%, caprolactam 0.4%; anionic emulsifier 7.7%, reactive 0.3% emulsifier, 1.5% non-ionic emulsifier, 0.5% ammonium persulfate, 0.8% 30% ammonia water, 0.2% bactericide, 49% deionized water.

[0040] Above-mentioned emulsion can be prepared by traditional technique, and more optimal selection is to select the preparation method of the present invention for use, comprises the following steps:

[0041] (1) Preparation of core layer pre-emulsion: add 2% deionized water, 2% anionic emulsifier, methyl methacrylate, ethyl acrylate, acrylamide, silane coupling agent successively in the pre-emulsification kettle I, Thorough...

Example Embodiment

[0053] Example 2

[0054] An acrylic emulsion for PVC water-based ink, comprising the following components by weight percentage, core structure monomer: 0.5% methyl methacrylate, 0.5% ethyl acrylate, 0.5% acrylamide, 0.5% silane coupling agent %; shell structure monomer: methyl methacrylate 15%, butyl acrylate 15%, ethyl acrylate 4%, methacrylic acid 0.5%, acrylic acid 0.5%, caprolactam 5%; anionic emulsifier 2%, reactive type 0.4% emulsifier, 1.5% non-ionic emulsifier, 1.5% ammonium persulfate, 0.5% 30% ammonia water, 0.1% bactericide, 52% deionized water.

[0055] Above-mentioned emulsion can be prepared by traditional technique, and more optimal selection is to select the preparation method of the present invention for use, comprises the following steps:

[0056] (1) Preparation of the core layer pre-emulsion: add 5% deionized water, 0.5% anionic emulsifier, methyl methacrylate, ethyl acrylate, acrylamide, silane coupling agent successively in the pre-emulsification kettle...

Example Embodiment

[0068] Example 3

[0069] An acrylic emulsion for PVC water-based ink, comprising the following components by weight percentage, core structure monomer: 0.4% methyl methacrylate, 0.6% ethyl acrylate, 0.6% acrylamide, 0.4% silane coupling agent %; shell structure monomer: methyl methacrylate 13.2%, butyl acrylate 16.7%, caprolactam 0.1%; anionic emulsifier 3%, reactive emulsifier 0.2%, nonionic emulsifier 1%, ammonium persulfate 2%, 30% ammonia water 1%, fungicide 0.3%, deionized water 60.5%.

[0070] Above-mentioned emulsion can be prepared by traditional technique, and more optimal selection is to select the preparation method of the present invention for use, comprises the following steps:

[0071] (1) Preparation of the core layer pre-emulsion: add 4% deionized water, 0.7% anionic emulsifier, methyl methacrylate, ethyl acrylate, acrylamide, silane coupling agent successively in the pre-emulsification kettle I, Fully stir for 1.2h to obtain the core layer pre-emulsion;

...

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Abstract

The invention discloses an acrylic emulsion for PVC (Polyvinyl Chloride) water-based ink, and belongs to the technical field of emulsions. The acrylic emulsion is of a core-shell structure and comprises the following components in percentage by mass: 2-10% of an anionic emulsifier, 0-0.5% of a reaction type emulsifier, 0-3% of a non-ionic emulsifier, 0.05-2% of ammonium persulfate, 0.5-1.0% of 30% ammonium hydroxide, 0.1-0.3% of a bactericide, 40-70% of deionized water, a core structure monomer and a shell structure monomer, wherein the core structure monomer comprises the following components in percentage by weight: 0.1-10% of methyl methacrylate, 0-5% of ethyl acrylate, 0-5% of acrylamide and 0-5% of a silane coupling agent; the shell structure monomer comprises the following components in percentage by weight: 10-25% of methyl methacrylate, 15-25% of butyl acrylate, 0-10% of ethyl acrylate, 0-1% of methacrylic acid, 0-1% of crylic acid and 0-5% of caprolactam. The acrylic emulsion is excellent in adhesion property and good in water resistance on a PVC substrate.

Description

technical field [0001] The invention belongs to the technical field of emulsions, relates to an acrylic emulsion, in particular to an acrylic emulsion used for PVC water-based ink and a preparation method thereof. The acrylic emulsion of the present invention has excellent adhesion and good water resistance on the PVC substrate, and at the same time, no alcohol substances harmful to human body are used in the synthesis process, which is more in line with people's requirements for paying attention to health. Background technique [0002] PVC is one of the most versatile general-purpose plastics. PVC has good water-repellent properties, and can be used for packaging of food, seasonings, beverages, etc., flexible packaging for packaging various items, beer bottle caps and beverage bottle cap linings, and wallpaper. Traditional PVC printing mostly uses solvent-based inks for the sake of printing effect and adhesion. The volatilization of the solvent will cause health damage to ...

Claims

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Application Information

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IPC IPC(8): C08F220/14C08F220/18C08F220/56C08F265/04C08F265/06C08F2/26C08F2/30C09D11/107
CPCC09D11/107C08F2/26C08F2/30C08F220/14C08F265/04C08F265/06C08F220/06C08F220/1804C08F220/18C08F220/56C08F220/1802
Inventor 王俊丽郝丽娟田海水焦健高昊
Owner GUANGDONG HENGGUANG CHEM CO LTD
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