Special low-temperature curing powder coating for electrostatic spraying and preparation method thereof

A powder coating, electrostatic spraying technology, applied in powder coatings, polyester coatings, epoxy resin coatings, etc., can solve the problems of harsh curing conditions, poor powder storage stability, inconvenient use, etc., to improve the decorative performance of pigments, The effect of improving dispersion stability and reducing production costs

Inactive Publication Date: 2017-05-31
TIANCHANG JINLING ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Powder coatings have their own production process characteristics, and the curing conditions are relatively harsh. The standard curing temperature is generally between 180-200 ° C, resulting in high energy consumption, and limiting the application of powder coatings on heat-sensitive substrates, hindering the application of powder coatings Therefore, low-temperature curing of powder coatings has become the development goal of the powder coating industry
[0004] Powder coating is a low-temperature latent curing system. If the system has high low-temperature reactivity, it will inevitably affect the powder milling extrusion process and storage stability. If the resin and curing agent used in the powder coating are relatively high softening Solids with a low softening point have high melt viscosity at low temperatures, and are difficult to level when solidified at low temperatures, which affects the surface effect. Using resins and curing agents with low softening points can reduce the melt viscosity of the system, but the storage stability of the powder will deteriorate. , need to be stored in low temperature refrigeration, which brings a lot of inconvenience to use; it can be seen that the key problem of powder coating ultra-low temperature curing technology is to find a system with a good balance between storage stability, melting, fluidity and curing

Method used

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  • Special low-temperature curing powder coating for electrostatic spraying and preparation method thereof

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Effect test

Embodiment 1

[0023] A special low-temperature curing powder coating for electrostatic spraying, its raw materials include by weight: 55 parts of polyester resin, 25 parts of epoxy resin, 5 parts of silicone resin, 8 parts of modified carbon nanotubes, 1 part of graphite powder, white carbon 6 parts of black, 5 parts of titanium dioxide, 40 parts of filler, 1 part of pigment, 5 parts of curing agent, 0.05 parts of curing accelerator, 3 parts of leveling agent, 1 part of dispersant, 0.5 parts of coupling agent, 1 part of styrene-acrylic emulsion ; The modified carbon nanotubes are made by in-situ polycondensation of activated carbon nanotubes and acrylic monomers.

Embodiment 2

[0025] A special low-temperature curing powder coating for electrostatic spraying, its raw materials include by weight: 75 parts of polyester resin, 15 parts of epoxy resin, 10 parts of polyester modified siloxane, 2 parts of modified carbon nanotubes, 3 parts of graphite powder Parts, 2 parts of precipitated silica, 15 parts of titanium dioxide, 5 parts of barium sulfate, 10 parts of pigment, 2 parts of triglycidyl isocyanurate, 0.5 parts of methylimidazole, 1 part of leveling agent, dispersant 3 parts, 0.1 parts of coupling agent, 5 parts of styrene-acrylic emulsion;

[0026] The acid value of the polyester resin is 45mgKOH / g, and the softening point is 95°C; the modified carbon nanotubes are made by in-situ polycondensation of activated carbon nanotubes and acrylic monomers, and the modified The method for carbon nanotubes includes: adding carbon nanotubes into a mixed acid solution of concentrated nitric acid and phosphomolybdic acid at a weight ratio of 1:0.001, ultrasoni...

Embodiment 3

[0028] A special low-temperature curing powder coating for electrostatic spraying, its raw materials include by weight: 65 parts of polyester resin, 20 parts of epoxy resin, 7 parts of polyether modified siloxane, 5 parts of modified carbon nanotubes, 2 parts of graphite powder 4 parts, white carbon black 4 parts, titanium dioxide 10 parts, filler 22 parts, pigment 5 parts, hydroxyalkylamide 3 parts, methyl imidazole 0.3 parts, leveling agent 2 parts, dispersant 2 parts, coupling agent 0.3 parts , 3 parts of styrene-acrylic emulsion;

[0029] The acid value of the polyester resin is 60mgKOH / g, and the softening point is 90°C; the white carbon black is precipitated silica and fumed silica; the filler is barium sulfate, lithopone, calcium carbonate and kaolin ;

[0030]The modified carbon nanotubes are made by in-situ polycondensation of activated carbon nanotubes and acrylic monomers, and the method for preparing the modified carbon nanotubes includes: adding carbon nanotubes ...

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Abstract

The invention relates to a special low-temperature curing powder coating for electrostatic spraying and a preparation method thereof. The powder coating is prepared from the following raw materials in parts by weight: 55-75 parts of polyester resin, 15-25 parts of epoxy resin, 5-10 parts of organic silicon resin, 2-8 parts of modified carbon nano tubes, 1-3 parts of graphite powder, 2-6 parts of white carbon black, 5-15 parts of titanium dioxide, 5-40 parts of filler, 1-10 parts of a pigment, 2-5 parts of a curing agent, 0.05-0.5 part of a curing catalyst, 1-3 parts of a flatting agent, 1-3 parts of a dispersing agent, 0.1-0.5 part of a coupling agent and 1-5 parts of a styrene-acrylic emulsion. The powder coating has the advantages of being simple in formula, low in curing temperature, good in mechanical property, smooth in film, high in adhesive force and stable to store, electrostatic spraying can be achieved, the construction difficulty is reduced and the work efficiency is improved.

Description

technical field [0001] The invention relates to the technical field of powder coatings, in particular to a special low-temperature curing powder coating for electrostatic spraying and a preparation method thereof. Background technique [0002] Powder coating is a coating that contains 100% solid content and is applied in powder form. The biggest difference between it and general solvent-based and water-based coatings is that it does not use solvent or water as a dispersion medium. Because of the recyclable and reused spraying material in the coating process, no solvent volatilization, safe production and construction, easy automation of coating, and improved productivity, it has become a new coating product with rapid development. At present, powder coating has been proved to be a major technical achievement, and has entered a relatively mature stage of development. [0003] Powder coatings have their own production process characteristics and are not cured at low temperatu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D167/00C09D163/00C09D183/04C09D125/14C09D5/03C09D7/12
CPCC09D167/00C08K2201/011C08L2205/035C09D5/033C09D5/034C08L63/00C08L83/04C08L25/14C08K13/06C08K9/10C08K7/24C08K3/04C08K3/36C08K2003/2241
Inventor 茆文斌
Owner TIANCHANG JINLING ELECTRONICS
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