A kind of aramid-spandex sheath-core composite fiber and preparation method thereof
A technology of composite fiber and spandex, which is applied in the field of polyurethane elastic fiber material manufacturing, can solve the problem of not solving the interface problem of co-spinning the cortex and core layer to form the cortex-core layer, poor performance stability and uniformity, and unsuitable for industrial production. , to achieve the effect of improving dyeability and color fastness, good emulsifying ability and high resilience
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[0035] The invention relates to an aramid-spandex skin-core composite fiber and a preparation method thereof. The skin layer is coated on the outside of the core layer. The skin layer is made of aramid fiber 1313, the core layer is made of spandex, and the cross section of the fiber is a concentric circular solid structure. The preparation method is as follows: dry spinning by sheath-core extrusion method, the cortex spinning stock solution and the core layer spinning stock solution enter the spinning system together, and the cortex accounts for 5-20% of the total weight of the composite fiber by separating elements and metering pumps. % and extrude from the spinneret together, enter the dry spinning tunnel, dry at high temperature, oil with oil, and wind up.
[0036]The described cortex spinning dope is prepared by low-temperature solution polycondensation from isophthaloyl chloride (IPC) and m-phenylenediamine (MPD). The preparation method comprises the following steps:
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Embodiment 1
[0054] The first step: preparation of cortical spinning dope
[0055] 1) Preparation of polymer solution: Dissolve m-phenylenediamine in N,N-dimethylacetamide (DMAC) solvent, the mass concentration is 10.0%, the temperature is -10°C, add isophthaloyl chloride under stirring , The molar ratio of m-phenylenediamine to isophthaloyl chloride is 1:1.02. During the initial reaction feeding, quickly add isophthaloyl chloride accounting for 75% of the total amount, and control the feeding time for 15 minutes to complete; then cool the obtained prepolymer solution to 5 ° C, and slowly add the remaining 25% isophthaloyl chloride. The control feeding time is 55min. Control the temperature of the prepolymer solution to be 28-32°C.
[0056] 2) Prepare the fiber-forming polymer solution: add calcium hydroxide to the polymer solution prepared in step 1) to neutralize the hydrogen chloride therein, filter impurities and adjust the fiber-forming polymer solution mass concentration to 32.0%, ...
Embodiment 2
[0067] The first step: preparation of cortical spinning dope
[0068] 1) Preparation of polymer solution: Dissolve m-phenylenediamine in N,N-dimethylacetamide (DMAC) solvent, the mass concentration is 15.0%, the temperature is -5°C, add isophthaloyl chloride under stirring , the mol ratio of m-phenylenediamine and isophthaloyl dichloride is 1:1.05, and the isophthaloyl dichloride that accounts for 75% of the total amount is added rapidly during the initial reaction charging, and the control feeding time is completed in 20 minutes; then the obtained prepolymer The temperature of the solution was lowered to 10°C, and the remaining 25% isophthaloyl chloride was added slowly, and the addition time was controlled to be 60 minutes. Control the temperature of the prepolymer solution to be 28-32°C.
[0069] 2) Prepare fiber-forming polymer solution: add butanediamine containing basic ions to the polymer solution prepared in step 1), filter impurities and adjust the mass concentration...
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